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One-step ultrasonication-assisted synthesis of graphitized multi-walled carbon nanotubes@Super P Li nanocomposite for the determination of isoproturon

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Abstract

Carbonaceous nanomaterials have exhibited huge practical prospects as conductive sensitizers for the modification of electrodes. In this work, the nanocomposite of graphitized multi-walled carbon nanotubes@Super P Li carbon nanoparticles (GCNTs@SP-Li) was designed via a simple ultrasonication-assisted strategy, and then the GCNTs@SP-Li/GCE sensor based on the synthesized GCNTs@SP-Li nanocomposite decorating glassy carbon electrode (GCE) was successfully applied in the sensitive detection of isoproturon (ISO). For the GCNTs@SP-Li nanocomposite, GCNTs with porous structure presented excellent adsorption property, which contributed to the preconcentration of ISO and facilitated the electrolyte penetration. Additionally, GCNTs possessed good electrical conductivity owing its higher graphitization degree. More importantly, the interconnected dot-line-like structure of GCNTs@SP-Li nanocomposite acted as conductive “highways” to remarkably reduce the electron transport distance, which could significantly accelerate the process of redox reaction. Benefiting from the synergistic effect of GCNTs and SP-Li, the optimized GCNTs@SP-Li/GCE sensor showed a low detection limit of 0.1653 μM in the linear concentration of 0.7–30 μM. Additionally, the proposed sensor exhibited satisfactory recoveries from 97.2 to 101.6% towards the determination of ISO in river water and tap water. This work offers a feasible and cost-effective idea in developing the high-performance ISO electrochemical sensor.

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Acknowledgements

This work is financially supported by the Zhongyuan Thousand Talents Program of Henan Province (ZYQR201810142), Young Backbone Teacher Training Project of Henan Province (2020GGJS166), National Key R&D Program of China (No. 2017YFD0301104) and Graduate Education Innovation Training Base Project of Henan Province in 2021 (107020221005).

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Authors and Affiliations

  1. Longping Branch, Graduate School of Hunan University, Changsha, 410125, China

    Dongdong Li & Lianyang Bai

  2. Hunan Weed Science Key Laboratory, Hunan Academy of Agricultural Sciences, Changsha, 410125, China

    Dongdong Li & Lianyang Bai

  3. Henan Institute of Science and Technology, Xinxiang, 453003, China

    Dongdong Li, Xuli Hu, Hongyuan Zhao, Kunjie Ding, Fang Li, Shixing Han, Hongliang Wang & Runqiang Liu

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  1. Dongdong Li
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Correspondence to Hongyuan Zhao, Lianyang Bai or Runqiang Liu.

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Li, D., Hu, X., Zhao, H. et al. One-step ultrasonication-assisted synthesis of graphitized multi-walled carbon nanotubes@Super P Li nanocomposite for the determination of isoproturon. J Porous Mater 29, 629–640 (2022). https://doi.org/10.1007/s10934-022-01201-9

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