Skip to main content
Log in

Synthesis and study of λ-MnO2 supported Pt nanocatalyst for methanol electro-oxidation

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

A λ-MnO2 supported Pt nanocatalyst (5 wt.% Pt/λ-MnO2) was synthesized using a facile approach. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electronic microscope (SEM), transmission electron microscopy (TEM), and energy disperse spectroscopy (EDS) were used for catalyst structure and morphology characterization, which showed that the metallic Pt particles were attached on a λ-MnO2 surface through the interaction between Pt and λ-MnO2. Cyclic voltammetry (CV) was used to test the catalytic activity of Pt/λ-MnO2 toward methanol oxidation, which showed that Pt/λ-MnO2 catalyst has much higher catalytic activity than baseline Pt/C catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Strasser P., Combinatorial optimization of ternary Pt alloy catalysts for the electrooxidation of methanol, J. Comb. Chem., 2008, 10: 216.

    Article  CAS  PubMed  Google Scholar 

  2. Liu S.H., Yu W.Y., Chen C.H., Lo A.Y., Hwang B.J., Chien S.H., and Liu S.B., Fabrication and characterization of well-dispersed and highly stable PtRu nanoparticles on carbon mesoporous material for applications in direct methanol fuel cell, Chem. Mater. 2008, 20: 1622.

    Article  CAS  Google Scholar 

  3. Guo S.J., Fang Y.X., Dong S.J., and Wang E.K., High-efficiency and low-cost hybrid nanomaterial as enhancing electrocatalyst:spongelike Au/Pt core/shell nanomaterial with hollow cavity, J. Phys. Chem. C., 2007, 111: 17104.

    Article  CAS  Google Scholar 

  4. Tang J.M., Jensen K., Waje M., Li W.Z., Larsen P., Pauley K., Chen Z.W., Ramesh P., Itkis M.E., Yan Y.S., and Haddon R.C., High performance hydrogen fuel cells with ultralow Pt loading carbon nanotube thin film catalysts, J. Phys. Chem. C., 2007, 111: 17901.

    Article  CAS  Google Scholar 

  5. Wu G., Li D.Y., Dai C.S., Wang D.L., and Li N., Well-dispersed high-loading Pt nanoparticles supported by shell-core nanostructured carbon for methanol electrooxidation, Langmuir 2008, 24: 3566.

    Article  CAS  PubMed  MathSciNet  Google Scholar 

  6. Wang N., Cao X., He L., Zhang W., Guo L., Chen C.P., Wang R.M., and Yang S.H., One-pot synthesis of highly crystallined λ-MnO2 nanodisks assembled from nanoparticles: morphology evolutions and phase transitions, J. Phys. Chem. C., 2008, 112: 365.

    Article  CAS  Google Scholar 

  7. Xu M.W., Kong L.B., Zhou W.J., and Li H.L., Hydrothermal synthesis and pseudocapacitance properties of α-MnO2 hollow spheres and hollow urchins, J. Phys. Chem. C., 2007, 111: 19141.

    Article  CAS  Google Scholar 

  8. Wang X. and Li Y.D., Selected-control hydrothermal synthesis of α- and β-MnO2 single crystal nanowires, J. Am. Chem. Soc., 2002, 124: 2880.

    Article  CAS  PubMed  Google Scholar 

  9. Karlsson U., Wang G.Z., and Bbkvall J.E., Rutheniumcatalyzed oxidation of nonactivated alcohols by MnO2, J. Org. Chem., 1994, 59: 1196.

    Article  CAS  Google Scholar 

  10. Liang S.H., Teng F., Bulgan G., Zong R.L., and Zhu Y.F., Effect of phase structure of MnO2 nanorod catalyst on the activity for CO oxidation, J. Phys. Chem. C., 2008, 112: 5307.

    Article  CAS  Google Scholar 

  11. Morales F., Smit E.D., de Groot F.M.F., Visser T., and Weckhuysen B.M., Effects of manganese oxide promoter on the CO and H2 adsorption properties of titania-supported cobalt Fischer-Tropsch catalysts, J. Catal., 2007, 246: 91.

    Article  CAS  Google Scholar 

  12. Han Y.F., Chen F., Zhong Z., Ramesh K., Chen L., and Widjaja E., Controlled synthesis, characterization, and catalytic properties of Mn2O3 and Mn3O4 nanoparticles supported on mesoporous silica SBA-15, J. Phys. Chem. B., 2006, 110: 24450.

    Article  CAS  PubMed  Google Scholar 

  13. Wei Z.D., Ji M.B., Hong Y., Sun C.X., Chan S.H., and Shen P.K., MnO2-Pt/C composite electrodes for preventing voltage reversal effects with polymer electrolyte membrane fuel cells, J. Power Sources, 2006, 160: 246.

    Article  CAS  Google Scholar 

  14. Wang L.C., Liu Y.M., Chen M., Cao Y., He H.Y., and Fan K.N., MnO2 nanorod supported gold nanoparticles with enhanced activity for solvent-free aerobic alcohol oxidation, J. Phys. Chem. C., 2008, 112: 6981.

    Article  CAS  Google Scholar 

  15. Zhao G.Y and Li H.L. Electrochemical oxidation of methanol on Pt nanoparticles composited MnO2 nanowire arrayed electrode, Appl. Surf. Sci., 2008, 254: 3232.

    Article  CAS  ADS  Google Scholar 

  16. Hunter J.C., Preparation of a new crystal form of manganese dioxide: λ-MnO2, J. Solid State Chem., 1981, 39: 142.

    Article  CAS  ADS  Google Scholar 

  17. Moulder J.F., Stickle W.F., Scbol P.E., and Bomben K.D., Handbook of X-ray Photoelectron Spectroscopy, Physical Electronics Inc., Chanhassen, 1992.

    Google Scholar 

  18. Nesbitt H.W. and Banerjee D., Interpretation of XPS Mn(2p) spectra of Mn oxyhydroxides and constraints on the mechanism of MnO2 precipitation, Am. Mineral., 1998, 83: 305.

    CAS  Google Scholar 

  19. Shukla A.K. and Ravikumar M.K., Electro-oxidation of methanol in sulfuric acid electrolyte on platinized-carbon electrodes with several functional-group characteristics, J. Electrochem. Soc., 1994, 141: 1517.

    Article  Google Scholar 

  20. Tong Y.Y., Rice C., and Wieckowski A., A detailed NMR-based model for CO on Pt catalysts in an electrochemical environment: shifts, relaxation, back-bonding, and the Fermi-Level local density of states, J. Am. Chem. Soc., 2000, 122: 1123.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Dingguo Xia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xie, J., Li, X., Yu, Z. et al. Synthesis and study of λ-MnO2 supported Pt nanocatalyst for methanol electro-oxidation. Rare Metals 29, 187–192 (2010). https://doi.org/10.1007/s12598-010-0032-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-010-0032-4

Keywords

Navigation