Abstract
Asynchronized surface modification method based on coaxial electrospinning was developed to fabricate high-efficiency photodegradative nanofiber for water purification. TiO2 nanoparticles assembled uniformly on the surface of polycaprolactone(PCL) nanofibers to form composite nanofibers through one step process. The maximal content of Ti element was 25.6%(mass fraction) in the PCL/TiO2 composite nanofibrous membrane, which exhibited hydrophilicity and excellent photodegradation under visible light in water. The Rhodamine B dye degraded 96.17% in 120 min under visible light by the PCL/TiO2 composite membrane. The adsorption behavior fitted Langmuir model well and indicated chemical related adsorption. This PCL/TiO2 composite nanofibrous membrane has super degradation properties and displays great application potential to environmental protection.
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References
Kant R., Natural Science, 2012, 4(1), 22
Gupta V. K., Suhas, Journal of Environmental Management, 2009, 90(8), 2313
Pourreza N., Rastegarzadeh S., Larki A., Talanta, 2008, 77(2), 733
Binnie C., Kimber M., Smethurst G., Basic Water Treatment, Royal Society of Chemistry, Cambridge, 2002
Faust S. D., Aly O. M., Chemistry of Water Treatment, CRC Press, Boca Raton, 2018
Hendricks D., Fundamentals of Water Treatment Unit Processes: Physical, Chemical, Biological, CRC Press, Boca Raton, 2016
Ali I., Gupta V., Nature Protocols, 2006, 1(6), 2661
Lee A., Elam J. W., Darling S. B., Environmental Science: Water Research & Technology, 2016, 2(1), 17
Bucs S. S., Farhat N., Kruithof J. C., Picioreanu C., van Loosdrecht M. C. M., Vrouwenvelder J. S., Desalination, 2018, 434, 189
Ademola Bode-Aluko C., Pereao O., Kyaw H. H., Al-Naamani L., Al-Abri M. Z., Tay Zar Myint M., Rossouw A., Fatoba O., Petrik L., Dobretsov S., Materials Science and Engineering: B, 2021, 264, 114913
Picos-Corrales L. A., Sarmiento-Sánchez J. I., Ruelas-Leyva J. P., Crini G. G., Hermosillo-Ochoa E., Gutierrez-Montes J. A., ACS Omega, 2020, 5(8), 3943
Heck K. N., Garcia-Segura S., Westerhoff P., Wong M. S., Accounts of Chemical Research, 2019, 52(4), 906
Gitis V., Hankins N., Journal of Water Process Engineering, 2018, 25, 34
Malini M., Thirumavalavan M., Yang W. Y., Lee J. F., Annadurai G., International Journal of Biological Macromolecules, 2015, 80, 121
Fujishima A., Rao T. N., Tryk D. A., Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2000, 1(1), 1
Zhang M., Chen C., Ma W., Zhao J., Angewandte Chemie International Edtion, 2008, 47(50), 9730
Zhang P., Shao C., Zhang Z., Zhang M., Mu J., Guo Z., Liu Y., Nanoscale, 2011, 3(7), 2943
Ghafuri H., Dehghani M., Rashidizadeh A., Rabbani M., Optik, 2019, 179, 646
Wang F., Min S., Han Y., Feng L., Superlattices and Microstructures, 2010, 48(2), 170
Li W., Li D., Lin Y., Wang P., Chen W., Fu X., Shao Y., The Journal of Physical Chemistry C, 2012, 116(5), 3552
Karagoz S., Kiremitler N. B., Sakir M., Salem S., Onses M. S., Sahmetlioglu E., Ceylan A., Yilmaz E., Ecotoxicology and Environmental Safety, 2020, 188, 109856
Pahasup-Anan T., Suwannahong K., Dechapanya W., Rangkupan R., Journal of Environmental Sciences-China, 2018, 72, 13
Cozzoli P. D., Fanizza E., Comparelli R., Curri M. L., Agostiano A., Laub D., The Journal of Physical Chemistry B, 2004, 108(28), 9623
Tryba B., Morawski A. W., Inagaki M., Toyoda M., Applied Catalysis B: Environmental, 2006, 63(3/4), 215
Wang H., You T., Shi W., Li J., Guo L., The Journal of Physical Chemistry C, 2012, 116(10), 6490
Ming H., Ma Z., Huang H., Lian S., Li H., He X., Yu H., Pan K., Liu Y., Kang Z., Chem Commun(Camb), 2011, 47(28), 8025
Zheng G., Peng H., Jiang J., Kang G., Liu J., Zheng J., Liu Y., Chem. Res. Chinese Universities, 2021, 37(3), 571
Zhu S., Nie L., Journal of Industrial and Engineering Chemistry, 2021, 93, 28
Scaffaro R., Lopresti F., Maio A., Botta L., Rigogliuso S., Ghersi G., Composites Part A: Applied Science and Manufacturing, 2017, 92, 97
S N., Joseph S., Journal of Water Process Engineering, 2018, 21, 61
Thamaphat K., Limsuwan P., Ngotawornchai B., Agriculture and Natural Resources, 2008, 42(5), 357
Pais V., Navarro M., Guise C., Martins R., Fangueiro R., Textile Research Journal, 2021, DOI: https://doi.org/10.1177/00405175211010669
Baranowska-Korczyc A., Warowicka A., Jasiurkowska-Delaporte M., Grześkowiak B., Jarek M., Maciejewska B. M., Jurga-Stopa J., Jurga S., RSC Advances, 2016, 6(24), 19647
Tu H., Li D., Yi Y., Liu R., Wu Y., Dong X., Shi X., Deng H., Composites Communications, 2019, 15, 58
Saricam C., Okur N., Göcek İ., Journal of Industrial Textiles, 2019, 50(3), 398
Pan L., Zou J. J., Zhang X., Wang L., Journal of the American Chemical Society, 2011, 133(26), 10000
Chen X., Mao S. S., Chemical Reviews, 2007, 107(7), 2891
Deskins N. A., Rousseau R., Dupuis M., The Journal of Physical Chemistry C, 2009, 113(13), 14583
Acknowledgements
This work was supported by the National Natural Science Foundation of China (No.51805460), the Science and Technology Planning Project of Fujian Province, China(Nos.2020H6003, 2021J011196), and the Fund of Fujian Innovation Center of Additive Manufacturing, China(No.ZCZZ202-31).
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Peng, H., Jiang, J., Liu, Y. et al. Surfaced-modified TiO2 Nanofibers with Enhanced Photodegradation Under Visible Light. Chem. Res. Chin. Univ. 38, 1475–1481 (2022). https://doi.org/10.1007/s40242-022-2056-3
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DOI: https://doi.org/10.1007/s40242-022-2056-3