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Effect of Polyaniline on Magnetic and Microwave Absorption Properties in SrFe12O19/Zn0.4Co0.2Ni0.4Fe2O4 Ferrite Nanocomposites

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Abstract

Polyaniline PANI/(SrFe12O19)(1-x)/(Co0.8Ni0.2Fe2O4)(x) (x = 0.2, 0.4, 0.6, 0.8) composites were prepared via the in situ polymerization process. The structure, morphology and electromagnetic absorption properties of samples were studied. XRD (x-ray diffractometer), FESEM (field emission scanning electron microscopy), and FTIR (field transform infrared) analyses demonstrated that SrFe12O19/Zn0.4Co0.2Ni0.4Fe2O4 ferrite particles were covered by PANI coating. VSM measurement revealed by adding non-magnetic polymer (PANI), magnetic features of aimed composites declined. The electromagnetic absorption of synthesized samples was measured by VNA. In the frequency range of 8.2–12.4 GHz (X-Band), the reflection loss improved to − 28.5 dB from − 2.93 dB composites of PANI/(SrFe12O19)0.2/(Zn0.4Co0.2Ni0.4Fe2O4)0.8 in comparison to (SrFe12O19)0.2/(Zn0.4Co0.2Ni0.4Fe2O4)0.8. Due to the perfect impedance matching between PANI as the dielectric part, and ferrites in the case of the magnetic part, the reflection loss decreased in PANI/(SrFe12O19)(1-x)/(Co0.8Ni0.2Fe2O4)(x) composites. The minimum reflection loss of the PANI/SrFe12O19/Zn0.4Co0.2Ni0.4Fe2O4 composites was − 28.6 dB at the frequency of 11.5 GHz.

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Authors and Affiliations

  1. Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran

    Faezeh Tavakolinia

  2. Department of Chemistry, Yadegar-E-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran

    Mohammad Yousefi & Susan Samadi

  3. Department of Engineering, Imam Hossein University, Tehran, Iran

    Seyyed Salman Seyyed Afghahi

  4. Department of Materials Engineering, Faculty of Engineering, Imam Khomeini International University, Qazvin, Iran

    Saeid Baghshahi

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  1. Faezeh Tavakolinia
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  2. Mohammad Yousefi
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  3. Seyyed Salman Seyyed Afghahi
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  4. Saeid Baghshahi
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  5. Susan Samadi
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Correspondence to Mohammad Yousefi.

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Tavakolinia, F., Yousefi, M., Afghahi, S.S.S. et al. Effect of Polyaniline on Magnetic and Microwave Absorption Properties in SrFe12O19/Zn0.4Co0.2Ni0.4Fe2O4 Ferrite Nanocomposites. J Inorg Organomet Polym 30, 4014–4026 (2020). https://doi.org/10.1007/s10904-020-01547-0

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