Abstract
Reformer tubes in petrochemical industries are exposed to high temperatures and gas pressure for prolonged period. Exposure of these tubes at severe operating conditions results in change in the microstructure and degradation of mechanical properties which may lead to premature failure. The present work highlights the high-temperature tensile properties and remaining creep life prediction using Larson-Miller parametric technique of service exposed 25Cr35NiNb micro-alloyed reformer tube. Young’s modulus, yield strength, and ultimate tensile strength of the steel are lower than the virgin material and decreases with the increase in temperature. Ductility continuously increases with the increase in temperature up to 1000 °C. Strain hardening exponent increases up to 600 °C, beyond which it starts decreasing. The tensile properties are discussed with reference to microstructure and fractographs. Based on Larson-Miller technique, a creep life of at least 8.3 years is predicted for the service exposed material at 800 °C and 5 MPa.
Similar content being viewed by others
References
C.W. Briggs, Steel Castings Handbook, 4th ed., Steel Founders’ Society of America, Crystal Lake, 1970
A. Alvino, D. Lega, F. Giacobbe, V. Mazzocchi, and A. Rinaldi, Damage Characterization in Two Reformer Heater Tubes After Nearly 10 Years of Service at Different Operative and Maintenance Conditions, Eng. Fail. Anal., 2010, 17, p 1526–1541
T.C. Chou, W. Huang, and R. Paciej, Stress Corrosion Cracking of Pyrotherm Reformer Tube for Steam-Reforming Hydrogen Production, J. Mater. Sci., 1997, 32, p 67–72
J.M. Joubert, W. St-Fleur, J. Sarthou, A. Steckmeyer, and B. Fournier, Equilibrium Characterization and Thermodynamic Calculations on Highly Alloyed Refractory Steels, Calphad, 2014, 46, p 55–61
C.J. Liu and Y. Chen, Variations of the Microstructure and Mechanical Properties of HP40Nb Hydrogen Reformer Tube with Time at Elevated Temperature, Mater. Des., 2011, 32, p 2507–2512
L.T. Li, Y.C. Lin, H.M. Zhou, Y.C. Xia, and Y.Q. Jiang, Modeling the High-Temperature Creep Behaviors of 7075 and 2124 Aluminum Alloys by Continuum Damage Mechanics Model, Comput. Mater. Sci., 2013, 73, p 72–78
A. Ghatak and P.S. Robi, A Comparative Study of Constitutive Equations for the Creep Deformation of HP40Nb Micro-alloyed Steel, Mater. Sci. Eng. A, 2015, 648, p 418–427
A. Ghatak and P.S. Robi, High-Temperature Deformation Behavior of HP40Nb Micro-alloyed Reformer Steel, Metallogr. Microstruct. Anal., 2015, 4, p 508–517
Y.C. Lin, Y.Q. Jiang, H.M. Zhou, and G. Liu, A New Creep Constitutive Model for 7075 Aluminium Alloy Under Elevated Temperatures, J. Mater. Eng. Perform., 2014, 23, p 4350–4357
F.R. Larson and J. Miller, A Time-temperature Relationship for Rupture and Creep Stresses, Trans. ASME, 1952, 74, p 765–771
J. Dong, K. Shin, K.C. Kim, and B.H. Kim, Precipitates in 9-12% Cr Steel After Creep Rupture Test and Determination of Life Time Assessment upon Larson-Miller Parameter, Adv. Sci. Lett., 2011, 4, p 2555–2559
A.H.D. Sorkhabi and F.V. Tahami, Creep Constitutive Equation for 2-Materials of Weldment-304L Stainless Steel, World Acad. Sci. Eng. Technol., 2012, 61, p 710–714
A.K. Ray, K. Diwakar, B.N. Prasad, Y.N. Tiwari, R.N. Ghosh, and J.D. Whittenberger, Long Term Creep-rupture Behaviour of 813 K Exposed 2.25-1Mo Steel Between 773 and 873 K, Mater. Sci. Eng. A, 2007, 454–455, p 124–131
J.E. Indacochea and R.A. Seshadri, An Analysis of Creep Damage in a Welded Low Alloy Steel Rotor, Mater. Sci. Eng. A, 1997, 234–236, p 555–558
A.K. Ray, S. Kumar, G. Krishna, M. Gunjan, B. Goswami, and S.C. Bose, Microstructural Studies and Remnant Life Assessment of Eleven Years Service Exposed Reformer Tube, Mater. Sci. Eng. A, 2011, 529, p 102–112
J. Swaminathan, K. Guguloth, M. Gunjan, P. Roy, and R. Ghosh, Failure Analysis and Remaining Life Assessment of Service Exposed Primary Reformer Heater Tubes, Eng. Fail. Anal., 2008, 15, p 311–331
E. Hamzah, M. Mudang, A.K. Jenq, and M.A. Khattak, High Temperature Creep Behavior of Austenitic Fe-Ni-Cr alloy, Adv. Mater. Res., 2013, 686, p 170–179
A.K. Ray, S.K. Sinha, Y.N. Tiwari, J. Swaminathan, G. Das, S. Chaudhuri, and R. Singh, Analysis of Failed Reformer Tubes, Eng. Fail. Anal., 2003, 10, p 351–362
ASTM E8M-04, Standard Test Methods for Tension Testing of Metallic Materials (metric) (Annual Book of ASTM Standards), ASTM, West Conshohocken, 2004
S. Surendarnath, K. Sankaranarayanasamy, and B. Ravisankar, Workability Study on 99.04% Pure Aluminium Processed by ECAP, Mater. Manuf. Process., 2014, 29, p 691–696
J. Luo and M.Q. Li, Strain Rate Sensitivity and Strain Hardening Exponent During the Isothermal Compression of Ti60 Alloy, Mater. Sci. Eng. A, 2012, 538, p 156–163
J. Deng, Y.C. Lin, J. Chen, S.S. Li, and Y. Ding, Hot Tensile Deformation and Fracture Behaviors of AZ31 Magnesium Alloy, Mater. Des., 2013, 49, p 209–219
ASTM 139, Standard Test Methods for Conducting Creep, Creep-Rupture, and Stress-Rupture Tests of Metallic Materials, ASTM, West Conshohocken, 2003
A. Ghatak and P.S. Robi, Investigation of Micro-structure and Creep Life Analysis of Centrifugally Cast Fe-Cr-Ni Alloy Reformer Tubes, Manuf. Sci. Technol., 2015, 3, p 155–159
A. Ghatak and P.S. Robi, Creep behavior and creep life assessment of HP40Nb reformer steel, Int. J. Res. Eng. Appl. Sci., 2015, 5, p 98–105
R.K. Bansal, A Textbook of Strength of Materials, 4th ed., Laxmi Publications (P) Ltd., New Delhi, 2010, p 749
H39WM, 25/35 Cr/Ni Nb 0.4% C Microalloy Cast Heat Resisting Alloy, Physical Properties, Doncasters Paralloy Ltd, Billingham, 2013
A.K. Jena and M.C. Chaturvedi, The Role of Alloying Elements in the Design of Nickel-Base Superalloys, J. Mater. Sci., 1984, 19, p 3121–3139
A. Ghatak and P.S. Robi, Effect of Temperature on the Microstructure and Hardness of Service Exposed 25Cr35NiNb Reformer Tubes, Trans. Indian Inst. Met., 2016, 69, p 823–827
Acknowledgments
The authors acknowledge Numaligarh Refineries Limited, India for providing the reformer tube necessary for the work. The authors are also grateful to Central Instruments Facility, IIT Guwahati, India for extending the SEM facility.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ghatak, A., Robi, P.S. High-temperature Tensile Properties and Creep Life Assessment of 25Cr35NiNb Micro-alloyed Steel. J. of Materi Eng and Perform 25, 2000–2007 (2016). https://doi.org/10.1007/s11665-016-2016-5
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-016-2016-5