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Nanoammonium salt: a novel and recyclable organocatalyst for one-pot three-component synthesis of 2-amino-3-cyano-4H-pyran derivatives

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Abstract

1,3-Propanediaminium methanesulfonate [(PDA)(MeSO3)] was synthesized as the first nanoaliphatic ammonium salt via a safe and simple chemical route in aqueous media. [(PDA)(MeSO3)] ammonium salt was characterized by XRD, TEM, SEM, EDS, DLS, AFM, 1H NMR, 13C NMR, FT-IR, TG, and elemental analysis. [(PDA)(MeSO3)] ammonium salt was efficiently applied as an eco-friendly and recyclable organocatalyst for the one-pot, three-component synthesis of 2-amino-3-cyano-4H-pyran derivatives. From an economical and environmental point of view, this novel catalyst has the merits of environmental friendliness, high yields, shorter reaction time, simple work-up, easy operation, the avoidance of the organic solvents, and inexpensive catalysts.

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Acknowledgements

We are thankful to Birjand University of Technology and University of Jiroft for their support on this work.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Mining, Civil and Chemical Engineering, Birjand University of Technology, Birjand, 97175/569, Iran

    Moones Honarmand

  2. Department of Chemistry, Faculty of Science, University of Jiroft, Jiroft, Iran

    Atena Naeimi & Mahboobeh Zahedifar

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  1. Moones Honarmand
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  2. Atena Naeimi
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Correspondence to Moones Honarmand.

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Honarmand, M., Naeimi, A. & Zahedifar, M. Nanoammonium salt: a novel and recyclable organocatalyst for one-pot three-component synthesis of 2-amino-3-cyano-4H-pyran derivatives. J IRAN CHEM SOC 14, 1875–1888 (2017). https://doi.org/10.1007/s13738-017-1127-8

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