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First examples of the cocrystallization of diastereomers of chiral phosphorus compounds

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Abstract

The first three examples of the cocrystallization of covalent diastereomers of phosphorus compounds containing different chiral elements (centres of chirality on carbon and phosphorus, and an axis of chirality) are reported. The phenomenon can be attributed to the complementarity of the molecular shapes of the diastereomers. The X-ray data of all the crystals exhibit centrosymmetric statistics regardless of their very different natures.

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Acknowledgments

This study was supported by the Russian Foundation for Basic Research, grants 06-03-32508, 06-03-32085 and 07-03-00617. The authors would like to thank Dr. R. Fröhlich and Prof. Dr. G. Erker for their support and for providing X-ray facilities at the University of Münster (Germany).

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Authors and Affiliations

  1. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, A.E.Arbuzov Str. 8, Kazan, 420088, Russia

    Vladimir A. Alfonsov, Alexander A. Bredikhin, Zemfira A. Bredikhina, Rimma M. Eliseenkova, Olga N. Kataeva, Igor A. Litvinov & Michael A. Pudovik

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  1. Vladimir A. Alfonsov
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  2. Alexander A. Bredikhin
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  3. Zemfira A. Bredikhina
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  4. Rimma M. Eliseenkova
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  5. Olga N. Kataeva
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  6. Igor A. Litvinov
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  7. Michael A. Pudovik
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Correspondence to Olga N. Kataeva.

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Dedicated to the memory of Professor Viktor Naumov (1932–2007).

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Alfonsov, V.A., Bredikhin, A.A., Bredikhina, Z.A. et al. First examples of the cocrystallization of diastereomers of chiral phosphorus compounds. Struct Chem 19, 873–878 (2008). https://doi.org/10.1007/s11224-008-9353-4

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  • DOI: https://doi.org/10.1007/s11224-008-9353-4

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