Skip to main content
Log in

Control of Slag Formation, Foaming, Slopping, and Chaos in BOF

  • Technical Paper
  • Published:
Transactions of the Indian Institute of Metals Aims and scope Submit manuscript

Abstract

Decarburization, slag formation, foaming, and slopping in basic oxygen furnace (BOF) can now be partly understood, and to some extent predicted with the help of several on-line measurements and on-line control models. The principal reaction in BOF is decarburization. The bulk of the decarburization takes place in the turbulent region of jet impact irrespective of the fact whether the slag is solid, liquid or foamy. Metal droplets are ejected from the jet impact zone but it is difficult to distinguish the decarburization occurring in the bulk metal from that occurring in the droplets. Slag in BOF is heterogeneous and always contains some entrained gas bubbles and solid material (either un-dissolved or precipitated). At no stage the slag is 100 % liquid. A significant part of the metal droplets fall back and travel through the semi liquid slag. Through this mechanism the droplets can cause slag foaming and slopping in the BOF. Phenomenon of slag foaming and slopping can be monitored and controlled by following, dynamically, the audio signals, gas flow rate and composition, by tracking ‘Chaos’ in chemical reactions, by manipulating the chaotic attractors, and by monitoring the lance water temperature and weight. Relative stability potential (RSP) diagrams are found to be a good indicator of the dynamics of process inside the BOF and help in advance prediction of the impending chaos.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Similar content being viewed by others

References

  1. “Beta Supersonic blow control for oxygen steelmaking”, www.hindu.com/2011/03/stories/201103035373020.htm; N P Gandhi Memorial Lecture: Chaos in steelmaking by Brahma Deo, Metal News 13, p. 11.

    Google Scholar 

  2. Deo B, Karamchetty A, Paul A, Singh P K, and Chhabra R P, ISIJ Int 36 (1996) 658.

    Article  CAS  Google Scholar 

  3. Brooks G A, Rhamdhani M A, Coley K S, Metall Mater Trans 40 B (2009) 353.

    Google Scholar 

  4. Malathi M, Shukla A K, Singh N, Deo B, Boom R, in This Paper was presented at the international conference AIST TECH-2007, May 7–10, 2007, Indianapolis Convention Center, Indianapolis, USA (2007).

  5. Deo B, and Balakrishnan V, AIST Tech Iron Steel Technol Conf Proc 1 (2009) 801.

  6. Svyazhin A, Scheller P, in Proceedings ICS 2012, Dresden, Germany (2012).

  7. Deo B, and Boom R, Fundamentals of Steelmaking Metallurgy, Prentice Hall, Hertfordshire (1993).

    Google Scholar 

  8. Shukla A K, Dissolution of Steel Scrap in Molten Metal During Steelmaking, Ph.D. Theis, IIT Kanpur (2011).

  9. Mohan A, Gopikrishna C, Sateesh Kumar A, Deo B, in 2nd International Congress on Science and Technology of Steelmaking, April 10–11 2001 University of Wales, Swansea (2001).

  10. Min D J, and Fruehan R J, Metall Mater Trans 23 B (1992), 37.

    Google Scholar 

  11. Paul A, Deo B, and Sathyamurthi N, Steel Res 65 (1994) 414.

    CAS  Google Scholar 

  12. Deo B, Shukla A K, Boom R, in The fourth International Congress on the Science and Technology of Steelmaking; October 6–8, Gifu, Japan, (2008) p. 598.

  13. Deo B, Ranjan P, and Kumar A, Steel Res 58 (1987), 427.

    CAS  Google Scholar 

  14. Boom R, Deo B, van der Knoop W, Mensonides F, and van Unen G, in Proceedings of Third International Conference on Metallurgical Slags and Fluxes, University of Strathclyde, 27–29 June 1988, Published by The Institute of Metals, London, (1988) p. 273.

  15. Deo B, Halder J, Gupta N, Fuloria D, Kumar, Das D, Das S, Shankar A, Basu S, Jha R K, and Sarkar A, Proc ASEA Steel Int, April 9–12 2003, (2003), p. 2.4.1.

  16. van Unen G, Snoeijer A B, van der Knoop W, Deo B, and Boom R, in 3rd International Oxygen Steelmaking Congress 15–17 May, 1990, Published by The Institute of Metals, London, (1990), p. 140.

  17. van der Knoop W, Deo B, Snoeijer A B, van Unen G, and Boom R, in, 4th International Conference on molten slags and fluxes, 1992, Sendai, Proceedings on Transaction, Iron and Steel Institute of Japan, Tokyo, Japan, (1992), p. 302.

  18. Ban-Ya S, ISIJ Int 33 (1993) 11.

    Article  Google Scholar 

  19. Kapoor M L, and Frohberg M G, in Proceedings on International Symposium. In Chemical Metallurgy if iron and Steel, (1973), p. 17, p. 35.

  20. Deo B, and Shukla A, in Proceedings ICS 2012, Oct. 1–3, Dresden, Germany (2012).

  21. Brooks G A, Dogan N, Alam M, Naser J, Rhamdhani M A, Developments in the modeling of oxygen steelmaking, ro.uow.edu.au/cgi/viewcontent.cgi?article=2675&context.

  22. Epstein IR, Showalter K, J Chem Phys 100 (1996) 13132.

    CAS  Google Scholar 

  23. Gyrogyi L, Field R J, Lett Nat 355 (1992) 808.

    Article  Google Scholar 

Download references

Acknowledgments

One of the authors (BD) would like to specially thank Mr. Willem van der Knoop of TATA Steel Ijmuiden, and also other researchers for the exchange of knowledge and interesting technical discussions that took place over a long period of nearly 25 years during the colloborative research work at Hoogovens Ijmuiden, CORUS Ijmuiden, TATA Corus, TATA Steel Ijmuiden, TATA Steel Jamshedpur, and Visakhapatnam Steel Plant Visakhapatnam.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Brahma Deo.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Deo, B., Overbosch, A., Snoeijer, B. et al. Control of Slag Formation, Foaming, Slopping, and Chaos in BOF. Trans Indian Inst Met 66, 543–554 (2013). https://doi.org/10.1007/s12666-013-0306-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12666-013-0306-2

Keywords

Navigation