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Geometry dependent photoconductivity of In2S3 kinks synthesized by kinetically controlled thermal deposition

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Abstract

High quality In2S3 kinks were synthesized via a kinetically controlled thermal deposition process and their optoelectronic characteristics were systematically explored. The growth mechanism was attributed to the combination of kinetic dynamic, crystal facial energy, and surface roughness. Two trap induced emission bands were evidenced via a low temperature cathodoluminescence (CL) study. Furthermore, the nanowire junctions demonstrated a degenerative photodetection performance, as compared to the straight arms, attributed to a stress-induced extra series resistance measured from the kinked area. The well-controllable shape of the inorganic nanostructures and the detailed exploration of their optoelectronic properties are particularly valuable for their further practical applications.

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References

  1. Hu, W. H.; Liu, Y. S.; Chen, T.; Liu, Y.; Li, C. M. Hybrid ZnO nanorod-polymer brush hierarchically nanostructured substrate for sensitive antibody microarrays. Adv. Mater. 2015, 27, 181–185.

    Article  Google Scholar 

  2. Kuyken, B.; Ideguchi, T.; Holzner, S.; Yan, M.; Hänsch, T. W.; Van Campenhout, J.; Verheyen, P.; Coen, S.; Leo, F.; Baets, R. et al. An octave-spanning mid-infrared frequency comb generated in a silicon nanophotonic wire waveguide. Nat. Commun. 2015, 6, 6310.

    Article  Google Scholar 

  3. Cheng, C. B.; Fan, H. J. Branched nanowires: Synthesis and energy applications. Nano Today 2012, 7, 327–343.

    Article  Google Scholar 

  4. Luo, T.; Liang, B.; Liu, Z.; Xie, X. M.; Lou, Z.; Shen, G. Z. Single-GaSb-nanowire-based room temperature photodetectors with broad spectral response. Sci. Bull. 2015, 60, 101–108.

    Article  Google Scholar 

  5. Zhao, M. G.; Cai, B.; Ma, Y.; Cai, H.; Huang, J. Y.; Pan, X. H.; He, H. P.; Ye, Z. Z. Introducing heterojunction barriers into single kinked nanowires for the probe-free detection of proteins and intracellular recording. Nanoscale 2014, 6, 4052–4057.

    Article  Google Scholar 

  6. Qing, Q.; Jiang, Z.; Xu, L.; Gao, R. X.; Mai, L. Q.; Lieber, C. M. Free-standing kinked nanowire transistor probes for targeted intracellular recording in three dimensions. Nat. Nanotechnol. 2013, 9, 142–147.

    Article  Google Scholar 

  7. Burgess, T.; Caroff, P.; Wang, Y. D.; Badada, B. H.; Jackson, H. E.; Smith, L. M.; Guo, Y.; Tan, H. H.; Jagadish, C. Zn3As2 nanowires and nanoplatelets: Highly efficient infrared emission and photodetection by an earth abundant material. Nano Lett. 2015, 15, 378–385.

    Article  Google Scholar 

  8. Yan, C. Y., Singh, N.; Lee, P. S. Kinking-induced structural evolution of metal oxide nanowires into single-crystalline nanorings. ACS Nano 2010, 4, 5350–5356.

    Article  Google Scholar 

  9. Madras, P.; Dailey, E.; Drucker, J. Kinetically induced kinking of vapor-liquid-solid grown epitaxial Si nanowires. Nano Lett. 2009, 9, 3826–3830.

    Article  Google Scholar 

  10. Li, H. Q.; Wang, X.; Xu, J. Q.; Zhang, Q.; Bando, Y.; Golberg, D.; Ma, Y.; Zhai, T. Y. One-dimensional CdS nanostructures: A promising candidate for optoelectronics. Adv. Mater. 2013, 25, 3017–3037.

    Article  Google Scholar 

  11. Li, J. B.; Meng, C.; Liu, Y.; Wu, X. Q.; Lu, Y. Z.; Ye, Y.; Dai, L.; Tong, L. M.; Liu, X.; Yang, Q. Wavelength tunable CdSe nanowire lasers based on the absorption-emissionabsorption process. Adv. Mater. 2013, 25, 833–837.

    Article  Google Scholar 

  12. Chaudhari, N.; Mandal, L.; Game, O.; Warule, S.; Phase, D.; Jadkar, S.; Ogale, S. Dramatic enhancement in photoresponse of ß-In2S3 through suppression of dark conductivity by synthetic control of defect-induced carrier compensation. ACS Appl. Mater. Interfaces 2015, 7, 17671–17681.

    Article  Google Scholar 

  13. Acharya, S.; Dutta, M.; Sarkar, S.; Basak, D.; Chakraborty, S.; Pradhan, N. Synthesis of micrometer length indium sulfide nanosheets and study of their dopant induced photoresponse properties. Chem. Mater. 2012, 24, 1779–1785.

    Article  Google Scholar 

  14. Xie, X. M.; Shen, G. Z. Single-crystalline In2S3 nanowirebased flexible visible-light photodetectors with an ultra-high photoresponse. Nanoscale 2015, 7, 5046–5052.

    Article  Google Scholar 

  15. Jayakrishnan, R.; John, T. T.; Kartha, C. S.; Vijayakumar, K. P.; Abe, T.; Kashiwaba, Y. Defect analysis of sprayed ß-In2S3 thin films using photoluminescence studies. Semicond. Sci. Technol. 2005, 20, 1162–1167.

    Article  Google Scholar 

  16. Caroff, P.; Dick, K. A.; Johansson, J.; Messing, M. E.; Deppert, K.; Samuelson, L. Controlled polytypic and twinplane superlattices in III–V nanowires. Nat. Nanotechnol. 2009, 4, 50–55.

    Article  Google Scholar 

  17. Algra, R. E.; Verheijen, M. A.; Borgström, M. T.; Feiner, L. F.; Immink, G.; van Enckevort, W. J. P.; Vlieg, E.; Bakkers, E. P. A. M. Twinning superlattices in indium phosphide nanowires. Nature 2008, 456, 369–372.

    Article  Google Scholar 

  18. Shen, G. Z.; Liang, B.; Wang, X. F.; Chen, P. C.; Zhou, C. W. Indium oxide nanospirals made of kinked nanowires. ACS Nano 2011, 5, 2155–2161.

    Article  Google Scholar 

  19. Tian, B. Z.; Xie, P.; Kempa, T. J.; Bell, D. C.; Lieber, C. M. Single-crystalline kinked semiconductor nanowire superstructures. Nat. Nanotechnol. 2009, 4, 824–829.

    Article  Google Scholar 

  20. Dellis, S.; Christoulaki, A.; Spiliopoulos, N.; Anastassopoulos, D. L.; Vradis, A. A. Electrochemical synthesis of large diameter monocrystalline nickel nanowires in porous alumina membranes. J. Appl. Phys. 2013, 114, 164308.

    Article  Google Scholar 

  21. Tan, M.; Chen, X. Q. Growth mechanism of single crystal nanowires of fcc metals (Ag, Cu, Ni) and hcp metal (Co) electrodeposited. J. Electrochem. Soc. 2012, 159, K15–K20.

    Article  Google Scholar 

  22. Tsong, T. T. Atom-Probe Field Ion Microscopy; Cambridge University Press: Cambridge, 1990.

  23. Kim, Y.; Trung, T. S. B.; Yang, S.; Kim, S.; Lee, H. Mechanism of the surface hydrogen induced conversion of CO2 to methanol at Cu(111) step sites. ACS Catal. 2016, 6, 1037–1044.

    Article  Google Scholar 

  24. Gan, L.; Liao, M. Y.; Li, H. Q.; Ma, Y.; Zhai, T. Y. Geometryinduced high performance ultraviolet photodetectors in kinked SnO2 nanowires. J. Mater. Chem. C 2015, 3, 8300–8306.

    Article  Google Scholar 

  25. Shin, N.; Chi, M. F.; Filler, M. A. Interplay between defect propagation and surface hydrogen in silicon nanowire kinking superstructures. ACS Nano 2014, 8, 3829–3835.

    Article  Google Scholar 

  26. Tchernycheva, M.; Lavenus, P.; Zhang, H.; Babichev, A. V.; Jacopin, G.; Shahmohammadi, M.; Julien, F. H.; Ciechonski, R.; Vescovi, G.; Kryliouk, O. InGaN/Gan core–shell single nanowire light emitting diodes with graphene-based p-contact. Nano Lett. 2014, 14, 2456–2465.

    Article  Google Scholar 

  27. Im, H. S.; Park, K.; Jang, D. M.; Jung, C. S.; Park, J.; Yoo, S. J.; Kim, J. G. Zn3P2-Zn3As2 solid solution nanowires. Nano Lett. 2015, 15, 990–997.

    Article  Google Scholar 

  28. Li, L.; Pandey, A.; Werder, D. J.; Khanal, B. P.; Pietryga, J. M.; Klimov, V. I. Efficient synthesis of highly luminescent copper indium sulfide-based core/shell nanocrystals with surprisingly long-lived emission. J. Am. Chem. Soc. 2011, 133, 1176–1179.

    Article  Google Scholar 

  29. Jayakrishnan, R.; Sebastian, T.; Sudha Kartha, C.; Vijayakumar, K. P. Effect of defect bands in ß-In2S3 thin films. J. Appl. Phys. 2012, 111, 093714.

    Article  Google Scholar 

  30. Rengaraj, S.; Venkataraj, S.; Tai, C. W.; Kim, Y.; Repo, E.; Sillanpää, M. S. Self-assembled mesoporous hierarchicallike In2S3 hollow microspheres composed of nanofibers and nanosheets and their photocatalytic activity. Langmuir 2011, 27, 5534–5541.

    Article  Google Scholar 

  31. Cansizoglu, H.; Cansizoglu, M. F.; Watanabe, F.; Karabacak, T. Enhanced photocurrent and dynamic response in vertically aligned In2S3/Ag core/shell nanorod array photoconductive devices. ACS Appl. Mater. Interfaces 2014, 6, 8673–8682.

    Article  Google Scholar 

  32. Nielsen, A.; Kuzmanich, G.; Garcia-Garibay, M. A. Quantum chain reaction of tethered diarylcyclopropenones in the solid state and their distance-dependence in solution reveal a Dexter S2-S2 energy-transfer mechanism. J. Phys. Chem. A 2014, 118, 1858–1863.

    Article  Google Scholar 

  33. Tang, J.; Konstantatos, G.; Hinds, S.; Myrskog, S.; Pattantyus- Abraham, A. G.; Clifford, J.; Sargent, E. H. Heavy-metal-free solution-processed nanoparticle-based photodetectors: Doping of intrinsic vacancies enables engineering of sensitivity and speed. ACS Nano 2009, 3, 331–338.

    Article  Google Scholar 

  34. Fan, C.; Zhang, Q. L.; Zhu, X. L.; Zhuang, X. J.; Pan, A. L. Photoluminescence and surface photovoltage properties of ZnSe nanoribbons. Sci. Bull. 2015, 60, 1674–1679.

    Article  Google Scholar 

  35. Ma, Y. Ultrathin SnSe2 flakes: A new member in twodimensional materials for high-performance photodetector. Sci. Bull. 2015, 60, 1789–1790.

    Article  Google Scholar 

  36. Li, L.; Lee, P. S.; Yan, C. Y.; Zhai, T. Y.; Fang, X. S.; Liao, M. Y.; Koide, Y.; Bando, Y.; Golberg, D. Ultrahighperformance solar-blind photodetectors based on individual single-crystalline In2Ge2O7 nanobelts. Adv. Mater. 2010, 22, 5145–5149.

    Article  Google Scholar 

  37. Shao, D. L.; Gao, J.; Chow, P.; Sun, H. T.; Xin, G. Q.; Sharma, P.; Lian, J.; Koratkar, N. A.; Sawyer, S. Organic–inorganic heterointerfaces for ultrasensitive detection of ultraviolet light. Nano Lett. 2015, 15, 3787–3792.

    Article  Google Scholar 

  38. Xing, X. N.; Zhang, Q.; Huang, Z.; Lu, Z. J.; Zhang, J. B.; Li, H. Q.; Zeng, H. B.; Zhai, T. Y. Strain driven spectral broadening of Pb ion exchanged CdS nanowires. Small 2016, 12, 874–881.

    Article  Google Scholar 

  39. Chen, J. N.; Conache, G.; Pistol, M. E.; Gray, S. M.; Borgstrom, M. T.; Xu, H. X.; Xu, H. Q.; Samuelson, L.; Håkanson, U. Probing strain in bent semiconductor nanowires with Raman spectroscopy. Nano Lett. 2010, 10, 1280–1286.

    Article  Google Scholar 

  40. Gruber, T.; Prinz, G. M.; Kirchner, C.; Kling, R.; Reuss, F.; Limmer, W.; Waag, A. Influences of biaxial strains on the vibrational and exciton energies in ZnO. J. Appl. Phys. 2004, 96, 289–292.

    Article  Google Scholar 

  41. Sahoo, S.; Arora, A. K. Laser-power-induced multiphonon resonant Raman scattering in laser-heated CdS nanocrystal. J. Phys. Chem. B 2010, 114, 4199–4203.

    Article  Google Scholar 

  42. Sahoo, S.; Sharma, G. L.; Katiyar, R. S. Raman spectroscopy to probe residual stress in ZnO nanowire. J. Raman Spectrosc. 2012, 43, 72–75.

    Article  Google Scholar 

  43. Cook, B. G.; Varga, K. Conductance of kinked nanowires. Appl. Phys. Lett. 2011, 98, 052104.

    Article  Google Scholar 

  44. Amer, M.; Bushmaker, A.; Cronin, S. Anomalous kink behavior in the current–voltage characteristics of suspended carbon nanotubes. Nano Res. 2012, 5, 172–180.

    Article  Google Scholar 

  45. Li, X. L.; Zhang, Y. Z.; Shen, Z. X.; Fan, H. J. Highly ordered arrays of particle-in-bowl plasmonic nanostructures for surfaceenhanced Raman scattering. Small 2012, 8, 2548–2554.

    Article  Google Scholar 

  46. Li, H. X.; Zhang, X. H.; Liu, N. S.; Ding, L. W.; Yao, J. Y.; Wang, S. L.; Su, J.; Li, L. Y.; Gao, Y. H. Enhanced photoresponse properties of a single ZnO microwire photodetector by coupling effect between localized Schottky barriers and piezoelectric potential. Opt. Express 2015, 23, 21204–21212.

    Article  Google Scholar 

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Correspondence to Tianyou Zhai.

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Xiong, X., Zhang, Q., Gan, L. et al. Geometry dependent photoconductivity of In2S3 kinks synthesized by kinetically controlled thermal deposition. Nano Res. 9, 3848–3857 (2016). https://doi.org/10.1007/s12274-016-1254-z

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  • DOI: https://doi.org/10.1007/s12274-016-1254-z

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