Abstract
The present research work revolves around the evaluation of the elimination of the cationic dye methylene blue (MB) from an aqueous solution by the exploitation of natural clay (TMG) from South-East Morocco. Several physicochemical techniques were used to characterize our TMG adsorbate, namely, X-ray diffraction, Fourier transform infrared absorption spectroscopy, differential thermal analysis, thermal gravimetric analysis, and zero charge point (pHpzc). The morphological properties and elemental composition of our material were identified using scanning electron microscopy coupled with an energy-dispersive X-ray spectrometer. The batch technique was used under different operating conditions to produce quantitative adsorption, namely, the amount of adsorbent, dye concentration, contact time, pH, and solution temperature. The maximum adsorption capacity of MB on TMG was 81.185 mg g−1 for a concentration of 100 mg L−1 MB at pHinitial = 6.43 (no initial adjustment of the pH-value was performed), temperature 293 K, and 1 g L−1 adsorbent. The adsorption data were examined by Langmuir, Freundlich, and Temkin isotherms. The Langmuir isotherm provides the best correlation with the experimental data, and the pseudo-second-order kinetic model is more appropriate for the adsorption of the MB dye. The thermodynamic study of MB adsorption indicates that the process is physical, endothermic, and spontaneous. The Box-Behnken method was applied to identify the optimal conditions for MB removal in the design of batch experiments. The parameters examined result in >99% removal. The TMG material’s regeneration cycles and low cost ($0.393 per gram) show that it is both environmentally friendly and very effective for dye removal in the various textile sectors.
Similar content being viewed by others
Data availability
ot applicable
References
Abdel Ghafar HH, Radwan EK, El-Wakeel ST (2020) Removal of hazardous contaminants from water by natural and zwitterionic surfactant-modified clay. ACS Omega 5:6834–6845. https://doi.org/10.1021/acsomega.0c00166
Adeniyi FI, Ogundiran MB, Hemalatha T, Hanumantrai BB (2020) Characterization of raw and thermally treated Nigerian kaolinite-containing clays using instrumental techniques. SN Appl Sci 2:821. https://doi.org/10.1007/s42452-020-2610-x
Ağtaş M, Dilaver M, Koyuncu İ (2021) Ceramic membrane overview and applications in textile industry: a review. Water Sci Technol 84(5):1059–1078. https://doi.org/10.2166/wst.2021.290
Benhiti R, Ait Ichou A, Zaghloul A, Aziam R, Carja G, Zerbet M, Sinan F, Chiban M (2020) Synthesis, characterization, and comparative study of MgAl-LDHs prepared by standard coprecipitation and urea hydrolysis methods for phosphate removal. Environ Sci Pollut Res 27:45767–45774. https://doi.org/10.1007/s11356-020-10444-5
Benjelloun M, Miyah Y, Bouslamti R, Nahali L, Mejbar F, Lairini S (2022) The fast-efficient adsorption process of the toxic dye onto shells powders of walnut and peanut: experiments, equilibrium, thermodynamic, and regeneration studies. Chem Africa 5:375–393. https://doi.org/10.1007/s42250-022-00328-1
Bentahar Y, Draoui K, Hurel C, Ajouyed O, Khairoun S, Marmier N (2019) Physico-chemical characterization and valorization of swelling and non-swelling Moroccan clays in basic dye removal from aqueous solutions. J. Afr. Earth Sci 154:80–88. https://doi.org/10.1016/j.jafrearsci.2019.03.017
Bingül Z (2022) Determination of affecting parameters on removal of methylene blue dyestuff from aqueous solutions using natural clay: Isotherm, kinetic, and thermodynamic studies. J Mol Struct 1250:131729. https://doi.org/10.1016/j.molstruc.2021.131729
Blanchard G, Maunaye M, Martin G (1984) Removal of heavy metals from waters by means of natural zeolites. Water Res 18(12):1501–1507. https://doi.org/10.1016/0043-1354(84)90124-6
Carnut L (2020) Theorizing about performance evaluation of health systems from the perspective of civil society. JSS 8:394–411. https://doi.org/10.4236/jss.2020.86030
Dabagh A, Bagui A, Abali M, Aziam R, Chiban M, Sinan F, Zerbet M (2021) Increasing the adsorption efficiency of methylene blue by acid treatment of the plant Carpobrotus edulis. Chem Africa 4:585–598. https://doi.org/10.1007/s42250-021-00233-z
Dehmani Y, Sellaoui L, Alghamdi Y, Lainé J, Badawi M, Amhoud A, Bonilla-Petriciolet A, Lamhasni T, Abouarnadasse S (2020) Kinetic, thermodynamic and mechanism study of the adsorption of phenol on Moroccan clay. J Mol Liq 312:113383. https://doi.org/10.1016/j.molliq.2020.113383
Doltade SB, Yadav YJ, Jadhav NL (2022) Industrial wastewater treatment using oxidative integrated approach. SAJCE 40:100–106. https://doi.org/10.1016/j.sajce.2022.02.004
Dra A, Tanji K, Arrahli A, Iboustaten EM, El Gaidoumi A, Kherchafi A, Benabdallah AC, Kherbeche A (2020) Valorization of Oued Sebou natural sediments (Fez-Morocco Area) as adsorbent of methylene blue dye: kinetic and thermodynamic study. Sci World J 2020:1–8. https://doi.org/10.1155/2020/2187129
El Gaayda J, Ezzahra Titchou F, Oukhrib R, Karmal I, Abou Oualid H, Berisha A, Zazou H, Swanson C, Hamdani M, Ait Akbour R (2022) Removal of cationic dye from coloured water by adsorption onto hematite-humic acid composite: Experimental and theoretical studies. Sep Purif Technol 288:120607. https://doi.org/10.1016/j.seppur.2022.120607
Esvandi Z, Foroutan R, Peighambardoust SJ, Akbari A, Ramavandi B (2020) Uptake of anionic and cationic dyes from water using natural clay and clay/starch/MnFe2O4 magnetic nanocomposite. Surf Interfaces 21:100754. https://doi.org/10.1016/j.surfin.2020.100754
Ethaib S, Zubaidi SL (2020) Removal of methylene blue dye from aqueous solution using kaolin. IOP Conf Ser Mater Sci Eng 928:022030. https://doi.org/10.1088/1757-899X/928/2/022030
Ghosh I, Kar S, Chatterjee T, Bar N, Das SK (2021) Removal of methylene blue from aqueous solution using Lathyrus sativus husk: adsorption study, MPR and ANN modelling. PSEP 149:345–361. https://doi.org/10.1016/j.psep.2020.11.003
Goswami B, Das C, Mahanta D (2021) Effect of dye-adsorption on Fe3O4-polypyrrole nanocomposite as electrode material in electrochemical capacitors. J Energy Storage 44:103429. https://doi.org/10.1016/j.est.2021.103429
Hicham Z, Bencheqroun Z, El Mrabet I, Kachabi M, Nawdali M, Neves I (2019) Removal of basic dyes from aqueous solutions by adsorption onto Moroccan clay (Fez City). Mediterr J Chem 8(2):158–167. https://doi.org/10.13171/mjc8319050803hz
Iaich S, Miyah Y, Elazhar F, Lagdali S, El-Habacha M (2021) Low-cost ceramic microfiltration membranes made from Moroccan clay for domestic wastewater and Congo Red dye treatment. DWT 235:251–271. https://doi.org/10.5004/dwt.2021.27618
Jaramillo-Fierro X, González S, Montesdeoca-Mendoza F, Medina F (2021) Structuring of ZnTiO3/TiO2 adsorbents for the removal of methylene blue, using zeolite precursor clays as natural additives. Nanomaterials 11(4):898. https://doi.org/10.3390/nano11040898
Kannaujiya MC, Kumar R, Mandal T, Mondal MK (2021) Experimental investigations of hazardous leather industry dye (Acid Yellow 2GL) removal from simulated wastewater using a promising integrated approach. PSEP 155:444–454. https://doi.org/10.1016/j.psep.2021.09.040
Kassa AE, Shibeshi NT, Tizazu BZ (2022) Characterization and optimization of calcination process parameters for extraction of aluminum from Ethiopian kaolinite. Int J Chem Eng 2022:1–18. https://doi.org/10.1155/2022/5072635
Kausar A, Sher F, Hazafa A, Javed A, Sillanpää M, Iqbal M (2020) Biocomposite of sodium-alginate with acidified clay for wastewater treatment: kinetic, equilibrium and thermodynamic studies. Int J Biol Macromol 161:1272–1285. https://doi.org/10.1016/j.ijbiomac.2020.05.266
Khan MI (2020) Adsorption of methylene blue onto natural Saudi Red Clay: isotherms, kinetics and thermodynamic studies. Mater Res Express 7:055507. https://doi.org/10.1088/2053-1591/ab903c
Khelifi S, Mallah B, Trabelsi Ayadi M, Oueslati MH, Sbihi HM, Ayari F (2020) Performance of a local clay deposit in adsorptive and photochemical removal of Acridine Orange dye and DNA indicator from wastewater. DWT 206:396–406. https://doi.org/10.5004/dwt.2020.26304
Kuang Y, Zhang X, Zhou S (2020) Adsorption of methylene blue in water onto activated carbon by surfactant modification. Water 12(2):587. https://doi.org/10.3390/w12020587
Kumar R, Chakrabortty S, Pal P (2015) Membrane-integrated physico-chemical treatment of coke-oven wastewater: transport modelling and economic evaluation. Environ Sci Pollut Res 22:6010–6023. https://doi.org/10.1007/s11356-014-3787-6
Li Y, Wang S, Shen Z, Li X, Zhou Q, Sun Y, Wang T, Liu Y, Gao Q (2020) Gradient adsorption of methylene blue and crystal violet onto compound microporous silica from aqueous medium. ACS Omega 5(43):28382–28392. https://doi.org/10.1021/acsomega.0c04437
Lin Y, Ma J, Liu W, Li Z, He K (2019) Efficient removal of dyes from dyeing wastewater by powder activated charcoal/titanate nanotube nanocomposites: adsorption and photoregeneration. Environ Sci Pollut Res 26:10263–10273. https://doi.org/10.1007/s11356-019-04218-x
Liu S, Ge H, Wang C, Zou Y, Liu J (2018) Agricultural waste/graphene oxide 3D bio-adsorbent for highly efficient removal of methylene blue from water pollution. Sci Total Environ 628:959–968. https://doi.org/10.1016/j.scitotenv.2018.02.134
Mittal H, Al Alili A, Morajkar PP, Alhassan SM (2021) Graphene oxide crosslinked hydrogel nanocomposites of xanthan gum for the adsorption of crystal violet dye. J Mol Liq 323:115034. https://doi.org/10.1016/j.molliq.2020.115034
Miyah Y, Benjelloun M, Lahrichi A, Mejbar F, Iaich S, El Mouhri G, Kachkoul R, Zerrouq F (2021) Highly-efficient treated oil shale ash adsorbent for toxic dyes removal: kinetics, isotherms, regeneration, cost analysis and optimization by experimental design. J Environ Chem Eng 9(6):106694. https://doi.org/10.1016/j.jece.2021.106694
Miyah Y, Lahrichi A, Idrissi M, Khalil A, Zerrouq F (2018) Adsorption of methylene blue dye from aqueous solutions onto walnut shells powder: equilibrium and kinetic studies. Surf Interfaces 11:74–81. https://doi.org/10.1016/j.surfin.2018.03.006
Muhammed NS, Olayiwola T, Elkatatny S (2021) A review on clay chemistry, characterization and shale inhibitors for water-based drilling fluids. J Pet Sci Eng 206:109043. https://doi.org/10.1016/j.petrol.2021.109043
Ndabambi M, Kwon J-H (2020) Benzalkonium ion sorption to peat and clays: relative contributions of ion exchange and van der Waals interactions. Chemosphere 247:125924. https://doi.org/10.1016/j.chemosphere.2020.125924
Necibi MC, Amar I, Draoui K, Mahjoub B (2021) Current situation and future prospects for the production and utilization of sorbing materials for water depollution in North Africa. Sorbents Mater Controll Environ Pollut 49–71. https://doi.org/10.1016/B978-0-12-820042-1.00023-7
Oussalah A, Boukerroui A, Aichour A, Djellouli B (2019) Cationic and anionic dyes removal by low-cost hybrid alginate/natural bentonite composite beads: adsorption and reusability studies. In J Biol Macromol 124:854–862. https://doi.org/10.1016/j.ijbiomac.2018.11.197
Perez JJ, Villanueva ME, Sánchez L, Ollier R, Alvarez V, Copello GJ (2020) Low cost and regenerable composites based on chitin/bentonite for the adsorption potential emerging pollutants. Appl Clay Sci 194:105703. https://doi.org/10.1016/j.clay.2020.105703
Pérez-Villarejo L, Eliche-Quesada D, Martín-Pascual J, Martín-Morales M, Zamorano M (2020) Comparative study of the use of different biomass from olive grove in the manufacture of sustainable ceramic lightweight bricks. Constr Build Mater 231:117103. https://doi.org/10.1016/j.conbuildmat.2019.117103
Qin L, Pan Y, Xie F, Yu L, Huai R, Yang L, Zhang D, Zhou Z (2021) Rapid and selective adsorption capacity towards cationic dye with an anionic functionalized Anderson-type polyoxometalate. Inorg Chem Commun 133:108988. https://doi.org/10.1016/j.inoche.2021.108988
Rashid R, Shafiq I, Akhter P, Iqbal M. J, Hussain M (2021) A state-of-the-art review on wastewater treatment techniques: the effectiveness of adsorption method. Environ Sci Pollut Res 28: 9050–9066. https://doi.org/10.1007/s11356-021-12395-x
Rehman MU, Manan A, Uzair M, Khan AS, Ullah A, Ahmad AS, Wazir AH, Qaz I, Khan MA (2021) Physicochemical characterization of Pakistani clay for adsorption of methylene blue: Kinetic, isotherm and thermodynamic study. Mater Chem Phys 269:124722. https://doi.org/10.1016/j.matchemphys.2021.124722
Revellame ED, Fortela DL, Sharp W, Hernandez R, Zappi ME (2020) Adsorption kinetic modeling using pseudo-first order and pseudo-second order rate laws: a review. Chem Eng J 1:100032. https://doi.org/10.1016/j.clet.2020.100032
Rodrigues AE, Silva CM (2016) What’s wrong with Lagergreen pseudo first order model for adsorption kinetics? Chem Eng J 306:1138–1142. https://doi.org/10.1016/j.cej.2016.08.055
Salh DM, Aziz BK, Kaufhold S (2020) High adsorption efficiency of Topkhana natural clay for methylene blue from medical laboratory wastewater: a linear and nonlinear regression. Silicon 12:87–99. https://doi.org/10.1007/s12633-019-00100-0
Sirirak J (2020) Preparation and characterization of lake pigments from sappan wood using Thai local clays. J Met Mater Miner 30(1):20–28. https://doi.org/10.14456/JMMM.2020.3
Sivakumar R, Lee NY (2022) Adsorptive removal of organic pollutant methylene blue using polysaccharide-based composite hydrogels. Chemosphere 286:131890. https://doi.org/10.1016/j.chemosphere.2021.131890
Viscusi G, Lamberti E, Gorrasi G (2022) Design of a hybrid bio-adsorbent based on Sodium Alginate/Halloysite/Hemp hurd for methylene blue dye removal: kinetic studies and mathematical modeling. Colloids Surf A: Physicochem Eng Asp 633:127925. https://doi.org/10.1016/j.colsurfa.2021.127925
Wei X, Chen D, Wang L, Ma Y, Yang W (2022) Carboxylate-functionalized hollow polymer particles modified polyurethane foam for facile and selective removal of cationic dye. Appl Surf Sci 579:152153. https://doi.org/10.1016/j.apsusc.2021.152153
Zaghloul A, Benhiti R, Ait Ichou A, Carja G, Soudani A, Zerbet M, Sinan F, Chiban M (2021) Characterization and application of MgAl layered double hydroxide for methyl orange removal from aqueous solution. Mater Today: Proc 37:3793–3797. https://doi.org/10.1016/j.matpr.2020.07.676
Author information
Authors and Affiliations
Contributions
M. El-Habacha: writing — original draft, review, and editing; A. Dabagh: review and editing; S. Lagdali: review and editing; Y. Miyah: review and editing, conceptualization, data analysis; G. Mahmoudy: review and editing; F. Sinan: critical feedback and revision; M. Chiban: review and editing; S. Iaich: co-supervision, writing — original draft; M. Zerbet: supervision, writing — original draft.
Corresponding author
Ethics declarations
Ethics approval
Not applicable
Consent to participate
Not applicable
Consent for publication
Not applicable
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Tito Roberto Cadaval Jr
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
El-Habacha, M., Dabagh, A., Lagdali, S. et al. An efficient and adsorption of methylene blue dye on a natural clay surface: modeling and equilibrium studies. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-27413-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11356-023-27413-3