Abstract
In pursuing excellent supercapacitor electrodes, we designed a series of MoS2/CoS2 composites consisting of flower-liked MoS2 and octahedron-shaped CoS2 through a facile one-step hydrothermal method and investigated the electrochemical performance of the samples with various hydrothermal time. Due to the coupling of two metal species and a big amount of well-developed CoS2 and MoS2, the results indicated that the MoS2/CoS2 composites electrodes exhibited the best electrochemical performance with a large specific capacitance of 490 F/g at 2 mV/s or 400 F/g at 10 A/g among all samples as the hydrothermal time reached 48 h (MCS48). Furthermore, the retention of MCS48 is 93.1% after 10000 cycles at 10 A/g, which manifests the excellent cycling stability. The outstanding electrochemical performance of MCS48 indicates that it could be a very promising and novel energy storage material for supercapacitors in the future.
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References
Ren X C, Tian C J, Li S, et al. Facile synthesis of tremella-like MnO2 and its application as supercapacitor electrodes. Frontiers of Materials Science, 2015, 9(3): 234–240
Zhao Y C, Misch J, Wang C A. Facile synthesis and characterization of MnO2 nanomaterials as supercapacitor electrode materials. Journal of Materials Science: Materials in Electronics, 2016, 27(6): 5533–5542
Gao Y P, Wang L B, Li Z Y, et al. Electrochemical performance of Ti3C2 supercapacitors in KOH electrolyte. Journal of Advanced Ceramics, 2015, 4(2): 130–134
Bissett M A, Kinloch I A, Dryfe R A W. Characterization of MoS2-graphene composites for high-performance coin cell supercapacitors. ACS Applied Materials & Interfaces, 2015, 7(31): 17388–17398
Zhang L J, Hui K N, Hui K S, et al. Facile synthesis of porous CoAl-layered double hydroxide/graphene composite with enhanced capacitive performance for supercapacitors. Electrochimica Acta, 2015, 186(6): 522–529
Zhang L, Hui K N, Hui K S, et al. High-performance hybrid supercapacitor with 3D hierarchical porous flower-like layered double hydroxide grown on nickel foam as binder-free electrode. Journal of Power Sources, 2016, 318: 76–85
Jaramillo T F, Jørgensen K P, Bonde J, et al. Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science, 2007, 317(5834): 100–102
Li Y, Wang H, Xie L, et al. MoS2 nanoparticles grown on graphene: an advanced catalyst for the hydrogen evolution reaction. Journal of the American Chemical Society, 2011, 133(19): 7296–7299
Bissett M A, Kinloch I A, Dryfe R A. Characterization of MoS2–graphene composites for high-performance coin cell supercapacitors. ACS Applied Materials & Interfaces, 2015, 7(31): 17388–17398
Zhou X, Xu B, Lin Z, et al. Hydrothermal synthesis of flower-like MoS2 nanospheres for electrochemical supercapacitors. Journal of Nanoscience and Nanotechnology, 2014, 14(9): 7250–7254
Chen J, Li S L, Xu Q, et al. Synthesis of open-ended MoS2 nanotubes and the application as the catalyst of methanation. Chemical Communications, 2002, 16(16): 1722–1723
Ji Y, Liu X Y, Liu W, et al. A facile template-free approach for the solid-phase synthesis of CoS2 nanocrystals and their enhanced storage energy in supercapacitors. RSC Advances, 2014, 4(91): 50220–50225
Wan H, Ji X, Jiang J, et al. Hydrothermal synthesis of cobalt sulfide nanotubes: The size control and its application in supercapacitors. Journal of Power Sources, 2013, 243(6): 396–402
Chakraborty I, Malik P K, Moulik S P. Preparation and characterisation of CoS2 nanomaterial in aqueous cationic surfactant medium of cetyltrimethylammonium bromide (CTAB). Journal of Nanoparticle Research, 2006, 8(6): 889–897
Ding S J, Jiang S J, Zhou Y S, et al. Catalytic characteristics of active corner sites in CoMoS nanostructure hydrodesulfurization–A mechanism study based on DFT calculations. Journal of Catalysis, 2017, 345: 24–38
Lauritsen J V, Besenbacher F. Atom-resolved scanning tunneling microscopy investigations of molecular adsorption on MoS2 and CoMoS hydrodesulfurization catalysts. Journal of Catalysis, 2015, 328: 49–58
Xiao J, Wan L, Yang S, et al. Design hierarchical electrodes with highly conductive NiCo2S4 nanotube arrays grown on carbon fiber paper for high-performance pseudocapacitors. Nano Letters, 2014, 14(2): 831–838
Chen H, Jiang J, Zhang L, et al. Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors. Nanoscale, 2013, 5(19): 8879–8883
Xiao J, Yang S. Sequential crystallization of sea urchin-like bimetallic (Ni, Co) carbonate hydroxide and its morphology conserved conversion to porous NiCo2O4 spinel for pseudocapa-citors. RSC Advances, 2011, 1(4): 588–595
Lu X, Pellechia P J, Flora J R V, et al. Influence of reaction time and temperature on product formation and characteristics associated with the hydrothermal carbonization of cellulose. Bioresource Technology, 2013, 138: 180–190
Li H Y, Zhao Y C, Wang C A. Formation of molybdenum–cobalt sulfide by one-step hydrothermal reaction for high-performance supercapacitors. Journal of Materials Science: Materials in Electronics, 2018, 29(16): 13703–13708
Tao F, Zhao Y Q, Zhang G Q, et al. Electrochemical characterization on cobalt sulfide for electrochemical supercapacitors. Electrochemistry Communications, 2007, 9(6): 1282–1287
Ragupathy P, Vasan H N, Munichandraiah N. Synthesis and characterization of nano-MnO2 for electrochemical supercapacitor studies. Journal of the Electrochemical Society, 2008, 155(1): A34–A40
Chmiola J, Yushin G, Dash R, et al. Effect of pore size and surface area of carbide derived carbons on specific capacitance. Journal of Power Sources, 2006, 158(1): 765–772
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This work was supported by the National Natural Science Foundation of China (Grant No. 51572145).
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Li, H., Zhao, Y. & Wang, CA. MoS2/CoS2 composites composed of CoS2 octahedrons and MoS2 nano-flowers for supercapacitor electrode materials. Front. Mater. Sci. 12, 354–360 (2018). https://doi.org/10.1007/s11706-018-0437-9
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DOI: https://doi.org/10.1007/s11706-018-0437-9