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AgCrTiS4: Synthesis, Properties, and Analytical Application

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Abstract

AgCrTiS4 was obtained by the solid-state synthesis method. The crystal structure of the quaternary phase was investigated by the X-ray powder method and is described in a trigonal structure (space group P \( \bar 3 \) m1) with the lattice parameters a = 0.34459 (1) nm and c = 0.64549(3) nm. Atomic parameters were refined in the anisotropic approximation (R I  = 0.0992). The possibility of the use of this compound as an electroactive substance in carbon paste electrodes for the measurement of Ag+ ions was investigated. The optimal electrode composition, determination limit (3 × 10−6 mol L−1), selectivity coefficient for major interfering elements, pH range, and practical applicability of such electrodes were established.

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References

  1. N.M. Kuzmin: Z. Anal. Khim., 1999, vol. 54, pp. 902–08

    Google Scholar 

  2. O.M. Petrukhin: Zavod. Lab., 2000, vol. 66, pp. 3–10

    Google Scholar 

  3. Y.G. Vlasov, Y.Y. Yermolenko, I.A. Popov, Y. El’-Marug, V.G. Khoroshev, and V.V. Kolodnikov: Z. Anal. Khim., 1997, vol. 52, pp. 81–85

    CAS  Google Scholar 

  4. Y.G. Vlasov and E.A. Bychkov: Ion-Selective Electrode Rev., 1987, vol. 9, pp. 5–24

    CAS  Google Scholar 

  5. Y.G. Vlasov: Fres. Z. Anal. Khim, 1989, vol. 335, pp. 92–99

    Article  CAS  Google Scholar 

  6. Y.G. Vlasov, E.A. Bychkov, and A.V. Legin: Talanta, 1994, vol. 41, pp. 1059–63

    Article  CAS  Google Scholar 

  7. A.V. Legin, E.A. Bychkov, and Y.G. Vlasov: Sen. Actuators B, 1995, vols. 24–25, pp. 309–11

    Article  Google Scholar 

  8. T.V. Velikanova, A.N. Titov, and N.M. Shishmintseva: Z. Anal. Khim., 2000, vol. 55, pp. 1172–75

    Google Scholar 

  9. T.V. Velikanova, A.N. Titov: Z. Anal. Khim., 2001, vol. 56, pp. 65–68

    Google Scholar 

  10. L.G. Akselrud, P.Y. Zavalij, Y.N. Grin’, V.K. Pecharski, B. Baumgartner, and E. Wolfel: Mater. Sci. Forum., 1993, vol. 133, p. 335

    Article  Google Scholar 

  11. O.V. Parasyuk, L.D. Gulay, Y.E. Romanyuk, and I.D. Olekseyuk: J. Alloys Compd., 2003, vol. 348, pp. 157–66

    Article  CAS  Google Scholar 

  12. N. Wiberg: Lehrbuch Anorganischen Chemie, Walter de Gruyter, Berlin, 1995, pp. 1838–40

    Google Scholar 

  13. V.S. Urusov: Theoretical Crystallography, MGU, Moskow, 1987, pp. 114–16

    Google Scholar 

  14. A.G. Gerards, H. Roede, R.J. Haange, B.A. Boukamp, and G.A. Wiegers: Synth. Met., 1984, vol. 10, pp. 51–56

    Article  CAS  Google Scholar 

  15. K. Kamman: Working with Ion-Selective Electrodes, Mir, Moscow, 1980, pp. 205–08

  16. E. Bakker, E. Pretsch, and P. Buhlmann: Anal. Chem., 2000, vol. 72, pp. 1127–33

    Article  CAS  Google Scholar 

  17. W.E. Morf: The Principles of Ion-Selective Electrodes and of Membrane Transport, Akademia Kiado, Budapest, 1981, pp. 132–37

    Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Volyn State University, 43021, Lutsk, Ukraine

    A.V. Laganovsky & Z.O. Kormosh

  2. Department of General and Inorganic Chemistry, Volyn State University, 43021, Lutsk, Ukraine

    V.P. Sachanyuk & O.V. Parasyuk

  3. Department of General and Inorganic Chemistry, Ivan Franko National University of Lviv, 79005, Lviv, Ukraine

    A.O. Fedorchuk

Authors
  1. A.V. Laganovsky
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  2. Z.O. Kormosh
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  3. A.O. Fedorchuk
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  4. V.P. Sachanyuk
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  5. O.V. Parasyuk
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Corresponding author

Correspondence to Z.O. Kormosh.

Additional information

Manuscript submitted June 1, 2007.

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Laganovsky, A., Kormosh, Z., Fedorchuk, A. et al. AgCrTiS4: Synthesis, Properties, and Analytical Application. Metall Mater Trans B 39, 155–159 (2008). https://doi.org/10.1007/s11663-007-9121-7

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  • DOI: https://doi.org/10.1007/s11663-007-9121-7

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