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Impurities Removal from Metallurgical-Grade Silicon by Combined Sn-Si and Al-Si Refining Processes

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Abstract

The purification of metallurgical-grade silicon (MG-Si) by combined solvent refining processes has been studied. The final high-purity silicon was recovered through Sn-Si refining and Al-Si refining processes in sequence after acid leaching, and the removal mechanism of impurities was explored. Inductively coupled plasma (ICP) chemical analysis revealed the concentrations of main impurities including B and P, and typical metallic impurities except for solvents Sn and Al were reduced to below 1 ppmw. The final removal efficiencies of B and P were 97.7 pct and 99.8 pct, respectively, and those of most metallic impurities were above 99.9 pct. SEM analysis showed that P-containing phases (Al-Ca-Mg-Si-P and Al-Si-P) formed on the surface of refined Si after Sn-Si refining and Al-Si refining, which was confirmed to be the main approach for P removal. It was also found that the formation of binary silicide such as Fe3Si7 and Mn11Si19 or multicomponent phases such as Ca-Mg-Si phase occurred during the solvent refining process, and they segregated on the grain boundaries in Si or attached to the surface of Si, which led to high removal efficiency of metallic impurities by the solvent refining process.

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Acknowledgments

This work was financially supported by National Natural Science Foundation of China (51174187) and National Key Technologies R&D Program (2011BAE03B01).

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Authors and Affiliations

  1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, P.R. China

    Lei Hu (Graduate Student), Zhi Wang (Professor), Xuzhong Gong (Doctor), Zhancheng Guo (Professor) & Hu Zhang (Graduate Student)

  2. Graduate University of Chinese Academy of Sciences, Beijing, 100049, P.R. China

    Lei Hu (Graduate Student)

  3. State Key Laboratory of Advanced Metallurgy, University of Science and Technology, Beijing, 100083, P.R. China

    Zhancheng Guo (Professor)

  4. Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming, 65000, P.R. China

    Hu Zhang (Graduate Student)

Authors
  1. Lei Hu
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  2. Zhi Wang
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  3. Xuzhong Gong
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  4. Zhancheng Guo
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Correspondence to Zhi Wang.

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Hu, L., Wang, Z., Gong, X. et al. Impurities Removal from Metallurgical-Grade Silicon by Combined Sn-Si and Al-Si Refining Processes. Metall Mater Trans B 44, 828–836 (2013). https://doi.org/10.1007/s11663-013-9850-8

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  • DOI: https://doi.org/10.1007/s11663-013-9850-8

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