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Synthesis and spectroscopic studies of the cobalt(II) complex with methyl 2-pyridylmethylidenehydrazinecarbodithioate (HNNS)

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Abstract

A new cobalt(II) complex with the Schiff base methyl 2-pyridylmethylidenehydrazinecarbodithioate (HNNS), Co(NNS)2, has been synthesized and characterized using single-crystal X-ray diffraction and spectroscopy (IR, UV–Vis, MS and EA). Complex [Co(NNS)2] crystallizes in the orthorhombic, space group Pna2(1). The coordination geometry around Co(II) in the complex is distorted octahedral and the two ligands in the mer-configuration (S and tertiary N atom cis to each other and the iminic N atoms trans). Furthermore, the neutral molecule unit CoII(NNS)2 is connected by hydrogen bonds C–H ··· S and forms a three dimensional ordered network structure.

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Authors and Affiliations

  1. School of Chemistry and Environment, South China Normal University, Guangzhou, 510006, P.R. China

    Jia-Xiang Lin, Mei-Li Lin, Yu-Juan Su, Mao-Sheng Liu, He-Ping Zeng & Yue-Peng Cai

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  1. Jia-Xiang Lin
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  2. Mei-Li Lin
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  3. Yu-Juan Su
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  4. Mao-Sheng Liu
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  6. Yue-Peng Cai
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Correspondence to Yue-Peng Cai.

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Lin, JX., Lin, ML., Su, YJ. et al. Synthesis and spectroscopic studies of the cobalt(II) complex with methyl 2-pyridylmethylidenehydrazinecarbodithioate (HNNS). Transition Met Chem 32, 338–343 (2007). https://doi.org/10.1007/s11243-006-0173-3

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