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Copper(II) immobilized on Fe3O4@SiO2@l-Histidine: a reusable nanocatalyst and its application in the synthesis of 5-substituted 1H-tetrazoles

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Abstract

Herein, we report the synthesis and application of Cu(II) immobilized on Fe3O4@SiO2@l-Histidine, which was characterized by FTIR spectroscopy, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy and atomic absorption spectroscopy. The obtained nanoparticles were employed as a heterogeneous catalyst for the synthesis of 5-substituted 1H-tetrazoles via [3+2] cycloaddition reactions of various organic nitriles with sodium azide in polyethylene glycol as solvent. The catalyst did not undergo metal leaching and could be easily recovered and reused many times.

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Acknowledgements

The authors acknowledge Ilam University, Ilam, Iran for financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, P. O. Box 69315516, Ilam, Iran

    Gouhar Azadi, Arash Ghorbani-Choghamarani & Lotfi Shiri

Authors
  1. Gouhar Azadi
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  2. Arash Ghorbani-Choghamarani
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  3. Lotfi Shiri
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Corresponding author

Correspondence to Arash Ghorbani-Choghamarani.

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Azadi, G., Ghorbani-Choghamarani, A. & Shiri, L. Copper(II) immobilized on Fe3O4@SiO2@l-Histidine: a reusable nanocatalyst and its application in the synthesis of 5-substituted 1H-tetrazoles. Transit Met Chem 42, 131–136 (2017). https://doi.org/10.1007/s11243-016-0115-7

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