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New uranyl complex with imidazolidine-2-one [UO2(Imon)4(H2O)](ClO4)2: Structure and some properties

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Abstract

A complex of uranyl perchlorate with imidazolidine-2-one as the molecular ligand, [UO2(Imon)4(H2O)](ClO4)2 (I), was synthesized and structurally characterized by X-ray diffraction analysis. The coordination number of the uranium atom is 7. The nearest environment of the uranyl ion includes four O atoms of the imidazolidine-2-one molecules and one O atom of the water molecule. The perchlorate anions are outer-sphere ligands. The crystals are monoclinic: space group P21/c; a = 16.294(3) Å, b = 16.135(3) Å, c = 9.987(2) Å, β= 97.69 (3)°, V = 2603.0 (9) Å3, ρ(calcd) = 2.117 g/cm3, Z = 4. The IR and luminescence spectra of the complex were recorded.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia

    G. B. Andreev, N. A. Budantseva, A. M. Fedoseev & A. B. Yusov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia

    M. Yu. Antipin

  3. Samara State University, Samara, Russia

    E. V. Tuchina & L. B. Serezhkina

Authors
  1. G. B. Andreev
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  2. M. Yu. Antipin
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  3. N. A. Budantseva
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  4. E. V. Tuchina
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  5. L. B. Serezhkina
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  6. A. M. Fedoseev
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  7. A. B. Yusov
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Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 30, No. 12, 2004, pp. 919–924.

Original Russian Text Copyright © 2004 by Andreev, Antipin, Budantseva, Tuchina, Serezhkina, Fedoseev, Yusov.

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Andreev, G.B., Antipin, M.Y., Budantseva, N.A. et al. New uranyl complex with imidazolidine-2-one [UO2(Imon)4(H2O)](ClO4)2: Structure and some properties. Russ J Coord Chem 30, 868–873 (2004). https://doi.org/10.1007/s11173-005-0038-x

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  • DOI: https://doi.org/10.1007/s11173-005-0038-x

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