Skip to main content
Log in

The Effect of Different Fly Ash and Vanadium Carbide Contents on the Various Properties of Hypereutectic Al-Si Alloys-Based Hybrid Nanocomposites

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

In the current work, a hybrid nanocomposite Al-Si matrix was fabricated using the powder metallurgy method. Due to their superior mechanical strength, formability, and durability, aluminum composite matrices have considered attractive materials for structural and advanced applications. The incorporation of fly ash (FA) as one of the cheapest and lowest density reinforcement available during the combustion process with high-density ceramic particles such as vanadium carbide (VC) has significant benefits in the production process of such composites. The hybridization of VC and FA nanoparticles with different weight percentages were used to reinforce the Al-Si matrix under various sintering conditions. A scanning electron microscopy (SEM) and diffraction particle size analyzer were utilized to examine the microstructure of the prepared powder and particle size. In addition to the mechanical and physical properties, the wear and corrosion resistance were investigated for the fabricated samples. The results revealed that the addition of 10 wt.% VC and 10 wt.% FA nanoparticles caused a decrease in the Al-Si alloy particle sizes up to 47.8 nm and act as a barrier for dislocation movement. Also, the microhardness, yield strength, and ultimate copressive strength were enhanced by 75, 42 and 38%, respectively. Moreover, there was an increase of about 25% in the ultrasonic longitudinal and shear velocities, thus showing a significant improvement in the elastic moduli group of about 50%. Finally, the addition of VC and FA particles significantly affected the wear and corrosion resistance; hence, they increased by 40 and 67%, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Zawrah MF, El-Meligy WM, Saudi HA, Ramadan S, Taha MA (2021) Mechanical and electrical properties of nano Al-matrix composites reinforced with SiC and prepared by powder metallurgy. Biointerface Res Appl Chem 12:2068–2083

    Article  Google Scholar 

  2. Taha MA, Youness RA, Ibrahim MA (2021) Evolution of the physical, mechanical and electrical properties of SiC-reinforced Al 6061 nanocomposites prepared by stir cast method. Biointerface Res Appl 11(2):8946–8956

    CAS  Google Scholar 

  3. Tang S, Shao S, Liu H, Jiang F, Fu D, Zhang H, Teng J (2021) Microstructure and mechanical behaviors of 6061 Al matrix hybrid composites reinforced with SiC and stainless steel particles. Mater Sci Eng 804:140732

    Article  CAS  Google Scholar 

  4. Zawrah MA, Mostafa H, Taha MA (2018) Effect of SiC content on microstructure, mechanical and electrical properties of sintered Al-20Si-xSiC nanocomposites fabricated by mechanical alloying. Mater Res Express 61:25014

    Google Scholar 

  5. Gökçe A, Fındık F, Kurt AO (2013) Effects of mg content on aging behavior of Al4CuXMg PM alloy. Mater Des 46:524–531

    Article  Google Scholar 

  6. Gökçe A, Fındık F, Kurt AO (2011) Microstructural examination and properties of premixed Al–cu–mg powder metallurgy alloy. Mater Charact 62:730–735

    Article  Google Scholar 

  7. Ahamad N, Mohammad A, Rinawa ML, Sadasivuni K.K, Gupta P (2021) Correlation of structural andmechanical properties for Al-Al2O3-SiC hybrid metal matrix composites, J Comp Mater 1–14

  8. Kareem A, Qudeiri JA, Abdudeen A, Ahammed T, Ziout A (2021) A review on AA 6061 metal matrix composites produced by stir casting. Mater 14(1):1–12

    Article  Google Scholar 

  9. John CF, Paul RC, Singh SCE, Jacobjose J, Ramkumar T, Hikku GS, Sharma RK, Sengottuvel P (2018) Corrosion behavior of ZrC particles reinforcement with Al-12Si composites by weight loss method using acidic media. B Pol Acad Sci-Tech 66:9–16

    CAS  Google Scholar 

  10. Nataraj G, Sudhakar A, Pruthviraj RD, Ramesh S (2015) Weight loss corrosion studies of aluminium-7075 alloy reinforced with silicon carbide particulates composites in acid chloride medium. Int J Eng Sci Res Technol 4:538–541

    Google Scholar 

  11. Bai Q, Zhang L, Ke L, Zhu P, Ma Y, Xi S, Zhou B (2020) The effects of surface chemical treatment on the corrosion behavior of an Al-B4C metal matrix nanocomposite in boric acid solutions at different temperatures, Mat Today In press

  12. Sherif EM, Abdo HS, Khalil KA, Nabawy AM (2016) Effect of titanium carbide content on the corrosion behavior of Al-TiC composites processed by high energy ball mill. Int J Electrochem Sci 11:4632–4644

    Article  CAS  Google Scholar 

  13. Rohatgi PK, Daoud A, Schultz BF, Puri T (2009) Microstructure and mechanical behavior of die casting AZ91D-Fly ash cenosphere composites. Compos Part Appl Sci Manuf 40:883–896

    Article  Google Scholar 

  14. Raju FA, Kumar MD (2017) Micro structure and mechanical behavior of AL-7075-T6 and fly ash metal matrix composite produced by stir casting process. Int J Theor Appl Mechan 12:365–374

    Google Scholar 

  15. Soy U, Demir A, Findik D (2011) Friction and wear behaviors of Al-SiC-B4C composites produced by pressure infiltration method. Ind Lubr Tribol 63:387–393

    Article  Google Scholar 

  16. Shanmughasundaram P (2014) Investigation on the wear behaviour of eutectic Al-Si alloy– Al2O3-graphite composites fabricated through squeeze casting. Mater Res 17:940–946

    Article  Google Scholar 

  17. Baradeswaran A, Vettivel SC, Perumal AE, Selvakumar N, Issac RF (2014) Experimental investigation on mechanical behaviour, modelling and optimization of wear parameters of B4C and graphite reinforced aluminium hybrid composites. Mater Des 63:620–632

    Article  CAS  Google Scholar 

  18. Ashrafi N, Azmah Hanim MA, Sarraf M, Sulaiman S, Hong TS (2020) Microstructural, tribology and corrosion properties of optimized Fe3O4-SiC reinforced aluminum matrix hybrid nano filler nanocomposite fabricated through powder metallurgy method. Mater 13:1–22

    Google Scholar 

  19. AbuShanab WS, Moustafa EB, Taha MA, Youness RA (2020) Synthesis and structural properties characterization of titania/ zirconia/calcium silicate nanocomposites for biomedical applications. Appl Phys A Mater Sci Process 787:1–12

    Google Scholar 

  20. Abulyazied D , Alturki A, Youness R, Abomostafa H (2021) Synthesis, structural and biomedical characterization of hydroxyapatite/borosilicatebioactive glass nanocomposites, J Inorg Organomet P , (In press)

  21. Taha MA, Youness RA, Zawrah MF (2020) Phase composition, sinterability and bioactivity of amorphous nano-CaOSiO2-CuO powder synthesized by sol-gel technique. Ceram Int 46:24462–24471

    Article  CAS  Google Scholar 

  22. Taha MA, Youness RA, El-Bassyouni GT, Azooz MA (2020) FTIR spectral characterization, mechanical and electrical properties of P2O5-Li2O-CuO glass-ceramics, Silicon

  23. Youness RA, Taha MA, Ibrahim MA (2021) The influence of various zirconia contents on crystallite sizes, shrinkage, and physical and mechanical properties of hydroxyapatite-based nanobiocomposites. Egypt J Chem 64:1347–1352

    Google Scholar 

  24. Moustafa EB, Melaibari A, Basha M (2020) Wear and microhardness behaviors of AA7075/SiC-BN hybrid composite surfaces fabricated by friction stir processing. Ceram Int 46:16938–16943

    Article  CAS  Google Scholar 

  25. Taha MA, Youness RA (2021) Review on using powder metallurgy method for production of metal-based nanocomposites, Egypt J Chem (in press)

  26. Elmahdy M, Abouelmagd G, Mazen AA (2018) Microstructure and properties of cu-ZrO2 nanocomposites synthesized by in situ processing. Mater Res 21:1–11

    Google Scholar 

  27. Ağaoğullar D (2019) Effects of ZrC content and mechanical alloying on the microstructural and mechanical properties of hypoeutectic Al-7 wt.% Si composites prepared by spark plasma sintering. Ceram Int 45:13257–13268

    Article  Google Scholar 

  28. Wah A, Muhamad N, Sulon AB, Ahmad RN (2016) Effect of sintering temperature on density, hardness and strength of MIM Co30Cr6Mo biomedical alloy. J Jpn Soc Powder Metall 63:434–437

    Article  Google Scholar 

  29. Youness RA, Taha MA, Ibrahim MA (2017) Effect of sintering temperatures on the in vitro bioactivity, molecular structure and mechanical properties of titanium/carbonated hydroxyapatite nanobiocomposites. Mol Struct 1150:188–195

    Article  CAS  Google Scholar 

  30. Moustafa EB, AbuShanab WS, Ghandourah E, Taha MA (2020) Microstructural, mechanical and thermal properties evaluation of AA6061/Al2O3-BN hybrid and mono composite surface. JMRT 9(6):15486–15495

    CAS  Google Scholar 

  31. Chen G, Wan J, HE N, Zhang H, han F, Zhang Y (2018) Strengthening mechanisms based on reinforcement distribution uniformity for particle reinforced aluminum matrix composites, Trans Nonferrous Met Soc China 28:2395–2400

  32. Habibnejad K, Mahmudi R, Poole WJ (2009) Enhanced properties of mg-based nano-composites reinforced with Al2O3 nano-particles. Mater Sci Eng A 519:198–203

    Article  Google Scholar 

  33. Alizadeh A, Maleki M, Abdollahi A (2017) Preparation of super-high strength nanostructured B4C reinforced Al-2Cu aluminum alloy matrix composites by mechanical milling and hot press method: microstructural, mechanical and tribological characterization. Adv Powder Technol 28:3274–3287

    Article  CAS  Google Scholar 

  34. Shaikh MBN, Arif S, Siddiqui MA (2018) Fabrication and characterization of aluminium hybrid composites reinforced with fly ash and silicon carbide through powder metallurgy. Mater Res Express 5:046506

    Article  Google Scholar 

  35. Kumar PS, Ramesh A, Soundararajan A (2020) Investigation on physical and mechanical behaviour of A356 - x wt. % SiC/gr hybrid composites. Metalurg 59:31–34

    Google Scholar 

  36. Kumar HGP, Xavior MA (2017) Assessment of mechanical and tribological properties of Al 2024- SiC - graphene hybrid composites. Procedia Eng 174:992–999

    Article  CAS  Google Scholar 

  37. Tyagi R (2005) Synthesis and tribological characterization of in situ cast Al-TiC composites. Wear. 259:569–576

    Article  CAS  Google Scholar 

  38. Tyagi R (2005) Effect of TiC content on friction and wear behavior of Al-tic composites. World Tribology congress 1:3–4

    Google Scholar 

  39. Dwivedi SP, Sharma S, Mishra RK (2015) Microstructure and mechanical behavior of A356/SiC/Fly-ash hybrid composites produced by electromagnetic stir casting. J Braz Soc Mech Sci Eng 37:56–57

    Article  Google Scholar 

  40. Moustafa EB, Taha MA (2020) Preparation of high strength graphene reinforced cu-based nanocomposites via mechanical alloying method: microstructural, mechanical and electrical properties. Appl Phys A Mater Sci Process 126:220

    Article  CAS  Google Scholar 

  41. Reddy TP, Kishore SK, Theja PC, Rao PP (2020) Development and wear behavior investigationon aluminum-7075/B4C/fly ash metal matrix composites, Adv. Compos. Hybrid Mater 3:255–265

    CAS  Google Scholar 

  42. Celik YH, Kilickap E (2019) Hardness and wear behaviors of Al matrix composites and hybrid composites, powder Metall. Met Ceram 57:613–622

    CAS  Google Scholar 

  43. John CF, Paul RC, Singh SCE, Jacobjose J, Ramkumar T, Hikku GS, Sharma RK, Sengottuvel P (2018) Corrosion behavior of ZrC particles reinforcement with Al-12Si composites by weight loss method using acidic media. Bull Pol Ac: Tech 66:9–16

    CAS  Google Scholar 

  44. Abubakar MS, Usman B (2019) Investigation of corrosion inhibition potential of ethanol extract of balanites aegyptiaca leaves on mild steel in 1 m hydrochloric acid solution. Mor J Chem 7:82–97

    CAS  Google Scholar 

Download references

Acknowledgments

This project was funded by the deanship of scientific research (DSR) at King Abdulaziz University, Jeddah under grant No. (RG-1-150-38). The authors therefore gratefully acknowledges technical and financial support from DSR.

Availability of Data and Material

The data and materials are available of this article.

Funding

This project was funded by the deanship of scientific research (DSR) at King Abdulaziz University, Jeddah under grant No. (RG-1-150-38). The authors therefore gratefully acknowledges technical and financial support from DSR.

Author information

Authors and Affiliations

Authors

Contributions

1. Waheed S. AbuShanab

• Project administration

• Funding acquisition

• Formal analysis

2. Essam B. Moustafa

• Data curation

• Participation in Writing the original draft

3. E. Ghandourah

• Methodology

• Formal analysis

4. Mohammed A. Taha

• Investigation

• Participation in Writing the original draft

• Writing – review - editing

Corresponding author

Correspondence to Mohammed A. Taha.

Ethics declarations

The authors have declared that no competing interests exist.

Conflict of Interest

The manuscript was written through the contributions of all authors. All authors have approved the final version of the manuscript. The authors declare that they have no competing interests.

Consent for Publication

The authors agree to publish this article in its current form.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

AbuShanab, W.S., Moustafa, E.B., Ghandourah, E. et al. The Effect of Different Fly Ash and Vanadium Carbide Contents on the Various Properties of Hypereutectic Al-Si Alloys-Based Hybrid Nanocomposites. Silicon 14, 5367–5377 (2022). https://doi.org/10.1007/s12633-021-01284-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-021-01284-0

Keywords

Navigation