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Aspects of proton transport in calix[6]arene sulfonic acid

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Abstract

The features of proton transport and proton hydration shell structure of calix[6]arene sulfonic acid were studied. XRD and NMR data indicate the existence of crystalline and amorphous phases and various conformations in the acid structure. The hydration process occurs in three stages by thermal analysis and IR spectroscopy. The change in the composition of the hydrate affected the conductivity only at low humidity; an inverse relationship between the water uptake and the activation energy of conductivity is observed in the entire investigated range of humidity.

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Acknowledgements

This work was supported by the Russian Scientific Foundation (Contract No. 14-23-00218).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics of RAS, 1 Academician Semenov Avenue, Chernogolovka, Moscow Region, 142432, Russia

    Lyubov Shmygleva, Evgeny Sanginov, Nikita Slesarenko, Aleksander Chernyak, Aleksander Karelin & Yury Dobrovolsky

  2. Science Center in Chernogolovka RAS, 9 Lesnaya str, Chernogolovka, Moscow Region, 142432, Russia

    Aleksander Chernyak

Authors
  1. Lyubov Shmygleva
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  2. Evgeny Sanginov
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  3. Nikita Slesarenko
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  4. Aleksander Chernyak
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  5. Aleksander Karelin
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  6. Yury Dobrovolsky
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Correspondence to Lyubov Shmygleva.

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Shmygleva, L., Sanginov, E., Slesarenko, N. et al. Aspects of proton transport in calix[6]arene sulfonic acid. Ionics 23, 1793–1800 (2017). https://doi.org/10.1007/s11581-017-2011-3

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  • DOI: https://doi.org/10.1007/s11581-017-2011-3

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