Abstract
Energy is the driver in the economic development of any country. However, most of the developing countries do not have sufficient oil reserves to cater to their energy requirement and depend upon oil producing countries. The perturbations in the crude oil price and adverse environmental impacts from fossil fuel usage are the biggest concern. Therefore, developing countries have started investing heavily in solar and wind power and are considering hydrogen as a future energy resource. However, to tap the potential of hydrogen as a fuel, an entirely new infrastructure will be needed for transporting, storing and dispensing it safely, which would be expensive. In the transportation sector, a liquid alternate to fossil fuels will be highly desirable as the existing infrastructure can be used with minor modifications. Among the possible liquid fuels, methanol is very promising. Methanol is a single carbon atom compound and can be produced from wide variety of sources such as natural gas, coal and biomass. The properties of methanol are conducive for use in gasoline engines since it has high octane number and flame speed. Other possible uses of methanol are: as a cooking fuel in rural areas and as a fuel for running the fuel cells. The present study reviews the limitations in the hydrogen economy and why moving toward methanol economy is more beneficial.
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References
Adinberg R, Epstein M, Karni J (2004) Solar gasification of biomass: a molten salt pyrolysis study. J Solar Energy Eng 126(3):850–857. https://doi.org/10.1115/1.1753577
Agrawal R, Singh NR, Ribeiro FH, Delgass WN (2007) Sustainable fuel for the transportation sector. Proc Natl Acad Sci USA 104(12):4828–4833. https://doi.org/10.1073/pnas.0609921104
Albarelli JQ, Onorati S, Caliandro P, Peduzzi E, Meireles MAA, Marechal F, Ensinas AV (2017) Multi-objective optimization of a sugarcane biorefinery for integrated ethanol and methanol production. Energy 138:1281–1290. https://doi.org/10.1016/j.energy.2015.06.104
Alves HJ, Bley Junior C, Niklevicz RR, Frigo EP, Frigo MS, Coimbra-Araújo CH (2013) Overview of hydrogen production technologies from biogas and the applications in fuel cells. Int J Hydrog Energy 38(13):5215–5225. https://doi.org/10.1016/J.IJHYDENE.2013.02.057
Anggarani R, Wibowo CS, Rulianto D (2014) Application of dimethyl ether as LPG substitution for household stove. Energy Proc 47:227–234. https://doi.org/10.1016/J.EGYPRO.2014.01.218
Asadullah M, Ito S, Kunimori K, Yamada M, Tomishige K (2002) Energy efficient production of hydrogen and syngas from biomass: development of low-temperature catalytic process for cellulose gasification. Environ Sci Technol 36(20):4476–4481. https://doi.org/10.1021/es020575r
Awad OI, Mamat R, Ibrahim TK, Hammid AT, Yusri IM, Hamidi MA, Humada AM, Yusop AF (2018) Overview of the oxygenated fuels in spark ignition engine: environmental and performance. Renew Sustain Energy Rev 91:394–408. https://doi.org/10.1016/J.RSER.2018.03.107
Baena-Moreno FM, Sebastia-Saez D, Pastor-Pérez L, Reina TR (2021) Analysis of the potential for biogas upgrading to syngas via catalytic reforming in the United Kingdom. Renew Sustain Energy Rev 144:110939. https://doi.org/10.1016/j.rser.2021.110939
Bakhtyari A, Haghbakhsh R, Rahimpour MR (2016) Investigation of thermally double coupled double membrane heat exchanger reactor to produce dimethyl ether and methyl formate. J Nat Gas Sci Eng 32:185–197. https://doi.org/10.1016/J.JNGSE.2016.04.002
Balachandra P, Reddy BS (2007)Hydrogen energy for indian transport sector: a well-to-wheel techno-economic and environmental feasibility analysis, Indira Gandhi Institute of Development Research, Mumbai (Vol. WP-2007-04)
Basu A, Wainwright J (2001) DME as a power generation fuel: performance in gas turbines. In: 4th international petroleum conference and exhibition, New Delhi, pp 9–12
Bawase M, Chaudhari S, Thipse SS (2021) Polymer/fuel interaction and properties of typical automotive fuel-system polymers exposed to methanol blended (M15) gasoline. Polym Test 97:107141. https://doi.org/10.1016/j.polymertesting.2021.107141
Bertau M, Wernicke HJ, Schmidt F (2014) Methanol utilisation technologies. In: Bertau M, Schmidt F, Offermanns H, Wernicke HJ, Plass L (eds) Methanol: the basic chemical and energy feedstock of the future. Springer, Berlin Heidelberg, pp 327–602
Blumberg T, Lee YD, Morosuk T, Tsatsaronis G (2019) Exergoenvironmental analysis of methanol production by steam reforming and autothermal reforming of natural gas. Energy 181:1273–1284. https://doi.org/10.1016/j.energy.2019.05.171
Boopathi D, Sonthalia A, Devanand S (2017) Experimental investigations on the effect of hydrogen induction on performance and emission behaviour of a single cylinder diesel engine fuelled with palm oil methyl ester and its blend with diesel. J Eng Sci Technol 12(7):1972–1987
Bossel U, Eliasson B, Taylor G (2003) The future of the hydrogen economy: bright or bleak? Retrieved from http://www.efcf.com/reports/. Accessed 28 Aug 2019
British Petroleum (2020) Statistical review of world energy. Retrieved from https://www.bp.com/content/dam/bp/business-sites/en/global/corporate/pdfs/energy-economics/statistical-review/bp-stats-review-2020-full-report.pdf. Accessed 24 Jan 2021
Bromberg L, Cheng W (2010) Methanol as an alternative transportation fuel in the US: options for sustainable and/or energysecure transportation. Retrieved from https://afdc.energy.gov/files/pdfs/mit_methanol_white_paper.pdf. Accessed 28 Aug 2019
Bromberg L, Cohn D (2010) Heavy duty vehicles using clean, high efficiency alcohol engines, PSFC/JA-10–43. Cambridge. https://dspace.mit.edu/bitstream/handle/1721.1/94385/10ja043_full.pdf?sequence=1. Accessed 30 Aug 2019
Canakci M, Sayin C, Ozsezen AN, Turkcan A (2009) Effect of injection pressure on the combustion, performance, and emission characteristics of a diesel engine fueled with methanol-blended diesel fuel. Energy Fuels 23(6):2908–2920. https://doi.org/10.1021/ef900060s
Cheng WH, Kung HH (1994) Methanol production and use. Marcel Dekker, New York
Chmielniak T, Sciazko M (2003) Co-gasification of biomass and coal for methanol synthesis. Appl Energy 74(3–4):393–403. https://doi.org/10.1016/S0306-2619(02)00184-8
Choi Y, Stenger HG (2002) Fuel cell grade hydrogen from methanol on a commercial Cu/ZnO/Al2O3 catalyst. Appl Catal B 38(4):259–269. https://doi.org/10.1016/S0926-3373(02)00054-1
Choudhary TV, Choudhary VR (2008) Energy-efficient syngas production through catalytic oxy-methane reforming reactions. Angew Chem Int Ed 47(10):1828–1847. https://doi.org/10.1002/anie.200701237
Clausen LR, Houbak N, Elmegaard B (2010) Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water. Energy 35(5):2338–2347. https://doi.org/10.1016/J.ENERGY.2010.02.034
Cruzan G (2009) Assessment of the cancer potential of methanol. Crit Rev Toxicol 39(4):347–363. https://doi.org/10.1080/10408440802475199
Dalai S, Vijayalakshmi S, Sharma P, Choo KY (2014) Magnesium and iron loaded hollow glass microspheres (HGMs) for hydrogen storage. Int J Hydrog Energy 39(29):16451–16458. https://doi.org/10.1016/J.IJHYDENE.2014.03.062
Demirbas A (2003) Biomass and wastes: upgrading alternative fuels. Energy Sources 25(4):317–329. https://doi.org/10.1080/00908310390142352
Demirbas A (2004) Current technologies for thermo-conversion of biomass into fuels and chemicals. Energy Sources 26(8):715–730. https://doi.org/10.1080/00908310490445562
DOE US (2018) Compare fuel cell vehicles. Retrieved from https://www.fueleconomy.gov/feg/fcv_sbs.shtml. Accessed 30 Nov 2019
Dolan GA (2002) In search of the perfect clean-fuel options. Hydrocarb Process 81(3):13–15
Donahue CJ, D’Amico T, Exline JA (2002) Synthesis and characterization of a gasoline oxygenate, ethyl tert-butyl ether. J Chem Educ 79(6):724. https://doi.org/10.1021/ed079p724
Dong Y, Borgwardt RH (1998) Biomass reactivity in gasification by the hynol process. Energy Fuels 12(3):479–484. https://doi.org/10.1021/ef970127i
Galindo CP, Badr O (2007) Renewable hydrogen utilisation for the production of methanol. Energy Convers Manag 48(2):519–527. https://doi.org/10.1016/j.enconman.2006.06.011
Geo VE, Nagarajan G, Nagalingam B (2008) Studies on dual fuel operation of rubber seed oil and its bio-diesel with hydrogen as the inducted fuel. Int J Hydrog Energy 33(21):6357–6367. https://doi.org/10.1016/j.ijhydene.2008.06.021
Goehna H, Koenig P (1994) Producing methanol from CO2. ChemTech 24(6):36
Goeppert A, Czaun M, Jones J-P, Surya Prakash GK, Olah GA (2014) Recycling of carbon dioxide to methanol and derived products—closing the loop. Chem Soc Rev 43(23):7995–8048. https://doi.org/10.1039/C4CS00122B
Goeppert A, Olah GA, Surya Prakash GK (2017) Toward a sustainable carbon cycle: the methanol economy In: Torok B, Dransfield T (eds) Green chemistry: an inclusive approach, Elsevier Inc., Amsterdam, pp 919–962 https://doi.org/10.1016/B978-0-12-809270-5.00031-5
Hamid H, Aliin MA (2004) Handbook of MTBE and other gasoline oxygenates. Marcel Dekker, New York
Hedegaard K, Thyo KA, Wenzel H (2008) Life cycle assessment of an advanced bioethanol technology in the perspective of constrained biomass availability. Environ Sci Technol 42(21):7992–7999. https://doi.org/10.1021/es800358d
Holladay JD, Hu J, King DL, Wang Y (2009) An overview of hydrogen production technologies. Catal Today 139(4):244–260. https://doi.org/10.1016/J.CATTOD.2008.08.039
Hsueh KL, Tsai LD, Lai CC, Peng YM (2012) Direct methanol fuel cells. In: Lui RS, Zhang L, Sun X, Liu H, Zhang J (eds), Electrochemical technologies for energy storage and conversion 1&2, Wiley-VCH GmbH, Weinheim, German
Intergovernment Panel on Climate Change (2007). AR4 Climate change 2007: Synthesis Report. Retrieved from https://www.ipcc.ch/site/assets/uploads/2018/02/ar4_syr_full_report.pdf. Accessed 28 Nov 2019
International Energy Agency (2018) World Energy Outlook. Retrieved from https://www.iea.org/reports/world-energy-outlook-2018. Accessed 28 Nov 2019
Jalali R, Rezaei M, Nematollahi B, Baghalha M (2020) Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane. Renew Energy 149:1053–1067. https://doi.org/10.1016/j.renene.2019.10.111
Ji C, Wang S (2009) Experimental study on combustion and emissions characteristics of a spark ignition engine fueled with gasoline—hydrogen blends. Energy Fuels 23(6):2930–2936. https://doi.org/10.1021/ef900209m
Ji C, Wang S (2011) Effect of hydrogen addition on lean burn performance of a spark-ignited gasoline engine at 800 rpm and low loads. Fuel 90(3):1301–1304. https://doi.org/10.1016/j.fuel.2010.11.014
Jiang Z, Pan Q, Xu J, Fang T (2014) Current situation and prospect of hydrogen storage technology with new organic liquid. Int J Hydrog Energy 39(30):17442–17451. https://doi.org/10.1016/j.ijhydene.2014.01.199
Joelsson JM, Gustavsson L (2008) CO2 emission and oil use reduction through black liquor gasification and energy efficiency in pulp and paper industry. Resour Conserv Recycl 52(5):747–763. https://doi.org/10.1016/j.resconrec.2007.11.002
Kauw M, Benders RMJ, Visser C (2015) Green methanol from hydrogen and carbon dioxide using geothermal energy and/or hydropower in Iceland or excess renewable electricity in Germany. Energy 90:208–217. https://doi.org/10.1016/j.energy.2015.06.002
Kvisle S, Fuglerud T, Kolboe S, Olsbye U, Lillerud KP, Vora BV (2008) Methanol-to-hydrocarbons. In: Ertl G, Knozinger H, Schuth F and Weitkamp J (eds) Handbook of heterogeneous catalysis, Wiley, New York, pp 2950–2965 https://doi.org/10.1002/9783527610044.hetcat0149
Lebaek J, Boegild Hansen J, Mogensen M (2011) GreenSynFuels. Economical and technological statement regarding integration and storage of renewable energy in the energy sector by production of green synthetic fuels for utilization in fuel cells. Retrieved from http://serenergy.com/wp-content/uploads/2015/11/GreenSynFuels_report_final.pdf. Accessed 21 Feb 2020
Levalley TL, Richard AR, Fan M (2014) The progress in water gas shift and steam reforming hydrogen production technologies—A review. Int J Hydrog Energy 39(30):16983–17000. https://doi.org/10.1016/j.ijhydene.2014.08.041
Li H, Hong H, Jin H, Cai R (2010) Analysis of a feasible polygeneration system for power and methanol production taking natural gas and biomass as materials. Appl Energy 87(9):2846–2853. https://doi.org/10.1016/J.APENERGY.2009.07.001
Li R, Wang Z, Ni P, Zhao Y, Li M, Li L (2014) Effects of cetane number improvers on the performance of diesel engine fuelled with methanol/biodiesel blend. Fuel 128:180–187. https://doi.org/10.1016/J.FUEL.2014.03.011
Lipman T (2011) An overview of hydrogen production and storage systems with renewable hydrogen case studies. Montpelier, Vermont. Retrieved from https://cdn.cesa.org/wp-content/uploads/CESA-Lipman-H2-prod-storage-050311.pdf. Accessed 21 Feb 2020
Liu F, Xuan G, Ai L, Liu Q, Yang L (2021) Key factors that affect catalytic activity of activated carbon-based catalyst in chemical looping methane decomposition for H2 production. Fuel Process Technol 215:106745. https://doi.org/10.1016/j.fuproc.2021.106745
Lu N, Gallucci F, Melchiori T, Xie D, Van Sint AM (2018) Modeling of autothermal reforming of methane in a fluidized bed reactor with perovskite membranes. Chem Eng Process Process Intensif 124:308–318. https://doi.org/10.1016/j.cep.2017.07.010
Lundgren J, Ekbom T, Hulteberg C, Larsson M, Grip CE, Nilsson L, Tuna P (2013) Methanol production from steel-work off-gases and biomass based synthesis gas. Appl Energy 112:431–439. https://doi.org/10.1016/J.APENERGY.2013.03.010
Manish S, Banerjee R (2008) Comparison of biohydrogen production processes. Int J Hydrog Energy 33(1):279–286. https://doi.org/10.1016/j.ijhydene.2007.07.026
Mario Toledo T, Karina Araus S, Diego Vasconcelo A (2015) Syngas production from coal in presence of steam using filtration combustion. Int J Hydrog Energy 40(19):6340–6345. https://doi.org/10.1016/j.ijhydene.2015.03.022
Melis A (2002) Green alga hydrogen production: progress, challenges and prospects. Int J Hydrog Energy 27(11–12):1217–1228. https://doi.org/10.1016/S0360-3199(02)00110-6
Methanol Institute (2004) Methanol Institute Comments to U.S. DOE On-Board Fuel Processing Review Panel
Methanol Institute (2013) Methanol safe handling manual. Retrieved from http://www.methanol.org/wp-content/uploads/2017/03/Safe-Handling-Manual.pdf. Accessed 16 May 2019
Nabil T (2019) Efficient use of oxy-hydrogen gas (HHO) in vehicle engines. J Eur Syst Autom 52(1):87–96. https://doi.org/10.18280/jesa.520112
Nieva MA, Villaverde MM, Monzón A, Garetto TF, Marchi AJ (2014) Steam-methane reforming at low temperature on nickel-based catalysts. Chem Eng J 235:158–166. https://doi.org/10.1016/j.cej.2013.09.030
Ogawa T, Inoue N, Shikada T, Ohno Y (2003) Direct dimethyl ether synthesis. J Nat Gas Chem 12:219–227
Ogden JM, Steinbugler MM, Kreutz TG (1999) A comparison of hydrogen, methanol and gasoline as fuels for fuel cell vehicles: implications for vehicle design and infrastructure development. J Power Sources 79(2):143–168. https://doi.org/10.1016/S0378-7753(99)00057-9
Olah G, Goeppert A, Surya Prakash G (2009) Beyond oil and gas: the methanol economy, 2nd edn. Wiley-VCH, Weinheim
Olah GA, Surya Prakash GK (2011) Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas, US Patent 7,906,559 B2. United States https://doi.org/10.1038/incomms1464
Poudyal RS, Tiwari I, Koirala AR et al (2015) Hydrogen production using photobiological methods. In: Subramani V, Basile A, & Veziroğlu TN (eds), Compendium of hydrogen energy: hydrogen production and purification, Woodhead Publishing, Oxford, pp 289–317 https://doi.org/10.1016/B978-1-78242-361-4.00010-8
Protti-Alvarez F (2017) Methanol-to-olefins drives methanol demand worldwide. Retrieved from https://chemweek.com/CW/Document/87374/IHS-Chemical-Methanol-to-olefins-drives-methanol-demand-worldwide, Acessed 9 Apr 2019
Qin YQ, Gong Y, Yuan YW, Yang ZG (2020) Failure analysis on leakage of hydrogen storage tank for vehicles occurring in oil circulation fatigue test. Eng Fail Anal 117:104830. https://doi.org/10.1016/j.engfailanal.2020.104830
Ribeiro AM, Santos JC, Rodrigues AE (2010) PSA design for stoichiometric adjustment of bio-syngas for methanol production and co-capture of carbon dioxide. Chem Eng J 163(3):355–363. https://doi.org/10.1016/J.CEJ.2010.08.015
Romm JJ (2004) The hype about hydrogen: fact and fiction in the race to save the climate. Island Press, Washington, DC
Rostrup-Nielsen J, Christiansen LJ (2011) Concepts in syngas manufacture, Imperial College Press, London
Rowlands WN, Masters A, Maschmeyer T (2008) The biorefinery-challenges, opportunities, and an Australian perspective. Bull Sci Technol Soc 28(2):149–158
Rozovskii AY, Lin GI (2003) Fundamentals of methanol synthesis and decomposition. Top Catal 22(3):137–150. https://doi.org/10.1023/A:1023555415577
Sarp S, Gonzalez Hernandez S, Chen C, Sheehan SW (2021) Alcohol production from carbon dioxide: methanol as a fuel and chemical feedstock. Joule 5(1):59–76. https://doi.org/10.1016/j.joule.2020.11.005
Satyapal S, Petrovic J, Read C, Thomas G, Ordaz G (2007) The U.S. department of energy’s national hydrogen storage project: progress towards meeting hydrogen-powered vehicle requirements. Catal Today 120(3–4):246–256. https://doi.org/10.1016/J.CATTOD.2006.09.022
Setthapun W, Bej SK, Thompson LT (2008) Carbide and nitride supported methanol steam reforming catalysts: parallel synthesis and high throughput screening. Top Catal 49(1):73. https://doi.org/10.1007/s11244-008-9070-7
Sharma N, Patel C, Tiwari N, Agarwal AK (2019) Experimental investigations of noise and vibration characteristics of gasoline-methanol blend fuelled gasoline direct injection engine and their relationship with combustion characteristics. Appl Therm Eng 158:113754. https://doi.org/10.1016/J.APPLTHERMALENG.2019.113754
Shulenberger AM, Jonsson FR, Ingolfsson O, Tran K-C (2007) Process for producing liquid fuel from carbon dioxide and water, US8198338B2. US Patent. Retrieved from https://patents.google.com/patent/US8198338B2/en
Simbeck DR, Chang E (2002) Hydrogen supply: cost estimate for hydrogen pathways—scoping snalysis: NREL Technical Report (Vol. NREL/SR-54) NREL/SR-540-32525
Singh S, Jain S, Venkateswaran PS, Tiwari AK, Nouni MR, Pandey JK, Goel S (2015) Hydrogen: a sustainable fuel for future of the transport sector. Renew Sustain Energy Rev 51:623–633
Subramani V, Sharma P, Zhang L, Liu K (2009) Catalytic steam reforming technology for the production of hydrogen and syngas. In: Liu K, Song C, Subramani V (eds) Hydrogen and syngas production and purification technologies, John Wiley & Sons, Inc. New Jersey
Tarhan C, Cil MA (2021) A study on hydrogen, the clean energy of the future: hydrogen storage methods. J Energy Storage 40:1026776. https://doi.org/10.1016/j.est.2021.102676
Thomas G, Feng B, Veeraragavan A, Cleary MJ, Drinnan N (2014) Emissions from DME combustion in diesel engines and their implications on meeting future emission norms: a review. Fuel Process Technol 119:286–304. https://doi.org/10.1016/j.fuproc.2013.10.018
Tremblay JF (2008) CO2 AS FEEDSTOCK Mitsui will make methanol from the greenhouse gas. Chem Eng News Arch 86(35):13. https://doi.org/10.1021/cen-v086n035.p013a
Turner J, Pearson RJ (2012) Renewable fuels—An automotive perspective. In: Sayigh A (ed) Comprehensive renewable energy. Elsevier, Amsterdam, pp 305–342
Verhelst S, Turner JW, Sileghem L, Vancoillie J (2019) Methanol as a fuel for internal combustion engines. Prog Energy Combust Sci 70:43–88. https://doi.org/10.1016/J.PECS.2018.10.001
Veziroglu TN, Sahin S (2008) 21st Century’s energy: hydrogen energy system. Energy Convers Manag 49(7):1820–1831. https://doi.org/10.1016/j.enconman.2007.08.015
Wang C, Li Y, Xu C, Badawy T, Sahu A, Jiang C (2019) Methanol as an octane booster for gasoline fuels. Fuel 248:76–84. https://doi.org/10.1016/J.FUEL.2019.02.128
Weiland P (2010) Biogas production: current state and perspectives. Appl Microbiol Biotechnol 85(4):849–860. https://doi.org/10.1007/s00253-009-2246-7
Williams RH, Liu G, Kreutz TG, Larson ED (2011) Coal and biomass to fuels and power. Annu Rev Chem Biomol Eng 2(1):529–553. https://doi.org/10.1146/annurev-chembioeng-061010-114126
Xu X, Xu H, Zheng J, Chen L, Wang J (2020) A high-efficiency liquid hydrogen storage system cooled by a fuel-cell-driven refrigerator for hydrogen combustion heat recovery. Energy Convers Manag 226:113496. https://doi.org/10.1016/j.enconman.2020.113496
Yao C, Pan W, Yao A (2017) Methanol fumigation in compression-ignition engines: a critical review of recent academic and technological developments. Fuel 209:713–732. https://doi.org/10.1016/J.FUEL.2017.08.038
Zhang F, Jiang J, Zhou Y et al (2017) A neat methanol fed passive DMFC with a new anode structure. Fuel Cells 17(3):315–320. https://doi.org/10.1002/fuce.201600221
Zhong J, Yang X, Wu Z, Liang B, Huang Y, Zhang T (2020) State of the art and perspectives in heterogeneous catalysis of CO2 hydrogenation to methanol. Chem Soc Rev 49(5):1385–1413. https://doi.org/10.1039/C9CS00614A
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Sonthalia, A., Kumar, N., Tomar, M. et al. Moving ahead from hydrogen to methanol economy: scope and challenges. Clean Techn Environ Policy 25, 551–575 (2023). https://doi.org/10.1007/s10098-021-02193-x
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DOI: https://doi.org/10.1007/s10098-021-02193-x