Abstract
Due to the inherent anisotropy of the system, gold nanorods behave differently in comparison to their spherical counterparts. Reactivity of gold nanorods, in presence of cupric ions, was probed in an attempt to understand the chemistry of anisotropic particles. The reaction progresses through a series of intermediates. It can be arrested at any stage to get nanorods of desired dimension and therefore, can be used for their reshaping. The presence or absence of cetyltrimethylammonium bromide (CTAB) on the nanorod surface was found to be determining the site of initiation of the reaction. When a large concentration of CTAB is present in the system, selective etching of the tips of the nanorod occurs and when the nanorods are purified to reduce the amount of CTAB in the solution, the side faces of the nanorod also get reacted. Gold nanorods are converted to particles by further surface reconstructions in a systematic surface specific chemistry.
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Asplund K U M, Jansson P J, Lindqvist C and Nordström T 2002 Free Radical Res. 36 1271
Bruck R, Shirin H, Aeed H, Matas Z, Hochman A, Pines M and Avni Y 2001 J. Hepatol. 35 457
Carretero A S, Blanco C C, Diaz B C and Gutiérrez A F 1998 Anal. Chim. Acta 361 217
Chang S-S, Shih C-W, Chen C-D, Lai W-C and Wang C R C 1999 Langmuir 15 701
Foss Jr C A, Hornyak G L, Stockert J A and Martin C R 1992 J. Phys. Chem. 96 7497
Jana N R, Gearheart L, Obare S O and Murphy C J 2002 Langmuir 18 922
Jin Y and Friedman N 2005 J. Am. Chem. Soc. 127 11902
Juste J P, Santos I P, Liz-Marzan L M and Mulvaney P 2005 Coord. Chem. Rev. 249 1870
Kadiiska M B, Hanna P M, Hernandez L and Mason R P 1992 Mol. Pharmacol. 42 723
Kim F, Song J H and Yang P 2002 J. Am. Chem. Soc. 124 14316
Kline T R, Paxton W F, Mallouk T E and Sen A 2005 Angew. Chem., Int. Ed. 44 744
Koppenol W H and Liebman J F 1984 J. Phys. Chem. 88 99
Link S, Burda C, Nikoobakht B and El-Sayed M A 2000 J. Phys. Chem. B104 6152
Liu F-K, Chang Y-C, Ko F-H and Chu T-C 2004 Mater. Lett. 58 373
Martin C R 1996 Chem. Mater. 8 1739
Mohamed M B, Ismail K Z, Link S and El-Sayed M A 1998 J. Phys. Chem. B102 9370
Nair A S 2006 Chemistry of halocarbons with bare and protected silver and gold nanoparticles, Ph D Thesis, Indian Institute of Technology, Madras
Nair A S and Pradeep T 2003 Curr. Sci. 84 1560
Nair A S and Pradeep T 2004 Indian Patent No. 51/CHE/2004
Nair A S and Pradeep T 2007 International Patent PCT application no. PCT/IN05/00022
Norberg N S, Dalpian G M, Chelikowsky J R and Gamelin D R 2006 Nano Lett. 6 2887
Prakash A, McCormick A V and Zachariah M R 2005 Nano Lett. 5 1357
Rajeev Kumar V R, Samal A K, Sreeprasad T S and Pradeep T 2007 Langmuir 23 8667
Rao C N R, Kulkarni G U, Thomas P J and Edwards P P 2000 Chem. Soc. Rev. 28 27
Rodriguez-Fernandez J, Perez-Juste J, Mulvaney P and Liz-Marzan L M 2005 J. Phys. Chem. B109 14257
Salem A K, Searson P C and Leong K W 2003 Nat. Mater. 2 668
Sau T K and Murphy C J 2004 Langmuir 20 6414
Smith E A and Corn R M 2003 Appl. Spectrosc. 57 320A
Song D K, Lenggoro I W, Hayashi Y, Okuyama K and Kim S S 2005 Langmuir 21 10375
Sreeprasad T S, Samal A K and Pradeep T 2007 Langmuir 23 9463
Subramaniam C, Pradeep T and Chakrabarti J 2005 Phys. Rev. Lett. 95 164501
Subramaniam C, Pradeep T and Chakrabarti J 2007 J. Phys. Chem. C111 19103
Todd B D and Lynden-Bell R M 1993 Surf. Sci. 281 191
Tom R T, Samal A K, Sreeprasad T S and Pradeep T 2007 Langmuir 23 1320
Tsung C K, Kou X, Shi Q, Zhang J, Yeung M H, Wang J and Stucky G D 2006 J. Am. Chem. Soc. 128 5352
Uppenbrink J, Johnston R L and Murrell J N 1994 Surf. Sci. 304 223
Wang Z L, Gao R P, Nikoobakht B and El-Sayed M A 2000 J. Phys. Chem. B104 5417
Yu Y Y, Chang S S, Lee C L and Wang C R C 1997 J. Phys. Chem. B101 6661
Zhan B-Z, White M A, Lumsden M, Mueller-Neuhaus J, Robertson K N, Cameron T S and Gharghouri M 2002 Chem. Mater. 14 3636
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Sreeprasad, T.S., Samal, A.K. & Pradeep, T. Reactivity and resizing of gold nanorods in presence of Cu2+ . Bull Mater Sci 31, 219–224 (2008). https://doi.org/10.1007/s12034-008-0039-8
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DOI: https://doi.org/10.1007/s12034-008-0039-8