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Sheet-like of MoV-SmIII assembly containing [MoV(CN)8]3− and Sm3+ ions as building blocks

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Abstract

The reaction of [Mo(CN)8]3− with Sm3+ and 2,2′-bipyridine (bpy) lead to a sheet-like bimetallic complex, {Sm(H2O)9[Sm2(bpy)2(OH)2·75(NO3)0·25][Mo(CN)8]2} n (1) in EtOH/H2O mixture solvent. The complex 1 crystallizes in monoclinic, space group C2/c. The structural investigation denotes that the layers interaction with each other by π-π stacks and hydrogen bonds result in a 3D network, containing Sm(H2O) 3+9 as guest molecules in the holes. The magnetic behaviour of the complex 1 has been studied.

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Authors and Affiliations

  1. Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, PR China

    Shu-Lin Ma & Shi Ren

  2. Department of Chemistry, Nankai University, Tianjin, 300071, PR China

    Yue Ma & Dai-Zheng Liao

Authors
  1. Shu-Lin Ma
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  2. Shi Ren
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  3. Yue Ma
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  4. Dai-Zheng Liao
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Correspondence to Shu-Lin Ma or Dai-Zheng Liao.

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Ma, SL., Ren, S., Ma, Y. et al. Sheet-like of MoV-SmIII assembly containing [MoV(CN)8]3− and Sm3+ ions as building blocks. J Chem Sci 121, 421–427 (2009). https://doi.org/10.1007/s12039-009-0049-0

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  • DOI: https://doi.org/10.1007/s12039-009-0049-0

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