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Copper complex immobilized on Fe3O4 nanoparticles: a novel and recoverable heterogenous catalyst for synthesis of heterocycles

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Abstract

2,4,6-Triaryl 1,3,5-triazine and 2-arylbenzothiazole derivatives have high biological activity potentials that are present in many natural and medicinal products. For these reasons, the synthesis of 2,4,6-triaryl 1,3,5-triazine and 2-arylbenzothiazole derivatives is of great interest among synthetic chemists. In this synthetic approach, we found that the utilization of Fe3O4@DH/Ph-ImH-Phen-CuCl2 nanocomposite in the presence of KOAc in ChCl/urea as solvent is an ecofriendly and efficient catalytic system for the synthesis of triazine and 2-arylbenzothiazole derivatives. Under this catalytic system, a broad range of 2,4,6-triaryl 1,3,5-triazine and 2-arylbenzothiazole derivatives were successfully synthesized with high to excellent yields. Compared to previously reported methods, this method has advantages such as synthesis of 2,4,6-triaryl 1,3,5-triazine and 2-arylbenzothiazole products with high to excellent yields, performance of reactions in ChCl/urea as green solvent, simple separation of the Fe3O4@DH/Ph-ImH-Phen-CuCl2 nanocatalyst only with an external magnet, high reusability of Fe3O4@DH/Ph-ImH-Phen-CuCl2 nanocatalyst, good characterization of the structure of copper nanomagnetic catalyst, and good characterization of the 2,4,6-triaryl 1,3,5-triazine and 2-arylbenzothiazole products by 1HNMR and 13CNMR spectroscopic techniques.

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Authors and Affiliations

  1. School of Chemical and Environmental Engineering, Jiaozuo University, Jiaozuo, 412000, China

    Jinfeng Fu, Xuemei Yang, Juan Du, Yan Hou & Zhongyang Liu

  2. Chemical Engineering and Technology, Guangzhou University, Guangzhou, China

    Jinwang Feng

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  1. Jinfeng Fu
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  4. Yan Hou
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  5. Zhongyang Liu
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Contributions

In this research work: Jinfeng FU is an advisor, helping in experimental works. Xuemei Yang is a student, performing experimental works. Juan Du is a student, performing experimental works. Yan Hou is a student, performing experimental works. Zhongyang Liu is a student, performing experimental works. Jinwang Feng is responsible and project manager.

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Correspondence to Jinfeng Fu or Jinwang Feng.

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Fu, J., Yang, X., Du, J. et al. Copper complex immobilized on Fe3O4 nanoparticles: a novel and recoverable heterogenous catalyst for synthesis of heterocycles. Res Chem Intermed (2024). https://doi.org/10.1007/s11164-024-05267-9

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