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Complexing properties of ambidentate benzo-15-crown-5-substituted azomethine ligands

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Abstract

Crown-containing azomethines and their zinc complexes were prepared. Examination of their structure by 1H and 7Li NMR and electronic spectroscopy showed that, in accordance with the concept of hard and soft acids and bases, the hard lithium cation coordinates to the crown ether fragment with the formation of mono-(Li) and binuclear (Li, Zn) complexes.

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/2, Rostov-on-Don, 344090, Russia

    A. S. Burlov, A. V. Tsukanov, G. S. Borodkin, Yu. V. Revinskii, V. A. Bren’, A. D. Garnovskii & V. I. Minkin

  2. Southern Scientific Center, Russian Academy of Sciences, Roston-on-Don, Russia

    A. D. Dubonosov

  3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    A. Yu. Tsivadze

Authors
  1. A. S. Burlov
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  2. A. V. Tsukanov
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  3. G. S. Borodkin
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  4. Yu. V. Revinskii
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  5. A. D. Dubonosov
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  6. V. A. Bren’
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  7. A. D. Garnovskii
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  8. A. Yu. Tsivadze
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  9. V. I. Minkin
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Additional information

Original Russian Text © A.S. Burlov, A.V. Tsukanov, G.S. Borodkin, Yu.V. Revinskii, A.D. Dubonosov, V.A. Bren’, A.D. Garnovskii, A.Yu. Tsivadze, V.I. Minkin, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 6, pp. 1037–1041.

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Burlov, A.S., Tsukanov, A.V., Borodkin, G.S. et al. Complexing properties of ambidentate benzo-15-crown-5-substituted azomethine ligands. Russ J Gen Chem 76, 992–996 (2006). https://doi.org/10.1134/S1070363206060259

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  • DOI: https://doi.org/10.1134/S1070363206060259

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