Abstract
A low-cost and high-activity catalyst for oxygen evolution reaction (OER) is the key to the water splitting technology for hydrogen generation. Here we report the use of three solvents, DMF, ethanol and glycol, in the solvothermal synthesis of three nano-catalysts, Co3(VO4)2-I, Co3(VO4)2-II, and Co3(VO4)2-III, respectively. Transmission electron microscope shows Co3(VO4)2-I, II, and III exist as ultrafine nanosheets, ultrathin nanofilms, and ultrafine nanosheet-comprised microspheres, respectively. These Co3(VO4)2 catalysts exhibit OER electrocatalysis, among which the Co3(VO4)2-II shows the lowest onset overpotential of 310 mVand only requires a small overpotential of 330 mV to drive current density of 10 mA/cm2. Due to their high surface free energy, the ultrathin nanofilms of Co3(VO4)2-II exhibits a good immobilization effect with the high electrocatalytic activity for OER.
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Herrera G, Jiménez-Mier J, Wilks R G, Moewes A, Yang W, Denlinger J. Fast electron dynamics in vanadates measured by resonant inelastic x-ray scattering. Materials Letters, 2013, 107: 144–146
Liang Y, Liu P, Li H B, Yang G W. Synthesis and characterization of copper vanadate nanostructures via electrochemistry assisted laser ablation in liquid and the optical multi-absorptions performance. CrystEngComm, 2012, 14(9): 3291–3296
Zhang S, Hou M, Hou L, Lu M. Synthesis and electrochemical performance of cable-like copper vanadates/polypyrrole nanobelts as anode materials for lithium-ion batteries. Chemical Physics Letters, 2016, 658: 203–206
Wang N, He Z, Cui M, Guo W, Zhang S, Yang M, Tang Y. Syntheses, structure and magnetic properties of two vanadate garnets Ca5M4V6O24 (M = Co, Ni). Journal of Solid State Chemistry, 2015, 228: 245–249
Liu Y, Dai H, Deng J, Zhang L, Au C T. Three-dimensional ordered macroporous bismuth vanadates: PMMA-templating fabrication and excellent visible light-driven photocatalytic performance for phenol degradation. Nanoscale, 2012, 4(7): 2317–2325
Abdi F F, Han L, Smets A H M, Zeman M, Dam B, Van De Krol R. Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode. Nature Communications, 2013, 4: 2195
Shi X, Choi I Y, Zhang K, Kwon J, Kim D Y, Lee J K, Oh S H, Kim J K, Park J H. Efficient photoelectrochemical hydrogen production from bismuth vanadate-decorated tungsten trioxide helix nanostructures. Nature Communications, 2014, 5: 4775
Vu T A, Dao C D, Hoang T T T, Dang P T, Tran H T K, Nguyen K T, Le G H, Nguyen T V, Lee G D. Synthesis of novel silver vanadates with high photocatalytic and antibacterial activities. Materials Letters, 2014, 123: 176–180
Yin K, Liu S, Cai Q, Gao A, Lu S, Shao M. The enhanced ammonia gas-sensing activity of gamma ray irradiated indium vanadate nanoribbons. Journal of Materials Science Materials in Electronics, 2014, 25(1): 419–422
Baddour-Hadjean R, Boudaoud A, Bach S, Emery N, Pereira-Ramos J P. A comparative insight of potassium vanadates as positive electrode materials for Li batteries: Influence of the longrange and local structure. Inorganic Chemistry, 2014, 53(3): 1764–1772
Nithya V D, Pandi K, Lee Y S, Selvan R K. Synthesis, characterization and electrochemical performances of nanocrystalline FeVO4 as negative and LiCoPO4 as positive electrode for asymmetric supercapacitor. Electrochimica Acta, 2015, 167: 97–104
Zhou B, Zhao X, Liu H, Qu J, Huang C P. Visible-light sensitive cobalt-doped BiVO4 (Co-BiVO4) photocatalytic composites for the degradation of methylene blue dye in dilute aqueous solutions. Applied Catalysis B: Environmental, 2010, 99(1-2): 214–221
Xiao M, Miao Y, Li W, Yang Y, Liang X. Onsite deposition of selfrepairing biomimetic nanostructured Ni catalysts with improved electrocatalysis toward glycerol oxidation for H2 production. Electrochimica Acta, 2015, 178: 209–216
Xiao M, Miao Y, Tian Y, Yan Y. Synthesizing nanoparticles of Co-P-Se compounds as electrocatalysts for the hydrogen evolution reaction. Electrochimica Acta, 2015, 165: 206–210
Xiao M, Zhang Z, Tian Y, Miao Y, Wang J. Co-Fe-Se ultrathin nanosheet-fabricated microspheres for efficient electrocatalysis of hydrogen evolution. Journal of Applied Electrochemistry, 2017, 47 (3): 361–367
Tian Y, Zhang Z, Miao Y. Co-Te-Se nano-compounds as electrocatalysts for hydrogen evolution reaction. Journal of the Electrochemical Society, 2016, 163(8): H625–H629
Xiao M, Liang X, Li W, Yang Y, Miao Y. Synthesis of ultrafine Pt/ Pd bimetallic nanoparticles and their decoration on MWCNTs for hydrogen evolution. Journal of the Electrochemical Society, 2015, 162(6): H415–H418
Liang Y, Liu Q, Luo Y, Sun X, He Y, Asiri A M. Zn0.76Co0.24S/ CoS2 nanowires array for efficient electrochemical splitting of water. Electrochimica Acta, 2016, 190: 360–364
Liu T, Liu Q, Asiri A M, Luo Y, Sun X. An amorphous CoSe film behaves as an active and stable full water-splitting electrocatalyst under strongly alkaline conditions. Chemical Communications, 2015, 51(93): 16683–16686
Liu T, Liang Y, Liu Q, Sun X, He Y, Asiri A M. Electrodeposition of cobalt-sulfide nanosheets film as an efficient electrocatalyst for oxygen evolution reaction. Electrochemistry Communications, 2015, 60: 92–96
Feng J X, Xu H, Dong Y T, Ye S H, Tong Y X, Li G R. FeOOH/Co/FeOOH hybrid nanotube arrays as high-performance electrocatalysts for the oxygen evolution reaction. Angewandte Chemie International Edition, 2016, 55(11): 3694–3698
Feng J X, Ye S H, Xu H, Tong Y X, Li G R. Design and synthesis of FeOOH/CeO2 heterolayered nanotube electrocatalysts for the oxygen evolution reaction. Advanced Materials, 2016, 28(23): 4698–4703
Le C. A review of non-fossil energy based hydrogen production technologies. Energy Research and Information, 2011, 3: 130–137
Zhou M, Ouyang R, Li Y, Miao Y. 3D microspheres organized from Ni-Mo-S nanoparticles in situ synthesized on porous Ti for hydrogen evolution electrocatalysis. Electrochimica Acta, 2017, 246: 9–16
Yin Y, Tan X, Hou F, Zhao L. Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO2 for water splitting. Frontiers of Chemical Engineering in China, 2009, 3 (3): 298–304
Gomathisankar P, Noda T, Katsumata H, Suzuki T, Kaneco S. Enhanced hydrogen production from aqueous methanol solution using TiO2/Cu as photocatalysts. Frontiers of Chemical Science and Engineering, 2014, 8(2): 197–202
Lu X F, Gu L F, Wang J W, Wu J X, Liao P Q, Li G R. Bimetalorganic framework derived CoFe2O4/C porous hybrid nanorod arrays as high-performance electrocatalysts for oxygen evolution reaction. Advanced Materials, 2017, 29(3): 1604437
Fei G, Zhao J. Applications and key materials of the vanadium redox flow battery. Energy Research and Information, 2008, 24(1): 49–55
Xing M, Kong L B, Liu M C, Liu L Y, Kang L, Luo Y C. Cobalt vanadate as highly active, stable, noble metal-free oxygen evolution electrocatalyst. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(43): 18435–18443
Cardenas-Morcoso D, Peiro-Franch A, Herraiz-Cardona I, Gimenez S. Chromium doped copper vanadate photoanodes for water splitting. Catalysis Today, 2017, 290: 65–72
Kim T W, Choi K S. Nanoporous BiVO4 photoanodes with duallayer oxygen evolution catalysts for solar water splitting. Science, 2014, 343(6174): 990–994
Tian Y, Zhou M, Meng X, Miao Y, Zhang D. Needle-like CoMoO with multi-modal porosity for pseudocapacitors. Materials Chemistry and Physics, 2017, 198: 258–265
Yan Y, Tian Y, Hao M, Miao Y. Synthesis and characterization of cross-like Ni-Co-P microcomposites. Materials & Design, 2016, 111: 230–238
Mazloom F, Masjedi-Arani M, Salavati-Niasari M. Controllable synthesis, characterization and photocatalytic studies on cadmium vanadate nanostructures. Journal of Molecular Liquids, 2016, 220: 566–572
Zhou D, Zhu Z, Liu B. Solvothermal synthesis and characterization of a novel reduced graphene oxide (RGO)/BiVO4/SiO2 nanocomposites. Materials Letters, 2016, 185: 32–35
Han G H, Yang S Z, Huang Y F, Yang J, Chai W C, Zhang R, Chen D L. Hydrothermal synthesis and electrochemical sensing properties of copper vanadate nanocrystals with controlled morphologies. Transactions of Nonferrous Metals Society of China, 2017, 27(5): 1105–1116
Pei L Z, Xie Y K, Pei Y Q, Jiang Y X, Yu H Y, Cai Z Y. Hydrothermal synthesis of Mn vanadate nanosheets and visiblelight photocatalytic performance for the degradation of methyl blue. Materials Research Bulletin, 2013, 48(7): 2557–2565
Kumar J V, Karthik R, Chen S M, Marikkani S, Elangovan A, Muthuraj V. Green synthesis of a novel flower-like cerium vanadate microstructure for electrochemical detection of tryptophan in food and biological samples. Journal of Colloid and Interface Science, 2017, 496: 78–86
Yu Y, Huang S Y, Li Y, Steinmann S N, Yang W, Cao L. Layerdependent electrocatalysis of MoS2 for hydrogen evolution. Nano Letters, 2013, 14(2): 553–558
Bao J, Zhu X, Liu Y, Li W, Yu R. N,N-dimethylformamide-induced synthesis and photoluminescence of CePO4 and Ce0.95PO4:Tb0.05 with sphere-like nanostructures. Materials Letters, 2014, 124: 97–100
Zahir M H, Mohamed S A, Rahman M M, Rehman A U. Hydrothermal synthesis of triangular CeCO3OH particles and photoluminescence properties. Chinese Chemical Letters, 2017, 28(3): 663–669
Xing M, Kong L B, Liu M C, Liu L Y, Kang L, Luo Y C. Cobalt vanadate as highly active, stable, noble metal-free oxygen evolution electrocatalyst. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(43): 18435–18443
Esch T R, Bredow T. Bulk and surface properties of magnesium peroxide MgO2. Applied Surface Science, 2016, 389: 1202–1207
Jiang J, Zhang A, Li L, Ai L. Nickel-cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction. Journal of Power Sources, 2015, 278: 445–451
Cheng N, Xue Y, Liu Q, Tian J, Zhang L, Asiri A M, Sun X. Cu/(Cu (OH)2-CuO) core/shell nanorods array: In-situ growth and application as an efficient 3D oxygen evolution anode. Electrochimica Acta, 2015, 163: 102–106
Miao Y, Ouyang L, Zhou S, Xu L, Yang Z, Xiao M, Ouyang R. Electrocatalysis and electroanalysis of nickel, its oxides, hydroxides and oxyhydroxides toward small molecules. Biosensors & Bioelectronics, 2014, 53(Supplement C): 428–439
Yang Z, Miao Y,Wang T, Liang X, Xiao M, Li W, Yang Y. The selfadsorption of Ni ultrathin layer on glassy carbon surface and their electrocatalysis toward glucose. Journal of the Electrochemical Society, 2014, 161(6): H375–H378
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The authors greatly appreciate the support from the National Natural Science Foundation of China (Grant No. 21305090).
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Hao, M., Xiao, M., Qian, L. et al. Synthesis of cobalt vanadium nanomaterials for efficient electrocatalysis of oxygen evolution. Front. Chem. Sci. Eng. 12, 409–416 (2018). https://doi.org/10.1007/s11705-017-1689-0
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DOI: https://doi.org/10.1007/s11705-017-1689-0