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Structural influence of the substituent in carboxylate anion on example of α- and β-naphthoate complexes of Co(II), Ni(II), Cu(II), and Zn(II)

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Abstract

The results on the synthesis and study of the crystal structures of molecular complexes of transition metals with anions of α- and β-naphthoic acids and monodentate N-donor ligands (MeCN, 2,3-lutidine) are presented. The compositions and structures of the isolated complexes are determined by the following factors: steric hindrances, intermolecular interactions of the aromatic fragments, and the electronic structure of the metal center.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. E. Goldberg, M. A. Kiskin, S. A. Nikolaevskii, E. N. Zorina-Tikhonova, G. G. Aleksandrov, A. A. Sidorov & I. L. Eremenko

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  1. A. E. Goldberg
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  2. M. A. Kiskin
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  3. S. A. Nikolaevskii
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  4. E. N. Zorina-Tikhonova
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  5. G. G. Aleksandrov
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  6. A. A. Sidorov
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  7. I. L. Eremenko
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Correspondence to S. A. Nikolaevskii.

Additional information

Original Russian Text © A.E. Goldberg, M.A. Kiskin, S.A. Nikolaevskii, E.N. Zorina-Tikhonova, G.G. Aleksandrov, A.A. Sidorov, I.L. Eremenko, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 3, pp. 163–169.

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Goldberg, A.E., Kiskin, M.A., Nikolaevskii, S.A. et al. Structural influence of the substituent in carboxylate anion on example of α- and β-naphthoate complexes of Co(II), Ni(II), Cu(II), and Zn(II). Russ J Coord Chem 41, 182–188 (2015). https://doi.org/10.1134/S1070328415030021

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  • DOI: https://doi.org/10.1134/S1070328415030021

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