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Synthesis and characterization of [Cu(N-MeIm)4(BF4)2] in ionic liquid

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Abstract

A new transition metal complex, [Cu(N-MeIm)4(BF4)2](N-MeIm=N-methylated imidazoles, BF4= tetrafluoroborate), was synthesized via the solvothermal method in ionic liquid. The ionic liquid acts as thermal decomposition reaction medium, soft temple agent and ligand compound. The central Cu(II) ion is coordinated by four N atoms from four N-methylated imidazole ligands, and the four N-methylated imidazole rings are perpendicular to each other. The crystal structure of [Cu(N-MeIm)4(BF4)2] was determined by single crystal X-ray diffraction. The results of thermogravimetry(TG) and Fourier transform infrared spectrometry(FTIR) analyses were in accordance with that of crystal structure. The complex showed strong ligand-based absorbance with maximum wavelength at 208 and 231 nm, which are attributed to π-π* transition of the N-methylated imidazole ligands.

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Authors and Affiliations

  1. Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, Harbin Engineering University, Harbin, 150001, P. R. China

    Jingyang Wang, Meng Zhang & Guoxin Tian

  2. Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin, 150001, P. R. China

    Meng Zhang, Xiaodong Xu, Jing Feng, Yanli Wang, Milin Zhang & Wei Han

  3. Department of Mechanical Engineering, University of Nevada Las Vegas, Las Vegas, NV, 89154-4027, USA

    Yitung Chen

Authors
  1. Jingyang Wang
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  2. Meng Zhang
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  3. Xiaodong Xu
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  4. Jing Feng
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  5. Yanli Wang
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  6. Milin Zhang
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  7. Wei Han
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  8. Yitung Chen
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  9. Guoxin Tian
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Correspondence to Meng Zhang or Xiaodong Xu.

Additional information

Supported by the National Natural Science Foundation of China(Nos. 51104050, 51301050, 51202047), the Natural Science Foundation of Heilongjiang Province, China(No. E201413), the Technology Foundation for Selected Overseas Chinese Scholar of Heilongjiang Province, China(No. 159150130002), the Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province, China(No.LBH-3236310448) and the Fundamental Research Funds for the Central Universities, China(No. GK2150260120).

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Wang, J., Zhang, M., Xu, X. et al. Synthesis and characterization of [Cu(N-MeIm)4(BF4)2] in ionic liquid. Chem. Res. Chin. Univ. 34, 8–12 (2018). https://doi.org/10.1007/s40242-018-7259-2

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  • DOI: https://doi.org/10.1007/s40242-018-7259-2

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