Abstract
The thermo-physical properties for four rock types (granite, granodiorite, gabbro, and garnet amphibolite) from room temperature to 1,173 K were investigated. Thermal diffusivity and specific heat capacity were measured using the laser-flash technique and heat flux differential scanning calorimetry, respectively. Combined with the density data, rock thermal conductivities were calculated. Rock thermal diffusivity and conductivity decrease as the temperature increases and approach a constant value at high temperatures. At room temperature, the measured thermal conductivity is consistently near or lower than the calculated conductivity using the mineral series model, which suggests that real thermal conduction is more complicated than is depicted in the model. Therefore, in situ measurement remains the best method for accurately obtaining thermal conductivity for rocks.
Similar content being viewed by others
References
Sass JH, Lachenbruch AH, Munroe RJ. Thermal conductivity of rocks from measurements on fragments and its application to heat-flow determinations. J Geophys Res. 1971;76(14):3391–401. doi:10.1029/JB076i014p03391.
van den Berg AP, Yuen DA. Delayed cooling of the earth’s mantle due to variable thermal conductivity and the formation of a low conductivity zone. Earth Planet Sci Lett. 2002;199(3–4):403–13.
Birch F, Clark H. The thermal conductivity of rocks and its dependence upon temperature and composition. Am J Sci. 1940;238(9):613–35.
Hofmeister AM. Thermal diffusivity of garnets at high temperature. Phys Chem Miner. 2006;33(1):45–62.
Ohta K, Yagi T, Taketoshi N, Hirose K, Komabayashi T, Baba T, et al. Lattice thermal conductivity of MgSiO3 perovskite and post-perovskite at the core-mantle boundary. Earth Planet Sci Lett. 2012;349–350:109–15.
Pohlmann C, Hutsch T, Röntzsch L, Weißgärber T, Kieback B. Novel approach for thermal diffusivity measurements in inert atmosphere using the flash method. J Therm Anal Calorim. 2013. doi:10.1007/s10973-013-3048-9.
Hofmeister AM. Mantle values of thermal conductivity and the geotherm from phonon lifetimes. Science. 1999;283(5408):1699–706.
Chapman DS. Thermal gradients in the continental crust. Geol Soc Spec Publ. 1986;24(1):63–70.
Parker WJ, Jenkins RJ, Abbott GL, Butler CP. Flash method of determining thermal diffusivity, heat capacity, and thermal conductivity. J Appl Phys. 1961;32(9):1679–84.
Branlund JM, Hofmeister AM. Thermal diffusivity of quartz to 1,000 degrees C: effects of impurities and the alpha-beta phase transition. Phys Chem Miner. 2007;34(8):581–95.
Pertermann M, Whittington AG, Hofmeister AM, Spera FJ, Zayak J. Transport properties of low-sanidine single-crystals, glasses and melts at high temperature. Contrib Mineral Petrol. 2008;155(6):689–702.
Hofmeister A, Whittington A, Pertermann M. Transport properties of high albite crystals, near-endmember feldspar and pyroxene glasses, and their melts to high temperature. Contrib Mineral Petrol. 2009;158(3):381–400.
Hofmeister AM, Pertermann M. Thermal diffusivity of clinopyroxenes at elevated temperature. Eur J Mineral. 2008;20(4):537–49.
Pertermann M, Hofmeister AM. Thermal diffusivity of olivine-group minerals at high temperature. Am Mineral. 2006;91(11–12):1747–60.
Whittington AG, Hofmeister AM, Nabelek PI. Temperature-dependent thermal diffusivity of the earth’s crust and implications for magmatism. Nature. 2009;458(7236):319–21.
Nabelek PI, Whittington AG, Hofmeister AM. Strain heating as a mechanism for partial melting and ultrahigh temperature metamorphism in convergent orogens: implications of temperature-dependent thermal diffusivity and rheology. J Geophys Res. 2010;115(B12):B12417. doi:10.1029/2010jb007727.
Romine W, Whittington A, Nabelek P, Hofmeister A. Thermal diffusivity of rhyolitic glasses and melts: effects of temperature, crystals and dissolved water. Bull Volcanol. 2012;74(10):2273–87.
Nabelek PI, Hofmeister AM, Whittington AG. The influence of temperature-dependent thermal diffusivity on the conductive cooling rates of plutons and temperature-time paths in contact aureoles. Earth Planet Sci Lett. 2012;317:157–64.
Merriman JD, Whittington AG, Hofmeister AM, Nabelek PI, Benn K. Thermal transport properties of major archean rock types to high temperature and implications for cratonic geotherms. Precambrian Res. 2013;233:358–72.
Rutkowski P, Piekarczyk W, Stobierski L, Górny G. Anisotropy of elastic properties and thermal conductivity of Al2O3/h-BN composites. J Therm Anal Calorim. 2013. doi:10.1007/s10973-013-3246-5.
Li S, Wang S, Li X, Li Y, Liu S, Coulson IM. A new method for the measurement of meteorite bulk volume via ideal gas pycnometry. J Geophys Res. 2012;117(E10):E10001. doi:10.1029/2012je004202.
Cha J, Seo J, Kim S. Building materials thermal conductivity measurement and correlation with heat flow meter, laser flash analysis and TCi. J Therm Anal Calorim. 2012;109(1):295–300.
Parameshwaran R, Jayavel R, Kalaiselvam S. Study on thermal properties of organic ester phase-change material embedded with silver nanoparticles. J Therm Anal Calorim. 2013. doi:10.1007/s10973-013-3064-9.
Hirono T, Hamada Y. Specific heat capacity and thermal diffusivity and their temperature dependencies in a rock sample from adjacent to the Taiwan Chelungpu fault. J Geophys Res. 2010;115(B5):B05313. doi:10.1029/2009jb006816.
Mojumdar SC, Sain M, Prasad RC, Sun L, Venart JES. Selected thermoanalytical methods and their applications from medicine to construction. J Therm Anal Calorim. 2007;90(3):653–62.
Saxena SK. Earth mineralogical model: Gibbs free energy minimization computation in the system MgO–FeO–SiO2. Geochim Cosmochim Acta. 1996;60(13):2379–95.
Seipold U. Temperature dependence of thermal transport properties of crystalline rocks—a general law. Tectonophysics. 1998;291(1–4):161–71.
Wang J, Carson JK, North MF, Cleland DJ. A new structural model of effective thermal conductivity for heterogeneous materials with co-continuous phases. Int J Heat Mass Transf. 2008;51(9–10):2389–97.
Branlund JM, Hofmeister AM. Heat transfer in plagioclase feldspars. Am Mineral. 2012;97(7):1145–54.
Clauser C, Huenges E. Thermal conductivity of rocks and minerals. Rock phys phase relat. 1995;3:105–26.
Kukkonen IT. Thermal properties of rocks at the investigation sites: measured and calculated thermal conductivity, specific heat capacity and thermal diffusivity. Helsinki, Finland. Geological Survey of Finland. 1998. 9798/97/AJH.
Christensen NI, Mooney WD. Seismic velocity structure and composition of the continental crust: a global view. J Geophys Res. 1995;100(B6):9761–88. doi:10.1029/95JB00259.
Acknowledgements
The study was performed under Project supported by “135” Program of Chinese Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Miao, S.Q., Li, H.P. & Chen, G. Temperature dependence of thermal diffusivity, specific heat capacity, and thermal conductivity for several types of rocks. J Therm Anal Calorim 115, 1057–1063 (2014). https://doi.org/10.1007/s10973-013-3427-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-013-3427-2