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Development of durable shrink-resist coating of wool with sol-gel polymer processing

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Abstract

Knitted wool fabric was pre-treated with the serine type protease, Esperase 8.0L (EC3.4.21.62), and sodium sulphite followed by an immersion treatment with a sol-gel hybrid polymer. To enhance the durability of the sol-gel treatment on wool, one of two different alkoxysilanes containing coupling epoxy or mercapto groups were added to the sol-gel hybrid. The combination of protease treatment with an immersion sol-gel treatment achieved wool fabric that was lightweight with a soft handle and had combined shrink-resistance and hydrophobic properties without fibre discoloration. The addition of an alkoxysilane with a mercapto coupling group within the sol-gel hybrid gave better performance than using an alkoxysilane with an epoxy coupling group in terms of polymer uptake, fabric shrink resistance, whiteness and durability to washing.

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References

  1. J. Shen, “Advances in Textile Biotechnology” (V. A. Nierstrasz and A. Cavaco-Paulo Eds.), pp.171–192, Woodhead Publishing, Cambridge, 2010.

    Book  Google Scholar 

  2. H. Nolte, D. P. Bishop, and H. Höcker, J. Text. Inst., 87, 212 (1996).

    Article  CAS  Google Scholar 

  3. J. Shen, D. Bishop, E. Heine, and B. Hollfelder, J. Text. Inst., 90, 404 (1999).

    CAS  Google Scholar 

  4. E. Smith and J. Shen, J. Biotechnol., 156, 134 (2011).

    Article  CAS  Google Scholar 

  5. E. Smith and J. Shen, Biocatal. Biotransfor., 30, 38 (2012).

    Article  CAS  Google Scholar 

  6. S. Vílchez, P. Jovancic, A. M. Manich, M. R. Julià, and P. Erra, J. Appl. Polym. Sci., 98, 1938 (2005).

    Article  Google Scholar 

  7. S. Vílchez, A. M. Manich, P. Jovancic, and P. Erra, Carbohydr. Polym., 71, 515 (2008).

    Article  Google Scholar 

  8. C. J. S. M. Silva, Q. Zhang, J. Shen, and A. Cavaco-Paulo, Enzyme Microb. Tech., 39, 634 (2006).

    Article  CAS  Google Scholar 

  9. E. Smith, Q. Zhang, J. Shen, M. Schroeder, and C. Silva, Biocatal. Biotransfor., 26, 391 (2008).

    Article  CAS  Google Scholar 

  10. E. Smith, M. Schroeder, G. Guebitz, and J. Shen, Enzyme Microb. Tech., 47, 105 (2010).

    Article  CAS  Google Scholar 

  11. R. Araújo, C. Silva, R. Machado, M. Casal, A. M. Cunha, J. C. Rodriguez-Cabello, and A. Cavaco-Paulo, Biomacro-molecules, 10, 1655 (2009).

    Article  Google Scholar 

  12. B. Simončič, B. Tomšič, B. Orel, and I. Jerman, “Surface Modification Systems for Creating Stimuli Responsiveness of Textiles” (D. Jocic Ed.), pp.17–34, University of Twente, Enschede, 2010.

    Google Scholar 

  13. B. Mahltig, H. Haufe, and H. Böttcher, J. Mater. Chem., 15, 4385 (2005).

    Article  CAS  Google Scholar 

  14. B. Mahltig and H. Böttcher, J. Sol-Gel Sci. Techn., 27, 43 (2003).

    Article  CAS  Google Scholar 

  15. W. A. Daoud, J. H. Xin, and X. Tao, J. Am. Ceram. Soc., 87, 1782 (2004).

    Article  CAS  Google Scholar 

  16. H. Wang, J. Ding, Y. Xue, X. Wang, and T. Lin, J. Mater. Res., 25, 1336 (2010).

    Article  CAS  Google Scholar 

  17. T. Textor, T. Bahners, and E. Schollmeyer, “Proceedings of the 10th International Wool Research Conference”, Fl-12, pp.1–5, Aachen, 2000.

    Google Scholar 

  18. K. Yan, H. Jiang, and C. Ding, “Proceedings of the 11th International Wool Research Conference”, 12KN, pp.1–10, Leeds, 2005.

    Google Scholar 

  19. H. Yi and K. Yan, J. Appl. Polym. Sci., 109, 2169 (2008).

    Article  CAS  Google Scholar 

  20. M. M. Chizyuka, Ph. D. Dissertation, De Montfort University, Leicester, 2016.

    Google Scholar 

  21. S. J. McNeil and O. C. Standard, Text. Res. J., 87, 607 (2017).

    Article  Google Scholar 

  22. T. Bahners, J. Adhes. Sci. Technol., 25, 2005 (2011).

    Article  CAS  Google Scholar 

  23. B. Mahltig, “Functional Finishes for Textiles Improving Comfort Performance and Protection” (R. Paul Ed.), pp.387–423, Woodhead Publishing, Cambridge, 2015.

    Book  Google Scholar 

  24. R. S. Carran, A. Ghosh, and J. M. Dyer, Appl. Surf. Sci., 287, 467 (2013).

    Article  CAS  Google Scholar 

  25. Woolmark Company “Woolmark Specification, Knitted Fabric, Specification SF-1”, The Woolmark Company, Australia, 2016.

    Google Scholar 

  26. F. Nickel, G. Koerner, G. Schmidt, and H. Rott, U. S. Patent 4405328 (1983).

    Google Scholar 

  27. R. W. Moncrieff, “Wool Shrinkage and its Prevention” The National Trade Press, London, 1953.

    Google Scholar 

  28. D. M. Lewis, “Wool Dyeing” (D. M. Lewis Ed.), pp.111–136, Society of Dyers and Colourists, Bradford, 1992.

    Google Scholar 

  29. K. R. Millington, “Advances in Wool Technology” (N. A. G. Johnson and I. M. Russell Eds.), pp.217–247, Woodhead Publishing, Cambridge, 2009.

    Book  Google Scholar 

  30. S. J. McNeil, O. C. Standard and M. T. Pailthorpe, “Proceedings of the 11th International Wool Research Conference”, 47CCF, pp.1–9, Leeds, 2005.

    Google Scholar 

  31. H. Wang, J. Ding, T. Lin, and X. Wang, Res. J. Text. Apparel, 14, 30 (2010).

    Article  CAS  Google Scholar 

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Correspondence to Jinsong Shen.

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Shen, J., Smith, E., Chizyuka, M. et al. Development of durable shrink-resist coating of wool with sol-gel polymer processing. Fibers Polym 18, 1769–1779 (2017). https://doi.org/10.1007/s12221-017-7294-5

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  • DOI: https://doi.org/10.1007/s12221-017-7294-5

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