Abstract
Nanostructured Cr-doped CdO thin films were deposited on glass substrates by reactive direct current magnetron sputtering and post-annealed in vacuum from 200°C to 500°C. X-ray diffraction studies confirmed that the films exhibit cubic nature with preferential orientation along the (111) plane. The crystallite size, lattice parameters, unit cell volume and strain in the films were determined from x-ray diffraction analysis. The surface morphology of the films has been characterized by field emission scanning electron microscopy and atomic force microscopy. The electrical properties of the Cr-doped CdO thin films were measured by using a four-probe method and Hall effect system. The lowest electrical resistivity of 2.20 × 10−4 Ω cm and a maximum optical transmittance of 88% have been obtained for the thin films annealed at 500°C. The optical band gap of the films decreased from 2.77 eV to 2.65 eV with the increase of annealing temperature. The optical constants, packing density and porosity of Cr-doped CdO thin films were also evaluated from the transmittance spectra.
Similar content being viewed by others
References
M. Azizar Rahman and M.K.R. Khan, Mater. Sci. Semicond. Process. 24, 26 (2014).
Z. Zhao, D.L. Morel, and C.S. Ferekides, Thin Solid Films 413, 203 (2002).
T.K. Subramanyam, B. Srinivasulu Naidu, and S. Uthanna, Appl. Surf. Sci. 169–170, 529 (2001).
B. Sahin, Y. Gulen, F. Bayansal, H.A. Cetinkara, and H.S. Guder, Superlattices Microstruct. 65, 56 (2014).
A.A. Dakhel, Phys. Status Solidi (a) 205, 2704 (2008).
R.K. Gupta, K. Ghosh, R. Patel, S.R. Mishra, and P.K. Kahol, Curr. Appl. Phys. 9, 673 (2009).
A.A. Dakhel, Thin Solid Films 518, 1712 (2010).
R.D. Shannon, Acta Cryst. A 32, 751 (1976).
C.H. Champness and C.H. Chan, Sol. Energy Mater. Sol. Cells 37, 75 (1995).
F.P. Koffyberg, Phys. Rev. B 13, 4470 (1976).
A.J. Varkey and A.F. Fort, Thin Solid Films 239, 211 (1994).
R. Ferro, J.A. Rodriguez, O. Vigil, A. Morales-Acevedo, and G. Contreras-Puente, Phys. Status Solidi (a) 177, 477 (2000).
M. Yan, M. Lane, C.R. Kannewurf, and R.P.H. Chang, Appl. Phys. Lett. 78, 2342 (2001).
A.B.M.A. Ashrafi, H. Kumano, I. Suemune, Y.W. Ok, and T.Y. Seong, Appl. Phys. Lett. 79, 470 (2001).
G. Phatak and R. Lal, Thin Solid Films 245, 17 (1994).
I.M. Ocampo, A.M. Ferandez, and P.J. Sabastian, Semicond. Sci. Technol. 8, 750 (1993).
M. Labeau, V. Reboux, D. Dhahri, and J.C. Joubert, Thin Solid Films 136, 257 (1986).
B. Hymavathi, B. Rajesh Kumar, and T. Subba Rao, Procedia Mater. Sci. 6, 668 (2014).
B. Hymavathi, B. Rajesh Kumar, and T. Subba Rao, Procedia Mater. Sci. 10, 285 (2015).
B. Rajesh Kumar and T. Subba Rao, in AIP Conference Proceedings (2014), pp. 118–122
T. Singh, D.K. Pandya, and R. Singh, Mater. Chem. Phys. 130, 1366 (2011).
A. Abdolahzadeh Ziabari and F.E. Ghodsi, J. Mater. Sci. Mater. Electron. 23, 1628 (2012).
A.A. Dakhel, Bull. Mater. Sci. 36, 819 (2013).
T. Singh, D.K. Pandya, and R. Singh, Mater. Sci. Eng. B 176, 945 (2011).
I. Akyuz, S. Kose, E. Ketenci, V. Bilgin, and F. Atay, J. Alloys Compd. 509, 1947 (2011).
Z.B. Fang, Z.J. Yan, Y.S. Tan, X.Q. Liu, and Y.Y. Wang, Appl. Surf. Sci. 241, 303 (2005).
A.N. Banerjee, S. Kundoo, and K.K. Chattopadhyay, Thin Solid Films 440, 5 (2003).
F.A. Kronger and H.J. Vink, J. Chem. Phys. 22, 250 (1954).
M.H. Suhail, I.M. Ibrahim, and G. Mohan Rao, J. Electron Devices 13, 965 (2012).
B. Rajesh Kumar and T. Subba Rao, Appl. Surf. Sci. 265, 169 (2013).
M. Caglar, S. Ilican, Y. Caglar, and F. Yakuphanoglu, J. Mater. Sci. Mater. Electron. 19, 704 (2008).
R.R. Salunkhe, D.S. Dhawale, T.P. Gujar, and C.D. Lokhande, Mater. Res. Bull. 44, 364 (2009).
S. Aksoy, Y. Caglar, S. Ilican, and M. Caglar, Int. J. Hydrogen Energy 34, 5191 (2009).
Y.-F. Kuo and T.-Y. Tseng, Mater. Chem. Phys. 61, 244 (1999).
J. Lv, K. Huang, X. Chen, J. Zhu, C. Cao, X. Song, and Z. Sun, Opt. Commun. 284, 2905 (2011).
W.L. Bragg and A.B. Pippard, Acta Crystallogr. 6, 865 (1953).
H.A. Mcleod, J. Vac. Sci. Technol. A 4, 418 (1986).
H.K. Pulker, Appl. Opt. 18, 1969 (1979).
G.M. Hale and M.R. Querry, Appl. Opt. 12, 555 (1973).
H. Koch, Phys. Status Solidi 12, 533 (1965).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hymavathi, B., Rajesh Kumar, B. & Subba Rao, T. Post-Annealing Effects on Surface Morphological, Electrical and Optical Properties of Nanostructured Cr-Doped CdO Thin Films. J. Electron. Mater. 47, 503–511 (2018). https://doi.org/10.1007/s11664-017-5799-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-017-5799-8