Abstract
It is well known that one way shape memory effect (SME) in Fe-Mn-Si-based shape memory alloys (SMAs) is related to the thermally induced reversion of ε (hexagonal close packed, hcp) stress-induced martensite (SIM) to γ (face centered cubic, fcc) austenite. In the case of a Fe-Mn-Si-Cr-Ni SMA, this reverse martensitic transformation was analyzed in regard to the critical temperature for the beginning of austenite formation (As) in different states characterized by quenching temperature and permanent tensile strain. For this purpose, dynamic mechanical analysis (DMA), dilatometry (DIL), differential thermal analysis (DSC), and optical microscopy (OM) were employed to determine the influence of quenching temperature and permanent tensile straining on SIM reversion to austenite during heating.
Similar content being viewed by others
References
T. Maki, Ferrous Shape Memory Alloys, in: Shape Memory Materials, K. Otsuka and C.M. Wayman, Eds., Cambridge University Press, 1998, pp. 117–132.
A. Sato, E. Chishima, K. Soma and T. Mori, Shape Memory Effect in γ↔ε Transformation in Fe-30Mn-1Si Alloy Single Crystals, Acta Metall. 30, 1982, pp. 1177-1183.
A. Sato, E. Chishima, Y. Yamaji and T. Mori, Orientation and Composition Dependencies of Shape Memory Effect in Fe-Mn-Si Alloys, Acta Metall. 32, 1984, pp. 539-547.
M. Murakami, H. Suzuki and Y. Nakamura, Effect of Si on the Shape Memory Effect of Polycrystalline Fe-Mn-Si Alloys, Trans ISIJ 27, 1987, B-87.
M. Murakami, H. Otsuka, H. Suzuki and S. Matsuda, Effect of Alloying Content, Phase and Magnetic Transformation on the Shape Memory Effect of Fe-Mn-Si Alloys, Trans ISIJ 27, 1987, B-88.
M. Murakami, H. Otsuka and S. Matsuda, Improvement of Shape Memory Effect of Fe-Mn-Si Alloys, Trans ISIJ 27, 1987, B-89.
H. Otsuka, H. Yamada, T. Maruyama, H. Tanahashi, S. Matsuda and M. Murakami, Effects of Alloying Additions on Fe-Mn-Si Shape Memory Alloys, ISIJ Int, 30 1990, pp. 674-679.
S. Kajiwara, Characteristic Features of Shape Memory Effect and Related Transformation Behavior in Fe-Based Alloys, Mater. Sci Eng A, 273-275, 1999, pp. 67-88.
T. Y. Hsu and Xu Zuyao, Martensitic Transformation in Fe-Mn-Si Based Alloys, Mater. Sci Eng A, 273-275, 1999, pp. 494-497.
O. Matsumura, T. Sumi, N. Tamura, K. Sakao, T. Furukawa and H. Otsuka, Pseudoelasticity in an Fe–28Mn–6Si–5Cr Shape Memory Alloy, Mater. Sci Eng A, 279, 2000, pp. 201–206.
T. Sawaguchi, T. Kikuchi and S. Kajiwara, The Pseudoelastic Behavior of Fe–Mn–Si-based Shape Memory Alloys, Containing Nb and C, Smart Mater. Struct. 14, 2005, S317–S322,
J. H. Yang, H. Chen and C. M. Wayman, Development of Fe-Based Shape Memory Alloys Associated with Face-Centered Cubic-Hexagonal Close-Packed Martensitic Transformations: Part I. Shape Memory Behavior, Metall Trans A 23A, 1992, pp. 1431-1437.
Tan Shiming, Lao Jinhai and Yang Shiwei, Two-Way Shape Memory Effect of an Fe-Mn-Si Alloy, Scripta Metall. Mater. 25, 1991, 1119-1121.
T. Sawaguchi, L. G. Bujoreanu, T. Kikuchi, K. Ogawa, M. Koyama and M. Murakami, Mechanism of Reversible Transformation-Induced Plasticity of Fe–Mn–Si Shape Memory Alloys, Scripta Mater 59, 2008, pp. 826–829.
N. Stanford, D. P. Dunne and H. Li, Re-examination of the Effect of NbC Precipitation on Shape Memory in Fe-Mn-Si-Based Alloys, Scripta Mater. 58, 2008, pp. 583-586.
Yuhua Wen, Ning Li and Mingjing Tu, Effect of Quenching Temperature on Recovery Stress of Fe-18Mn-5Si-8Cr-4Ni Alloy, Scripta mater. 44, 2001, pp. 1113–1116.
L. G. Bujoreanu, V. Dia, S. Stanciu, M. Susan and C. Baciu, Study of the Tensile Constrained-Recovery Behavior of a Fe-Mn-Si Shape Memory Alloy, Eur. Phys. J. Special Topics, 158, 2008, pp. 15-20.
J. H. Yang and C. M. Wayman, Self-Accommodation and Shape Memory Mechanism of ε-Martensite – I. Experimental Observations, Mater. Charact. 28, 1992, pp. 23-35.
S. Kajiwara, D. Liu, T. Kikuchi and N. Shinya, Remarkable Improvement of Shape Memory Effect in Fe-Mn-Si Based Shape Memory Alloys by Producing NbC Precipitates, Scripta Mater. 44, 2001, pp. 2809–2814.
Y. H. Wen, W. Zhang, N. Li, H. B. Peng and L.R. Xiong, Principle and Realization of Improving Shape Memory Effect in Fe-Mn-Si-Cr-Ni Alloy through Aligned Precipitations of Second-Phase Particles, Acta Mater. 55, 2007, 6526-6534.
J. H. Yang, H. Chen and C. M. Wayman, Development of Fe-Based Shape Memory Alloys Associated with Face-Centered Cubic-Hexagonal Close-Packed Martensitic Transformations: Part II. Transformation Behavior, Metall Trans A 23A, 1992, pp. 1439-1444.
N. Bergeon, G. Guenin and C. Esnouf, Microstructural Analysis of the Stress-Induced ε Martensite in a Fe-Mn-Si-Cr-Ni Shape memory Alloy. Part II: Transformation Reversibility, Mater. Sci Eng A, 242, 1998, pp. 87-95.
Y.H. Wen, N. Li and L.R. Xiong, Composition Design Principles for Fe–Mn–Si–Cr–Ni Based Alloys with Better Shape Memory Effect and Higher Recovery Stress, Mater. Sci Eng A, 407, 2005, pp. 31-35.
Huijun Li, D. Dunne and N. Kennon, Factors Influencing Shape Memory Effect and Phase Transformation Behaviour of Fe-Mn-Si Based Shape Memory Alloys, Mater. Sci Eng A, 273-275, 1999, pp. 517-523.
N. Stanford, D.P. Dunne, Thermo-Mechanical Processing and the Shape Memory Effect in an Fe–Mn–Si-Based Shape Memory Alloy, Mater. Sci Eng A, 422, 2006, pp. 352–359.
Lin Chengxin, Wang Guixin, Wu Yandong, Liu Qingsuo, Zhang Jianjun, Effect of Addition of V and C on Strain Recovery Characteristics in Fe–Mn–Si Alloy, Mater. Sci Eng A, 438–440, 2006, pp. 808–811.
T. Sawaguchi, L. G. Bujoreanu, T. Kikuchi, K. Ogawa and F. Yin, Effects of Nb and C in Solution and in NbC Form on the Transformation-related Internal Friction of Fe-17 Mn (mass. %) Alloys, ISIJ Int 48(1), 2008, pp. 99-106.
J. E. Bidaux, R. Schaller and W. Benoit, Study of the h.c.p-f.c.c. Phase Transition in Cobalt by Acoustic Measurements, Acta Metall., 37, 1989, pp. 803-811.
J. Van Humbeeck, J. Stoiber, L. Delaey and Rolf Gotthardt, The High Damping Capacity of Shape Memory Alloys, Z. Metallkd. 86, 1995, pp. 176-183.
A. K. De, N. Cabanas and B. C. De Cooman, Fcc-hcp Transformation-Related Internal Friction in Fe-Mn Alloys, Z. Metallkd. 93, 2002, pp. 228-235.
J. F. Wan, S. P. Chen, T. Y. Hsu and Y. N. Huang, Modulus Softening during the γ → ε Martensitic Transformation in Fe-25 Mn-6 Si-5 Cr-0.14 N Alloy, Mater. Sci Eng A, 438–440, 2006, pp. 887–890.
A. Sato, K. Ozaki, Y. Watanabe and T. Mori, Internal Friction due to ε → γ Reverse Transformation in an Fe-Mn-Si-Cr Shape Memory Alloy, Mater. Sci Eng A, 101, 1988, pp. 25–30.
T. Sawaguchi, T. Kikuchi, F. Yin, and S. Kajiwara, Internal Friction of an Fe-28Mn-6Si-5Cr-0.5NbC Shape Memory Alloy, Mater. Sci Eng A, 438-440, 2006, pp. 796–799.
Bhadeshia, H. K. D. H., Bainite in steels, second edition, IOM Communications Ltd, 2001.
N. Van Caenegem, L. Duperez, K. Verbeken, D. Segers, Y. Houbaert, Stress related to the shape memory effect in Fe-Mn-Si-based shape memory alloys, Mater. Sci Eng A, 481-482, 2008, pp. 183-189.
Acknowledgments
This study was financially supported by UEFISCU by means of the research Grant PN II-ID 301-PCE-2007-1, Contract no. 279/01.10.2007. Special thanks are due to Dr. Takahiro Sawaguchi, NIMS Tsukuba, for fruitful scientific discussions.
Author information
Authors and Affiliations
Corresponding author
Additional information
This article is an invited paper selected from presentations at Shape Memory and Superelastic Technologies 2008, held September 21-25, 2008, in Stresa, Italy, and has been expanded from the original presentation.
Rights and permissions
About this article
Cite this article
Bujoreanu, L.G., Stanciu, S., Comaneci, R.I. et al. Factors Influencing the Reversion of Stress-induced Martensite to Austenite in a Fe-Mn-Si-Cr-Ni Shape Memory Alloy. J. of Materi Eng and Perform 18, 500–505 (2009). https://doi.org/10.1007/s11665-009-9499-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-009-9499-2