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New assembly of organic components and transition metal complexes based on [VMo6O22]3− and [V2Mo6O26]6− building blocks: syntheses, crystal structures, and magnetic properties

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Abstract

Two new molybdovanadates, (H3NCH2CH2NH3)3 [Mo6VO22(CH3COO)3]·5H2O (1) and (H3NCH2CH2NH3)2{(Mo6V2O26)[Cu(NH2CH2CH2NH2)(H2O)2]}·4H2O (2), have been synthesized in aqueous solution and characterized by IR, UV–vis, single-crystal X-ray diffraction, thermal gravimetric, elemental analysis, and magnetic analysis. Compound 1 is a crown-shaped ring consisted of six edge-sharing MoO6 octahedra linked to a central {VO4} unit. The MoO6 octahedra are in pairs connected with the carboxylato ligands from three acetic acid molecules. Compound 1 is the first example of a molybdovanadate coordinated by acetic acid molecules. In addition, multipoint hydrogen-bonding interactions exist in 1, which bridge the crown-shaped [Mo6VO22 (CH3COO)3]6− clusters and the protonated ethylenediamine molecules into three-dimensional (3D) networks. The structural feature of compound 2 is the formation of one-dimensional (1D) zip-zag chain in which [Mo6V2O26]6− clusters are covalently bonded to copper coordination groups through the terminal oxygen of the {VO4} tetrahedron. The magnetic investigation on compound 2 demonstrates the possible occurrence of antiferromagnetic interactions by intermolecular linkage.

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Acknowledgments

This work was financially supported by the Natural Science Foundation of China (Grant No. 20731002, 20971019, and 21001021) and the Fundamental Research Funds for the Central Universities. This work was also supported by the Program for Changjiang Scholars and Innovative Research Team in University.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Jianmei Li, Lin Xu, Ning Jiang, Lili Zhao & Fengyan Li

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  1. Jianmei Li
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  2. Lin Xu
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  3. Ning Jiang
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  4. Lili Zhao
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  5. Fengyan Li
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Correspondence to Lin Xu.

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Li, J., Xu, L., Jiang, N. et al. New assembly of organic components and transition metal complexes based on [VMo6O22]3− and [V2Mo6O26]6− building blocks: syntheses, crystal structures, and magnetic properties. Struct Chem 22, 1339–1345 (2011). https://doi.org/10.1007/s11224-011-9830-z

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  • DOI: https://doi.org/10.1007/s11224-011-9830-z

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