Abstract
A fully automated calorimeter has been designed and tested over the temperature range 200K–400K. The system may be used for measurements with an absolute accuracy of 0.2% of samples of approximate mass 50g and thermal capacity 15 JK−1. The temperature of the sample is determined by a quartz crystal thermometer of resolution 100 µK which is not in direct thermal contact with the sample. The performance of the system is illustrated by results obtained on high purity copper, distilled water and K2PbCu(NO2)6 which exhibits very sharp first order phase transitions at about 273.4K and 281.8K.
Similar content being viewed by others
References
Benson B B and Krause D Jr 1974Rev. Sci. Instrum. 45 1499
Brooks C R, Norem W E, Hendrix D E, Wright J W and Northcutt W G 1968J. Phys. Chem. Solids 29 565
Dockerty S M 1933Can. J. Res. 9 84
Garnier P R and Salamon M B 1971Phys. Rev. Lett. 27 1523
Giauque W F and Meads P F 1941J. Am. Chem. Soc. 63 1897
Harrowfield B V and Weber R 1972Phys. Lett. A38 27
Klinkhardt H 1927Ann. Phys. 84 182
Maier C G and Anderson C T 1934J. Chem. Phys. 2 513
Martin D L 1960Can. J. Phys. 38 17
Martin D L 1972Rev. Sci. Instrum. 43 1762
McCullough J P and Scott D W 1968Experimental Thermodynamics: Vol. I Calorimetry of nonreacting systems (London: Butterworths)
Osborne N S, Stimson H F and Ginnings D C 1939B. of S. J. Res. 23 238
Pawel R E and Stanbury E E 1965J. Phys. Chem. Solids 24 607
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Williams, I.S., Street, R. & Gopal, E.S.R. An automated high precision calorimeter for the temperature range 200K–400K. Part 1: Design and performance. Pramana - J Phys 11, 519–527 (1978). https://doi.org/10.1007/BF02848197
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02848197