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Binuclear zinc naphthoate complex with 1,10-phenanthroline: synthesis, structure, and photoluminescence properties

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Abstract

The new binuclear complex [(1,10-phen)2Zn22-OOCR)22-OOCR)2]·4THF (2·4THF, RCOO is the β-naphthoate anion) was synthesized. According to the single-crystal X-ray diffraction study, a one-dimensional supramolecular structure is formed through intra- and intermolecular π-π interactions between the phenanthroline moieties of complex 2. Compound 2 exhibits photoluminescence properties at room temperature.

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Correspondence to M. A. Kiskin.

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Dedicated to Academician V. N. Charushin on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 987–990, May, 2011.

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Goldberg, A.E., Kiskin, M.A., Kozyukhin, S.A. et al. Binuclear zinc naphthoate complex with 1,10-phenanthroline: synthesis, structure, and photoluminescence properties. Russ Chem Bull 60, 1012–1015 (2011). https://doi.org/10.1007/s11172-011-0158-z

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  • DOI: https://doi.org/10.1007/s11172-011-0158-z

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