Abstract
The spinel cobalt chromium zinc ferrites (Co0.7Cr0.1Zn0.2Fe2O4) and the polyaniline (PANI)-Co0.7Cr0.1Zn0.2Fe2O4 composites were prepared by polyacrylamide gel and an in situ polymerization method, respectively. The structure of the synthesized material was characterized by X-ray diffraction (XRD) and Fourier transform infrared spectrometer (FTIR), which shows that the spinel Co0.7Cr0.1Zn0.2Fe2O4 ferrites and the PANI-Co0.7Cr0.1Zn0.2Fe2O4 composites are obtained. As a small amount of Co2+ in the octahedron ferrite is replaced by Cr3+, the lattice constant of Co0.8Zn0.2Fe2O4 ferrites reduces from 0.8409 to 0.8377 nm. The magnetic properties of the two materials were investigated by vibrating sample magnetometer (VSM). The VSM results confirm that the saturation magnetization (M s), remanent magnetization (M r) and coercive force (H c) of the PANI-Co0.7Cr0.1Zn0.2Fe2O4 composites are 8.80 mA·m2·g−1, 3.14 mA·m2·g−1 and 37.22 kA·m−1, respectively, which are smaller than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites. The microwave absorbing capability of the two materials was studied by waveguide method. In the frequency range of 5–20 GHz, two reflection loss maximum values of the PANI-Co0.7Cr0.1Zn0.2Fe2O4 composites appear at 14.1 and 17.9 GHz with −13.17 and −15.36 dB, respectively, which are obviously higher than those of the Co0.7Cr0.1Zn0.2Fe2O4 ferrites.
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Zhang X, Wang S, Zhang J, Zhang P, Liu P, Zhang M. Synthesis and microwave absorbing properties of La-doped barium ferrite nano powders via sol–gel auto-combustion method. Chin J Rare Met. 2015;39(8):715.
Ye JW, Liu Y, Chen XF. Microwave electromagnetic and absorption properties of Sm N/α-Fe/Sm2Fe17N3 composites in 0.5–18 GHz range. J Alloys Compd. 2012;526(15):59.
Li LZ, Lan ZW, Zhu XH, Yu Z. Microstructure and temperature dependence of magnetic properties of CuO-added MnZn ferrites. Rare Met. 2011;30(3):287.
Hosseini HH, Mohseni SH, Asadnia A. Synthesis and microwave absorbing properties of polyaniline/MnFe2O4 nanocomposite. J Alloys Compd. 2011;509(14):4682.
Yang G, Zhuang QX, Cai RL, Liu XY, Kan Z, Han ZW. Preparing and conductivity properties of polyaniline/polybenzobisoxazole composites. Mater Lett. 2014;123(15):27.
Gupta K, Jana PC, Meikap AK. Electrical transport and optical properties of the composite of polyaniline with gold. Solid State Sci. 2012;14(3):324.
Yao Y, Jiang HY, Wu JS, Gu D, Shen L. Synthesis of Fe3O4/polyaniline nanocomposite in reversed micelle systems and its performance characteristics. Proc Eng. 2012;27(12):664.
Xiao HM, Fu SY. Synthesis and physical properties of electromagnetic polypyrrole composites via addition of magnetic crystals. Cryst Eng Commun. 2014;16(11):2097.
Gairola SP, Verma V, Kumar L, Dar MA, Annapoomi S, Kotnala RK. Enhanced microwave absorption properties in polyaniline and nano-ferrite composite in X-band. Synth Met. 2010;160(21–22):2315.
Yang CC, Gung YJ, Hung WC, Ting TH, Wu KH. Infrared and microwave absorbing properties of BaTiO3/polyaniline and BaFe12O19/polyaniline composites. Compos Sci Technol. 2010;70(3):466.
Ma RT, Tian YW, Zhao HT, Zhang G, Zhao H. Synthesis, characterization and electromagnetic studies on nanocrystalline Co0.5Zn0.5Fe2O4 by polyacrylamide gel. J Mater Sci Technol. 2008;24(4):628.
Hwang CC, Tsai JS, Huang TH. Combustion synthesis of Ni–Zn ferrite by using glycine and metal nitrates—investigations of precursor homogeneity, product reproducibility, and reaction mechanism. Mater Chem Phys. 2005;93(2–3):330.
Leng CJ, Wei JH, Liu ZY, Shi J. Influence of imidazolium-based ionic liquids on the performance of polyaniline-CoFe2O4 nanocomposites. J Alloys Compd. 2011;509(6):3052.
Prasanna CD, Jayanna HS, Lamani AR, Dash S. Polyaniline/CoFe2O4 nanocomposites: a novel synthesis, characterization and magnetic properties. Synth Met. 2011;161(21–22):2306.
Dirajdar DS, Devatwal UN, Jadhav KM. X-ray, IR and bulk magnetic properties of Cu1+x Mn x Fe2−2x O4 ferrite system. J Mater Sci. 2002;37(7):1443.
Li LC, Jiang J, Xu F. Synthesis and ferromagnetic properties of novel Sm-substituted LiNi ferrite–polyaniline nanocomposite. Mater Lett. 2007;61(4–5):1091.
Namita G, Kuldeep S, Anil O, Singh DP, Dhawan SK. Thermal, dielectric and microwave absorption properties of polyaniline-CoFe2O4 nanocomposites. Compos Sci Technol. 2011;71(15):1754.
Duan YP, Wu GL, Li XG. On the correlation between structural characterization and electromagnetic properties of doped polyaniline. Solid State Sci. 2010;12(8):1374.
Phang SW, Hino T, Abdullah MH, Kuramoto N. Applications of polyaniline doubly doped with p-toluene sulphonic acid and dichloroacetic acid as microwave absorbing and shielding materials. Mater Chem Phys. 2007;104(2–3):327.
Peng CH, Wang HW, Kan SW, Shen MZ, Wei YM, Chen SY. Microwave absorbing materials using Ag–NiZn ferrite core-shell nanopowders as fillers. J Magn Magn Mater. 2004;284(1–3):113.
Ting TH, Yu RP, Jau YN. Synthesis and microwave absorption characteristics of polyaniline/NiZn ferrite composites in 2–40 GHz. Mater Chem Phys. 2011;126(1–2):364.
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This work was financially supported by the Natural Science Foundation of Liaoning Province (No. 2014020094) and the Key Laboratory Construction Fund of Shenyang (No. F14-187-1-00).
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Ma, RT., Shang, HY., Wang, X. et al. Dielectric, magnetic and microwave absorbing properties of polyaniline-Co0.7Cr0.1Zn0.2Fe2O4 composites. Rare Met. 36, 118–122 (2017). https://doi.org/10.1007/s12598-015-0650-y
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DOI: https://doi.org/10.1007/s12598-015-0650-y