Abstract
Lead-free 0.98(Na0.5K0.5)NbO3-0.02(Ba0.5Ca0.5)TiO3 (0.98NKN-0.02BCT) ceramics were produced by using a conventional mixed oxide method with sintering temperature from 1080°C to 1120°C and their piezoelectric properties were investigated. The results indicate that the sintering temperature influences the electrical and the piezoelectric properties of 0.98NKN-0.02BCT ceramics. For the 0.98NKN-0.02BCT ceramics sintered from 1080°C to 1120°C, the piezoelectric constant d 33, electromechanical coupling factor k p , remnant polarization values P r and curie temperature T c increased with increase sintering temperature. However, for 0.98NKN-0.02BCT sintered above 1100°C, their values decreased. Piezoelectric properties of d 33 = 210 ρC/N and k p =46%, ferroelectric properties of P r = 16.2 µC/cm2 and dielectric constant ɛ r = 5159 were obtained for specimen sintered at 1100°C for 4 h. Therefore, the 0.98NKN-0.02BCT ceramics are excellent candidate materials for lead-free piezoelectric ceramics.
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References
P. Hansen, D. Hennings, and H. Schreinemacher, J. Am. Ceram. Soc. 81, 1369 (1998).
H. Kishi, N. Kohzu, and J. Sugino, J. Eur. Ceram. Soc. 20, 1997 (2000).
S. P. Nam, S. G. Lee, S. G. Bae, and Y. H. Lee, J. Elect. Eng. Tech. 2, 98 (2007).
S. Anwar, P. R. Sagdeo, and N. P. Lalla, Solid State Commun. 138, 331 (2006).
S. H. Lee, H. J. Kim, and Y. H. Lee, Electron. Mater. Lett. 8, 289 (2012).
B. J. Sung, E. W. Lee, and J. G. Lee, J. Elect. Eng. Tech. 3, 293 (2008).
I. J. Cho, K. S. Yun, and H. J. Nam, J. Elect. Eng. Tech. 6, 119 (2011).
M. Matsubara, T. Yamaguchi, K. Kikuta, and S. Hirano, Jpn. J. Appl. Phys. 43, 7159 (2004).
W. K. Jeung, S. M. Choi, and Y. J. Kim, J. Elect. Eng. Tech. 1, 263 (2006).
S. J. Zhang, R. Xia, T. R. Shrout, G. Z. Zang, and J. F. Wang, J. Appl. Phys. 100, 104108 (2006).
H. J. Bae, J. Koo, and J. P. Hong, J. Elect. Eng. Tech. 1, 120 (2006).
G. L. Yuan and S. W. Or, Appl. Phys. Lett. 88, 062905 (2006).
D. H. Lee, S. H. Lee, E. S. Choi, S. C. Lee, and Y. H. Lee, Electron. Mater. Lett. 8, 147 (2012).
M. S. Kim, Y. M. Jeon, Y. M. Im, Y. H. Lee, and T. H. Nam, Trans. Elect. Electron. Mater. 12, 20 (2011).
S. H. Lee, S. G. Lee, and Y. H. Lee, Nanos. Res. Lett. 7, 15 (2012).
H. J. Noh, S. G. Lee, and S. P. Nam, J. Elect. Eng. Tech. 4, 527 (2009).
H. T. Li, B. P. Zhang, P. P. Shang, Y. Fan, and Q. Zhang, J. Am. Ceram. Soc. 94, 628 (2011).
S. H. Lee, S. D. Baek, H. J. Kim, S. G. Lee, and Y. H. Lee, Electron. Mater. Lett. 8, 147 (2012).
S. H. Lee, J. Elect. Eng. Tech. 2, 102 (2007).
V. V. Thang, I. S. Kim, S. J. Jeong, M. S. Kim, and J. S. Song, J. Elect. Eng. Tech. 6, 671 (2011).
K. S. Chang, S. M. Kang, K. G. Park, S. H. Shin, H. S. Kim, and H. S. Kim, J. Elect. Eng. Tech. 7, 75 (2012).
K. A. Fonteyn, A. Belahcen, P. Rasilo, R. Kouhia, and A. Arkkio, J. Elect. Eng. Tech. 7, 336 (2012).
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Kim, SH., Lee, SH., Kim, HJ. et al. Effect of sintering temperatures on the piezoelectric and dielectric properties of 0.98(Na0.5K0.5)NbO3-0.02(Ba0.5Ca0.5)TiO3 ceramics. Electron. Mater. Lett. 9, 237–240 (2013). https://doi.org/10.1007/s13391-012-2160-5
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DOI: https://doi.org/10.1007/s13391-012-2160-5