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Polymeric composites based on natural rubber and hemp fibers

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Abstract

The purpose of this work is to present the results of preparing a polymeric composite with enhanced properties based on natural rubber and hemp. Amounts of 10 and 20 phr hemp were used to obtain the composites. The samples have been processed by sulfur vulcanization and characterized by several methods. The mechanical characteristics, gel fraction, cross-link density, rubber-fiber interactions and water uptake have been investigated depending on the hemp content. Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) techniques were also employed for characterization. The values of hardness, tensile strength and tearing strength have increased with the fiber content increasing due to the interaction between the fibers and natural rubber. Also, good adhesion between hemp fibers and rubber matrix was observed in SEM micrographs. The gel fraction value was over 95 % for all composites and increased with the increasing of hemp content. The cross-link density was determined on the basis of equilibrium solvent-swelling measurements applying the modified Flory–Rehner equation. It was observed that cross-linking density of composites increased slightly with the increase of amount of hemp but still was lower than that of the natural rubber without hemp. The extent of interaction between rubber and fiber was determined using the Kraus equation. Results of water absorption tests showed that water uptake increased with the increase of fiber content and temperature. The physical and chemical investigations have shown the reinforcing effect of hemp on sulfur vulcanized natural rubber, as well.

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Authors and Affiliations

  1. National Institute for Laser, Plasma and Radiation Physics, Electron Accelerators Laboratory, 409 Atomistilor St., 077125, Magurele, Romania

    Elena Manaila

  2. National R&D Institute for Textile and Leather, Leather and Footwear Research Institute, 93 Ion Minulescu St, Bucharest, Romania

    Maria Daniela Stelescu

  3. Department Of Scanning Electron Microscopy, Petru Poni Institute of Macromolecular Chemistry, Physical Characterization of Polymers, Aleea Grigore Ghica Voda, 41A, Iasi, 700487, Romania

    Florica Doroftei

Authors
  1. Elena Manaila
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  2. Maria Daniela Stelescu
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  3. Florica Doroftei
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Correspondence to Maria Daniela Stelescu.

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Manaila, E., Stelescu, M.D. & Doroftei, F. Polymeric composites based on natural rubber and hemp fibers. Iran Polym J 24, 135–148 (2015). https://doi.org/10.1007/s13726-015-0307-6

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