Abstract
Thermophysical properties (such as specific heat capacity, thermal conductivity, and thermal diffusivity) of coal measure strata at a wide range of temperatures are important to coal in situ gasification with environmental treatments. These thermophysical properties have been investigated for different rocks but few are available for the rocks from coal measure strata. This study experimentally investigated the specific heat capacity and the thermal conductivity of six types of rock samples from coal measure strata, including sandy mudstone 1 and 2, mudstone, siltstone, coarse sandstone, and fine sandstone when the testing temperature varies from 100 to 1000 °C. Two critical temperatures, 500 °C for sandy mudstone 1 and 400 °C for the other five types of rock samples, were observed. The test results show that both the specific heat capacity and the thermal conductivity decrease with the increase of temperature when the testing temperature is below the critical temperature. When the testing temperature is over the critical temperature, the specific heat capacity is almost constant and the thermal conductivity still continues decreasing. These test results further show that the classical physics theory can well predict the experimental data for both specific heat capacity and thermal conductivity of six rocks.
Similar content being viewed by others
References
Abdulagatova Z, Abdulagatov I, Emirov V (2009) Effect of temperature and pressure on the thermal conductivity of sandstone. Int J Rock Mech Min Sci 46(6):1055–1071
Alishaev MG, Abdulagatov IM, Abdulagatova ZZ (2012) Effective thermal conductivity of fluid-saturated rocks: experiment and modeling. Eng Geol 135–136:24–39
Buttner R, Zimanowski B, Blumm J, Hagemann L (1998) Thermal conductivity of a volcanic rock material (olivine–melilitite) in the temperature range between 288 and 1470 K. J Volcanol Geotherm Res 80(3–4):293–302
Chen YF, Li DQ, Jiang QH, Zhou CB (2012) Micromechanical analysis of anisotropic damage and its influence on effective thermal conductivity in brittle rocks. Int J Rock Mech Min Sci 50:102–116
Cho WJ, Kwon S, Choi JW (2009) The thermal conductivity for granite with various water contents. Eng Geol 107(3–4):167–171
Clauser C, Huenges E (1995) Thermal conductivity of rocks and minerals. In: Ahrens TJ (ed) Rock physics and phase relations––a handbook of physical constants, vol 3. AGU Reference Shelf, American Geophysical Union, Washington, pp 105–126
Duchkov AD, Sokolova LS, Rodyakin SV, Chernysh PS (2014) Thermal conductivity of the sedimentary-cover rocks of the West Siberian Plate in relation to their humidity and porosity. Russ Geol Geophys 55(5):784–792
El Sayed AM (2011) Thermophysical study of sandstone reservoir rocks. J Petrol Sci Eng 76(3–4):138–147
Fuchs S, Förster A (2014) Well-log based prediction of thermal conductivity of sedimentary successions: a case study from the North German Basin. Geophys J Int 196(1):291–311
Fuchs S, Schütz F, Förster HJ, Förster A (2013) Evaluation of common mixing models for calculating bulk thermal conductivity of sedimentary rocks: correction charts and new conversion equations. Geothermics 47:40–52
Görgülü K, Durutürk YS, Demirci A, Poyraz B (2008) Influences of uniaxial stress and moisture content on the thermal conductivity of rocks. Int J Rock Mech Min Sci 45(8):1439–1445
Goto S, Matsubayashi O (2009) Relations between the thermal properties and porosity of sediments in the eastern flank of the Juan de Fuca Ridge. Earth Planets Space 61(7):863–870
Gruescu C, Giraud A, Homand F, Kondo D, Do DP (2007) Effective thermal conductivity of partially saturated porous rocks. Int J Solids Struct 44(3–4):811–833
Hall K (2011) Natural building stone composed of light-transmissive minerals: impacts on thermal gradients, weathering and microbial colonization; a preliminary study, tentative interpretations, and future directions. Environ Earth Sci 62(2):289–297
Huang K (original), Han RQ (adapted) (1999) Solid state physics. Higher Education Press, Beijing
Jobmann M, Buntebarth G (2009) Influence of graphite and quartz addition on the thermo–physical properties of bentonite for sealing heat-generating radioactive waste. Appl Clay Sci 44(3–4):206–210
Kitano K, Shin K, Kinoshita N, Okuno T (1988) Mechanical properties, thermal characteristics and permeability of rock under high temperature. J Jpn Soc Eng Geol 29(3):36–47
Kreynin EV (2012) An analysis of new generation coal gasification projects. Int J Min Sci Technol 22(4):509–515
Leth-Miller R, Jensen AD, Glarborg P, Jensena LM, Hansena PB, Jørgensenb SB (2003) Experimental investigation and modelling of heat capacity, heat of fusion and melting interval of rocks. Thermochim Acta 406(1–2):129–142
Liu SW, Feng CG, Wang LS, Li C (2011) Measurement and analysis of thermal conductivity of rocks in the Tarim Basin, Northwest China. Acta Geologica Sinica (English Edition) 85(3):598–609
Maqsood A, Kamran K (2005) Thermophysical properties of porous sandstones: measurements and comparative study of some representative thermal conductivity models. Int J Thermophys 26(5):1617–1632
Maqsood A, Rehman MA, Gul IH (2003) Chemical composition, density, specific gravity, apparent porosity, and thermal transport properties of volcanic rocks in the temperature range 253 to 333 K. J Chem Eng Data 48:1310–1314
Miao S, Li H, Chen G (2014) Temperature dependence of thermal diffusivity, specific heat capacity, and thermal conductivity for several types of rocks. J Therm Anal Calorim 115(2):1057–1063
Noack V, Scheck-Wenderoth M, Cacace M (2012) Sensitivity of 3D thermal models to the choice of boundary conditions and thermal properties: a case study for the area of Brandenburg (NE German Basin). Environ Earth Sci 67(6):1695–1711
Norden B, Förster A, Behrends K, Krause K, Stecken L, Meyer R (2012) Geological 3-D model of the larger Altensalzwedel area, Germany, for temperature prognosis and reservoir simulation. Environ Earth Sci 67(2):511–526
Popov Y, Tertychnyi V, Romushkevich R, Korobkov D, Pohl J (2003) Interrelations between thermal conductivity and other physical properties of rocks: experimental data. In: Thermo-hydro-mechanical coupling in fractured rock. Springer, p 1137–1161
Popov Y, Romushkevich R, Korobkov D, Mayr S, Bayuk I, Burkhardt H, Wilhelm H (2011) Thermal properties of rocks of the borehole Yaxcopoil-1 (Impact Crater Chicxulub, Mexico). Geophys J Int 184(2):729–745
Ray L, Förster HJ, Schilling FR, Forster A (2006) Thermal diffusivity of felsic to mafic granulites at elevated temperatures. Earth Planet Sci Lett 251(3–4):241–253
Rezaei HR, Gupta RP, Bryant GW, Hart JT, Liu GS, Bailey CW, Wall TF, Miyamae S, Makino K, Endo Y (2000) Thermal conductivity of coal ash and slags and models used. Fuel 79:1697–1710
Roufosse MC, Jeanloz R (1983) Thermal conductivity of minerals at high pressure: the effect of phase transitions. J Geophys Res Solid Earth 88(B9):7399–7409
Schärli U, Rybach L (2001) Determination of specific heat capacity on rock fragments. Geothermics 30(1):93–110
Shabbir G, Maqsood A, Majid CA (2000) Thermophysical properties of consolidated porous rocks. J Phys D-Appl Phys 33:658–661
Sipio ED, Chiesa S, Destro E, Galgaro A, Giaretta A, Gola G, Manzella A (2013) Rock thermal conductivity as key parameter for geothermal numerical models. Energy Procedia 40:87–94
Teklu H, Clinton CL, James EB (2007) Determination of heat capacity of Yucca Mountain stratigraphic layers. Int J Rock Mech Min Sci 44(7):1022–1034
Vosteen HD, Schellschmidt R (2003) Influence of temperature on thermal conductivity, thermal capacity and thermal diffusivity for different types of rock. Phys Chem Earth Parts A/B/C 28(9–11):499–509
Wai RS, Lo KY, Rowe RK (1982) Thermal stress analysis in rocks with nonlinear properties. Int J Rock Mech Min Sci Geomech Abstr 19(5):211–220
Wall TF, Mai-Viet T, Becker HB, Gupta RP (1979) Fireside deposits and their effect on heat transfer in p.f. boilers: the emissivity and thermal conductivity of deposits and their components. In: Proceedings pulverised coal firing––the effects of mineral matter. University of Newcastle, pp L8.1–L8.16
Wan ZJ (2009) Theory of the thermomechanical coupling of heterogeneous rock and the stability of underground coal gasification channel. China University of Mining and Technology Press, Xuzhou
Wang DY, Lu XC, Song YC, Shao R, Qi T (2010) Influence of the temperature dependence of thermal parameters of heat conduction models on the reconstruction of thermal history of igneous-intrusion-bearing basins. Comput Geosci 36(10):1339–1344
Whittington AG, Hofmeister AM, Nabelek PI (2009) Temperature-dependent thermal diffusivity of the Earth’s crust and implications for magmatism. Nature 458:319–321
Acknowledgments
The authors would like to thank Dr Yang Ju, Dr. Xianbiao Mao, and Dr Ruidong Peng for their valuable time, help and suggestions. The financial supports of the National Natural Science Foundation of China (Grant No. 51204159), the National Basic Research Program of China (Grant No. 2011CB201201), the National Science Fund for Distinguished Young Scholars (Grant No. 51125017), the National Natural Science Foundation of China (Grant No. 51104128) and the Fundamental Research Funds for the Central Universities (Grant No. 2011QNB05) are gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tang, F., Wang, L., Lu, Y. et al. Thermophysical properties of coal measure strata under high temperature. Environ Earth Sci 73, 6009–6018 (2015). https://doi.org/10.1007/s12665-015-4364-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12665-015-4364-0