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Structure and some properties of UO2(C2H5COO)2 · nQ · mH2O (Q is carbamide or ethylenecarbamide)

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Abstract

The crystals of [UO2(C2H5COO)2(CO(NH2)2)2] · H2O (I) and [UO2(C2H5COO)2(H2O)2] · 2C3H6N2O (II), where CO(NH2)2 is carbamide, C3H6N2O is ethylenecarbamide, were synthesized and studied by IR spectroscopy and X-ray diffraction. The key structural units of compounds I are II are mononuclear electrically neutral complexes, which belong to the AB01M3 1 and AB01M2 1 crystal-chemical groups (A = UO2 2+ B01 = C2H5COO–; M1 = C2H5COO– or CO(NH2)2 (I), H2O (II)) of uranyl complexes. The factors that affect the “selection” of the coordination number of U(VI) atoms (7 or 8, respectively) in the crystal structures of I and II and, as a consequence, are responsible for different structures of uranium complexes are discussed.

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Authors and Affiliations

  1. Samara State University, Samara, Russia

    V. N. Serezhkin, A. R. Abdul’myanov & L. B. Serezhkina

  2. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    M. S. Grigor’ev

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  1. V. N. Serezhkin
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  2. M. S. Grigor’ev
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  3. A. R. Abdul’myanov
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  4. L. B. Serezhkina
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Correspondence to V. N. Serezhkin.

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Original Russian Text © V.N. Serezhkin, M.S. Grigor’ev, A.R. Abdul’myanov, L.B. Serezhkina, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 1, pp. 26–35.

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Serezhkin, V.N., Grigor’ev, M.S., Abdul’myanov, A.R. et al. Structure and some properties of UO2(C2H5COO)2 · nQ · mH2O (Q is carbamide or ethylenecarbamide). Russ. J. Inorg. Chem. 61, 24–32 (2016). https://doi.org/10.1134/S0036023616010228

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  • DOI: https://doi.org/10.1134/S0036023616010228

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