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Syntheses, characterization and crystal structures of potassium and barium complexes of a Schiff base ligand with different anions

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Abstract

New pseudopolymorph of a O,N,N’-donor hydrazone ligand, 2-pyridylcarboxaldehyde isonicotinoylhydrazone (L) and its discrete complexes with K+ and Ba2+ have been reported. L forms isostructural dinuclear complexes with K+ when bromide and iodide were employed as counter anions. However, a monomeric complex in the case of Ba2+ with existence of coordinated as well as lattice perchlorate counter anions was observed. All compounds were characterized by single crystal X-ray analysis and other physicochemical techniques. Structural analysis and spectral features of all compounds are described in detail.

New psuedopolymorpic form of the schiiff base ligand O,N,N'-donor hydrazone ligand(2-pyridylcarboxaldehyde isonicotinoylhydrazone) (L) and the their complexes with alkali and alkaline earth metal have been investigated by various physico-chemical techniques such as FTIR, TGA, PXRD and solid state absorption spectra including X-ray crystallography. L formed isostructural binuclear complexes with K+ when bromide and iodide were employed as counter anion, whereas, a mononuclear complex with Ba2+ having coordinated as well as uncoordinated perchlorate counter anion.

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Acknowledgement

Authors acknowledge the CSIR, India (K-TEN Project, Grant no. CSC 0105) for financial support, Mrs. Monika Gupta for TGA data, Ms. Riddhi Laiya for XRPD data, Mr. Satyaveer Gothwal for elemental data, Mr. Viral Vakani for IR data. BP and KKB acknowledge CSIR (India) for research fellowships. Publication Registration Number: CSIR-CSMCRI No. : 066/2014.

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Authors and Affiliations

  1. Analytical Discipline and Centralized Instrument Facility, CSIR–Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G B Marg, Bhavnagar, 364 002, Gujarat, India

    BHAVESH PARMAR, KAMAL KUMAR BISHT, PARIMAL PAUL & ERINGATHODI SURESH

  2. Academy of Scientific and Innovative Research (AcSIR), CSIR–Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G B Marg, Bhavnagar, 364 002, Gujarat, India

    KAMAL KUMAR BISHT, PARIMAL PAUL & ERINGATHODI SURESH

  3. Scale-up and Process Engineering Unit, CSIR–Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, G B Marg, Bhavnagar, 364 002, Gujarat, India

    PRATYUSH MAITI

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  1. BHAVESH PARMAR
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  2. KAMAL KUMAR BISHT
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  3. PRATYUSH MAITI
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Correspondence to ERINGATHODI SURESH.

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Supplementary Information

Crystallographic data of for the psuedopolymorhic form of L.2H2O, complexes 1, 2 and 3 has been deposited at the Cambridge Crystallographic Data Centre with CCDC nos. 992911 to 991914 respectively. Copies of this information can be obtained free of charge from The Director, CCDC, 12 Union Road, Cambridge, CB2 IEZ, UK (Fax: + 44-1223-336033; Email: deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk). Characterization data for the ligand and complexes such experimental and simulated PXRD for L.2H2O (figure S2), Experimental and simulated PXRD for 1-3 (figure S2), 1H and 13C NMR Spectra of ligands and complexes (figure S4) and ORTEP diagram and crystal structure for complex 2 (figure S1) and selected bond lengths and angles (table S1) are available in the supporting information (www.ias.ac.in/chemsci).

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PARMAR, B., BISHT, K.K., MAITI, P. et al. Syntheses, characterization and crystal structures of potassium and barium complexes of a Schiff base ligand with different anions. J Chem Sci 126, 1373–1384 (2014). https://doi.org/10.1007/s12039-014-0701-1

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