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Syntheses and crystal structure of copper (II) and cobalt (II) complexes containing N-heterocyclic compounds

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Abstract

Four Cu(II) and Co(II) complexes with N-containing heterocycles as ligands were reported firstly. In a simple method, the reaction of 2-benzenediacetonitrile and pyridine-2-carboxaldehyde 2-quinolylhydrazone with Cu(OAc)2·H2O afforded the copper(II) complexes I–II, and addition of 2-(2-pyridyl)-1-(2-thiazolylazo)-2-naphthol with CoCl2·6H2O and 2-(2-pyridyl)benzimidazole with Co(OAc)2·4H2O furnished two mononuclear cobalt complexes III–IV. The structures of complexes I–IV were determined by elemental analysis, X-ray diffraction, NMR spectroscopy and IR spectroscopy.

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Scheme 1: The synthetic route for complex 1
Scheme 2: The synthetic route for complex 2
Scheme 3: The synthetic route for complex 3
Scheme 4: The synthetic route for complex 4
Fig. 1
Fig. 2
Fig. 3
Fig. 4

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Acknowledgements

This work was supported by Hefei University of Technology.

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Author notes

  1. Chen Chen Guo and Ya Zhou Li have contributed equally to this research work.

Authors and Affiliations

  1. Department of Chemical Engineering, Hefei University of Technology, Hefei, 230009, China

    Mei Luo, Chen Chen Guo, Ya Zhou Li & Jing Cheng Zhang

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  1. Mei Luo
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  2. Chen Chen Guo
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Correspondence to Mei Luo.

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Luo, M., Guo, C.C., Li, Y.Z. et al. Syntheses and crystal structure of copper (II) and cobalt (II) complexes containing N-heterocyclic compounds. J IRAN CHEM SOC 15, 415–420 (2018). https://doi.org/10.1007/s13738-017-1242-6

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  • DOI: https://doi.org/10.1007/s13738-017-1242-6

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