Abstract
Landfill leachate contains a high concentration of organic pollutants that are active agents in water pollution. This study was conducted to remove various pollutants from landfill leachate through electrolysis and activated carbon (AC) treatments. A simple electrolytic reactor was designed to investigate the removal efficiency of these treatments for biochemical oxygen demand (BOD), chemical oxygen demand (COD), total suspended solids (TSSs), and total dissolved solids (TDSs) from landfill leachate at different electric current densities (CDs) and retention times (RTs). The results showed that the highest removal efficiencies for BOD and COD were 75.6 and 57 %, respectively, under a 7-V current for 4 h. It was also found that BOD, COD, TSS, and TDS removal efficiencies improved in proportion to an increase in CD and RT. However, pH gradually increased with an increase in CD and RT. A number of treated leachate samples were further polished by AC filtration to compare the effect of this additional process on the removal of color, BOD, COD, TSS, and TDS. This secondary treatment resulted in a higher removal of color and other pollutants than electrolysis alone. At 4 h RT, the BOD removal efficiency was 54.6 % at 3 V and 66.4 % at 5 V, and the efficiency increased to 61.5 and 70.5 %, respectively, after treatment by AC filtration. Under the same conditions, COD removal efficiency increased from 7.5 to 38.5 % at 3 V and from 31.1 to 49.5 % at 5 V. TSS and TDS removal efficiencies were also significantly improved by AC filtration. It is therefore concluded that 7 V of CD and 4 h of RT are the optimum parameters for removing pollutants from leachate and that the secondary treatment of AC filtration is an efficient method of further polishing.
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References
Adhoum, N., & Monser, L. (2004). Decolorization and removal of phenolic compounds from olive mill wastewater by electrocoagulation. Chemical Engineering and Processing, 43, 1281–1287.
APHA. (1998). Standard methods for the examination of water and wastewater. Washington DC: American Public Health Association.
Bayramoglu, M., Can, O. T., Kobya, M., & Sozbir, M. (2004). Operating cost analysis of electrocoagulation of textile dye wastewater. Separation and Purification Technology, 37, 117–125.
Bonmati, A., & Flotats, X. (2003). Air stripping of ammonia from pig slurry: characterization and feasibility as a pre- of post-treatment to mesophilic anaerobic digestion. Waste Management, 23, 261–272.
Calvo, L. S., Leclerc, J. P., Tanguy, G., Cames, M. C., Paternotte, G., Valentin, G., Rostan, A., & Lapicque, F. (2003). An electrocoagulation unit for the purification of soluble oil wastes of high COD. Environmental Progress, 22, 57–65.
Can, O. T., Bayramoglu, M., & Kobya, M. (2003). Decolorization of reactive dye solutions by electrocoagulation using aluminum electrodes. Industrial and Engineering Chemistry Research, 42, 3391–3396.
Chen, G. (2004). Electrochemical technologies in wastewater treatment. Separation and Purification Technology, 38, 11–41.
Chen, X., Chen, G., & Yue, P. L. (2000a). Electrocoagulation and electroflotation of restaurant wastewater. Journal of Environmental Engineering, 126, 858–863.
Chen, X., Chen, G., & Yue, P. L. (2000b). Separation of pollutants from restaurant wastewater by electrocoagulation. Separation and Purification Technology, 19, 65–76.
Chen, X., Chen, G., & Yue, P. L. (2002). Novel electrode system for electroflotation of wastewater. Environmental Science and Technology, 36, 778–783.
Cho, J. H., Lee, J. E., & Ra, C. S. (2010). Effects of electric voltage and sodium chloride level on electrolysis of swine wastewater. Journal of Hazardous Materials, 180(1), 535–541.
Costa, C. R., & Olivi, P. (2009). Effect of chloride concentration on the electrochemical treatment of a synthetic tannery wastewater. Electrochimica Acta, 54, 2046–2052.
Daneshvar, N., Oladegaragoze, A., & Djafarzadeh, N. (2006). Decolorization of basic dye solutions by electrocoagulation: an investigation of the effect of operational parameters. Journal of Hazardous Materials, 129, 116–122.
Domínguez, J. R., González, T., Palo, P., Sánchez-Martín, J., Rodrigo, M. A., & Sáez, C. (2012). Electrochemical degradation of a real pharmaceutical effluent. Water, Air, and Soil Pollution, 223(5), 2685–2694.
Fernandes, A., Spranger, P., Fonseca, A. D., Pacheco, M. J., Ciríaco, L., & Lopes, A. (2014). Effect of electrochemical treatments on the biodegradability of sanitary landfill leachates. Applied Catalysis. B: Environment, 144, 514–520.
Fornazari, A. L. T., Malpass, G. R., Miwa, D. W., & Motheo, A. J. (2012). Application of electrochemical degradation of wastewater composed of mixtures of phenol–formaldehyde. Water, Air, and Soil Pollution, 223(8), 4895–4904.
Holt, P. K., Barton, G. W., & Mitchell, C. A. (2005). The future for electrocoagulation as a localised water treatment technology. Chemosphere, 59, 355–367.
Ibanez, J. G., Takimoto, M., Vasquez, R., Rajeshwar, K., & Basak, S. (1995). Laboratory experiments on electrochemical remediation of the environment: electrocoagulation of oily wastewater. Journal of Chemical Education, 72, 1050–1052.
Ilhan, F., Kurt, U., Apaydin, O., & Gonullu, M. T. (2008). Treatment of leachate by electrocoagulation using aluminum and iron electrodes. Journal of Hazardous Materials, 154(1), 381–389.
Inan, H., Dimoglu, A., Simsek, H., & Karpuzcu, M. (2004). Olive oil mill wastewater treatment by means of electrocoagulation. Separation and Purification Technology, 36, 23–31.
Jeong, B. Y., Song, S. H., Baek, K. W., Cho, I. H., & Hwang, T. S. (2006). Preparation and properties of heterogeneous cation exchange membrane for recovery of ammonium ion from waste water. Polymer (Korea), 30, 486–491.
Kabuk, H. A., İlhan, F., Avsar, Y., Kurt, U., Apaydin, O., & Gonullu, M. T. (2013). Investigation of leachate treatment with electrocoagulation and optimization by response surface methodology. CLEAN–Soil, Air, Water, 42(5), 571–577.
Khristoskova, S. (1984). Possibility of purification and decoloring wastewaters from the yeast industry by electrocoagulation. Nauchni Tr-Plovdski Uni. (Bul.), 22, 177–185.
Kim, K. W., Kim, Y. J., Kim, I. T., Park, I. G., & Lee, E. H. (2006). Electrochemical conversion characteristics of ammonia to nitrogen. Water Research, 40, 1431–1441.
Kobya, M., Can, O. T., & Bayramoglu, M. (2003). Treatment of textile wastewaters by electrocoagulation using iron and aluminum electrodes. Journal of Hazardous Materials, 100, 163–178.
Kobya, M., Senturk, E., & Bayramoglu, M. (2006). Treatment of poultry slaughterhouse wastewaters by electrocoagulation. Journal of Hazardous Materials, 133, 172–176.
Lin, S. H., & Chen, M. L. (1997). Treatment of textile wastewater by chemical methods for reuse. Water Research, 31, 868–876.
Lin, S. H., & Lin, C. S. (1998). Reclamation of wastewater effluent from a chemical fiber plant. Desalination, 120, 185–195.
Lin, S. H., & Peng, C. F. (1994). Treatment of textile wastewaters by electrochemical method. Water Research, 28, 277–876.
Mahmoud, A., & Hoadley, A. F. A. (2012). An evaluation of a hybrid ion exchange electrodialysis process in the recovery of heavy metals from simulated dilute industrial wastewater. Water Research, 46, 3364–3376.
Mollah, M. Y. A., Schennach, R., Parga, J. P., & Cocke, D. L. (2001). Electrocoagulation (EC)-science and applications. Journal of Hazardous Materials, 84, 29–41.
Öztürk, T., Veli, S., & Dimoglo, A. (2013). The effect of seawater conductivity on the treatment of leachate by electrocoagulation. Chemistry Biochemistry Engineering Quarterly, 27(3), 347–354.
Peng, Y., 2013. Perspectives on technology for landfill leachate treatment. Arab. J. Chemistry. http://dx.doi.org/10.1016/j.arabjc.2013.09.031
Pouet, M. F., & Grasmick, A. (1995). Urban wastewater treatment by electrocoagulation and flotation. Water Science and Technology, 31, 275–283.
Rada, E. C., Istrate, I. A., Ragazzi, M., Andreottola, G., & Torretta, V. (2013). Analysis of electro-oxidation suitability for landfill leachate treatment through an experimental study. Sustainability, 5(9), 3960–3975.
Rahman, M. M., Salleh, M. A. M., Rashid, U., Ahsan, A., Hossain, M. M., & Ra, C. S. (2014). Production of slow release crystal fertilizer from wastewaters through struvite crystallization—a review. Arabic Journal Chemistry., 7(1), 139–155.
Rajeshwar, K., Ibanez, J. G., & Swain, G. M. (1994). Electrochemistry and the environment. Journal of Applied Electrochemistry, 24, 1077–1091.
Renk, R. R. (1988). Electrocoagulation of tar sand and oil shale wastewater. Energy Progress, 8, 205–208.
Rizvi, H., Ahmad, N., Abbas, F., Bukhari, I. H., Yasar, A., Ali, S., Yasmeen, T, Riaz, M., 2013. Start-up of UASB reactors treating municipal wastewater and effect of temperature/sludge age and hydraulic retention time (HRT) on its performance. Arab. J. Chemistry. http://dx.doi.org/10.1016/j.arabjc.2013.12.016
Sanz, J., Lombrana, J. I., Luis, A. M. D., Ortueta, M., & Varona, F. (2003). Microwave and Fenton’s reagent oxidation of wastewater. Environmental Chemistry Letters, 1, 45–50.
Tsai, C. T., Lin, S. T., Shue, Y. C., & Su, P. L. (1997). Electrolysis of soluble organic matter in leachate from landfills. Water Research, 31, 3073–3081.
Un, U. T., Koparal, A. S., & Ogutveren, U. B. (2009). Hybrid processes for the treatment of cattle-slaughterhouse wastewater using aluminum and iron electrodes. Journal of Hazardous Materials, 164, 580–586.
Vijayaraghavan, K., Ahmad, D., & Ahmad, Y. A. Y. (2008). Electrolytic treatment of latex waste water. Desalination, 219, 214–221.
Wang, C. T., Chou, W. L., & Kuo, Y. M. (2009). Removal of COD from laundry wastewater by electrocoagulation/electroflotation. Journal of Hazardous Materials, 164, 81–86.
Xu, L. J., Sheldon, B. W., Larick, D. K., & Carawan, R. E. (2002). Recovery and utilization of useful by-products from egg processing wastewater by electrocoagulation. Poultry Science, 81, 785–792.
Yetilmezsoy, K., Ilhan, F., Zengin, Z. S., Sakar, S., & Gonullu, M. T. (2009). Decolorization and COD reduction of UASB pretreated poultry manure wastewater by electrocoagulation process: a post-treatment study. Journal of Hazardous Materials, 162, 120–132.
Zaleschi, L., Secula, M. S., Teodosiu, C., Stan, C. S., & Cretescu, I. (2014). Removal of rhodamine 6G from aqueous effluents by electrocoagulation in a batch reactor: assessment of operational parameters and process mechanism. Water, Air, and Soil Pollution, 225(9), 1–14.
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The financial support provided by UPM under RUGS, 05-02-12-1874RU, 9,344,400 is acknowledged. Authors gratefully acknowledge Prof. Thamer, Dr. Nik NND and students who supported this study.
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Ahsan, A., Kamaludin, M., Rahman, M.M. et al. Removal of Various Pollutants from Leachate Using a Low-Cost Technique: Integration of Electrolysis with Activated Carbon Contactor. Water Air Soil Pollut 225, 2163 (2014). https://doi.org/10.1007/s11270-014-2163-y
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DOI: https://doi.org/10.1007/s11270-014-2163-y