Abstract
Philosophical debates about chemistry have clarified that the issue of emergence plays a critical role in the epistemology and ontology of chemistry. In this article, it is argued that the issue of emergence has also significant implications for understanding learning difficulties and finding ways of addressing them in chemistry. Particularly, it is argued that many misconceptions in chemistry may derive from students’ failure to consider emergence in a systemic manner by taking into account all relevant factors in conjunction. Based on this argument, undergraduate students’ conceptions of acids, and acid strength (an emergent chemical property) were investigated and it was examined whether or not they conceptualized acid strength as an emergent chemical property. The participants were 41 third- and fourth-year undergraduate students. A concept test and semi-structured interviews were used to probe students’ conceptualizations and reasoning about acid strength. Findings of the study revealed that the majority of the undergraduate students did not conceptualize acid strength as an emergent property that arises from interactions among multiple factors. They generally focused on a single factor to predict and explain acid strength, and their faulty responses stemmed from their failure to recognize and consider all factors that affect acid strength. Based on these findings and insights from philosophy of chemistry, promoting system thinking and epistemologically sound argumentative discourses among students is suggested for meaningful chemical education.
Similar content being viewed by others
References
Adúriz-Bravo, A. (2013). A “semantic” view of scientific models for science education. Science & Education, 22(7), 1593–1611.
Andersson, B. (1990). Pupils’ conceptions of matter and its transformations (age 12–16). Studies in Science Education, 18(1), 53–85.
Arrhenius, S. (1912). Electrolytic dissociation. Journal of the American Chemical Society, 34(4), 353–364.
Assaraf, O. B.-Z., & Orion, N. (2005). Development of system thinking skills in the context of earth system education. Journal of Research in Science Teaching, 42(5), 518–560.
Ben-Zvi, R., Eylon, B.-S., & Silberstein, J. (1986). Is an atom of copper malleable? Journal of Chemical Education, 63(1), 64–66.
Bernal, A., & Daza, E. E. (2010). On the epistemological and ontological status of chemical relations. HYLE-International Journal for Philosophy of Chemistry, 16(2), 80–103.
Bhattacharyya, G. (2006). Practitioner development in organic chemistry: How graduate students conceptualize organic acids. Chemistry Education Research and Practice, 7(4), 240–247.
Brønsted, J. (1923). Some remarks on the concept of acids and bases. Recueil des Travaux Chimiques des Pays-Bas, 42, 718–728.
Caldin, E. F. (1959). Theories and the development of chemistry. The British Journal for the Philosophy of Science, 10(39), 209–222.
Chi, M. T., Roscoe, R. D., Slotta, J. D., Roy, M., & Chase, C. C. (2012). Misconceived causal explanations for emergent processes. Cognitive Science, 36(1), 1–61.
Coll, R. K., & Treagust, D. F. (2003). Investigation of secondary school, undergraduate, and graduate learners’ mental models of ionic bonding. Journal of Research in Science Teaching, 40(5), 464–486.
Creswell, J. W. (1994). Research design qualitative and quantitative approaches. Thousand Oaks: Sage.
De Vos, W., & Pilot, A. (2001). Acids and bases in layers: The stratal structure of an ancient topic. Journal of Chemical Education, 78(4), 494–499.
DeFever, R. S., Bruce, H., & Bhattacharyya, G. (2015). Mental rolodexing: Senior chemistry majors’ understanding of chemical and physical properties. Journal of Chemical Education, 92(3), 415–426.
Demerouti, M., Kousathana, M., & Tsaparlis, G. (2004). Acid-base equilibria, part I: Upper secondary students, misconceptions and difficulties. The Chemical Educator, 9(2), 122–131.
Driver, R., Leach, J., Millar, R., & Scott, P. (1996). Young people’s images of science. Buckingham, UK: Open University Press.
Erduran, S. (1999). Merging curriculum design with chemical epistemology: A case of teaching and learning chemistry through modelling. Unpublished Ph.D. dissertation, Vanderbilt University, Nashville.
Erduran, S. (2001). Philosophy of chemistry: An emerging field with implications for chemistry education. Science & Education, 10, 581–593.
Erduran, S. (2005). Applying the philosophical concept of reduction to the chemistry of water: Implications for chemical education. Science & Education, 14(2), 161–171.
Erduran, S. (2007). Breaking the law: Promoting domain-specificity in chemical education in the context of arguing about the periodic law. Foundations of Chemistry, 9(3), 247–263.
Erduran, S., & Jiménez-Aleixandre, M. P. (2007). Argumentation in science education: Perspectives from classroom-based research. Dordrecht: Springer.
Erduran, S., & Scerri, E. (2002). The nature of chemical knowledge and chemical education. In J. K. Gilbert, O. de Jong, R. Justi, D. F. Treagust, & J. H. van Driel (Eds.), Chemical education: Towards research-based practice (pp. 7–27). Dordrecht: Kluwer Academic Publishers.
Furió-Más, C., Calatayud, M. L., Guisasola, J., & Furió-Gómez, C. (2005). How are the concepts and theories of acid–base reactions presented? Chemistry in textbooks and as presented by teachers. International Journal of Science Education, 27(11), 1337–1358.
Gabel, D. (1998). The complexity of chemistry and implications for teaching. In B. J. Fraser & K. G. Tobin (Eds.), International handbook of science education (pp. 233–248). Great Britain: Kluwer.
Garnett, P. J., Garnett, P. J., & Hackling, M. W. (1995). Students’ alternative conceptions in chemistry: A review of research and implications for teaching and learning. Studies in Science Education, 25(1), 69–96.
Gilbert, J. K., & Watts, D. M. (1983). Concepts, misconceptions and alternative conceptions: Changing perspectives in science education. Studies in Science Education, 10(1), 61–98.
Glaser, B. G., & Strauss, A. L. (1967). The discovery of grounded theory: Strategies for qualitative research. Chicago: Aldine Publishing Company.
Griffiths, A. K., & Preston, K. R. (1992). Grade-12 students’ misconceptions relating to fundamental characteristics of atoms and molecules. Journal of Research in Science Teaching, 29(6), 611–628.
Hawkes, S. J. (1992). Arrhenius confuses students. Journal of Chemical Education, 69(7), 542–543.
Izquierdo-Aymerich, M. (2013). School chemistry: An historical and philosophical approach. Science & Education, 22(7), 1633–1653.
Jensen, W. B. (1980). The Lewis acid-base concepts: An overview. New York: Wiley.
Jensen, W. B. (1998). Logic, history, and the chemistry textbook: I. Does chemistry have a logical structure? Journal of Chemical Education, 75(6), 679–687.
Johnstone, A. H. (1991). Why is science difficult to learn? Things are seldom what they seem. Journal of Computer Assisted learning, 7(2), 75–83.
Kaya, E., & Erduran, S. (2013). Integrating epistemological perspectives on chemistry in chemical education: The cases of concept duality, chemical language, and structural explanations. Science & Education, 22(7), 1741–1755.
Kousathana, M., Demerouti, M., & Tsaparlis, G. (2005). Instructional misconceptions in acid-base equilibria: An analysis from a history and philosophy of science perspective. Science & Education, 14, 173–193.
Kovac, J., & Weisberg, M. (2012). Roald Hoffmann on the philosophy, art, and science of chemistry. New York: Oxford University Press.
Laszlo, P. (2013). Towards teaching chemistry as a language. Science & Education, 22(7), 1669–1706.
Lavoisier, A. L. (1789). Traité élémentaire de chimie. Cuchet, Paris. English Translation by R. Kerr (1790), Elements of chemistry, Creech, Edinburgh.
Lewis, G. N. (1916). The atom and the molecule. Journal of the American Chemical Society, 38(4), 762–785.
Lewis, G. N. (1923). Valence and the structure of atoms and molecules. New York: The Chemical Catalog Company.
Lincoln, Y. S., & Guba, E. G. (1985). Naturalistic inquiry. Newbury Park, Ca: Sage.
Lombardi, O., & Labarca, M. (2005). The ontological autonomy of the chemical world. Foundations of Chemistry, 7, 125–148.
Lowry, T. M. (1923). The uniqueness of hydrogen. Journal of the Society of Chemical Industry, 42(3), 43–47.
Luisi, P. L. (2002). Emergence in chemistry: Chemistry as the embodiment of emergence. Foundations of Chemistry, 4, 183–200.
McClary, L. M., & Bretz, S. L. (2012). Development and assessment of a diagnostic tool to identify organic chemistry students’ alternative conceptions related to acid strength. International Journal of Science Education, 34(15), 2317–2341.
McClary, L., & Talanquer, V. (2011a). College chemistry students’ mental models of acids and acid strength. Journal of Research in Science Teaching, 48(4), 396–413.
McClary, L., & Talanquer, V. (2011b). Heuristic reasoning in chemistry: Making decisions about acid strength. International Journal of Science Education, 33(10), 1433–1454.
McIntyre, L. (1999). The emergence of the philosophy of chemistry. Foundations of Chemistry, 1, 57–63.
McIntyre, L. (2007). Emergence and reduction in chemistry: Ontological or epistemological concepts? Synthese, 155, 337–343.
Moran, M. J. (2006). Factors that influence relative acid strength in water: A simple model. Journal of Chemical Education, 83(5), 800–803.
Nakhleh, M. B. (1992). Why some students don’t learn chemistry: Chemical misconceptions. Journal of Chemical Education, 69(3), 191–196.
Nakiboğlu, C. (2003). Instructional misconceptions of Turkish prospective chemistry teachers about atomic orbitals and hybridization. Chemistry Education Research and Practice, 4(2), 171–188.
Newman, M. (2013). Emergence, supervenience, and introductory chemical education. Science & Education, 22, 1655–1667.
Ogborn, J., Kress, G., Martins, I., & McGillicuddy, K. (1996). Explaining science in the classroom. Buckingham, Philadelphia: Open University Press.
Rappoport, L. T., & Ashkenazi, G. (2008). Connecting levels of representation: Emergent versus submergent perspective. International Journal of Science Education, 30(12), 1585–1603.
Reiher, M. (2003). A systems theory for chemistry. Foundations of Chemistry, 5(1), 23–41.
Scerri, E. R. (2001). The new philosophy of chemistry and its relevance to chemical education. Chemistry Education Research and Practice, 2(2), 165–170.
Shulman, L. S. (1987). Knowledge and teaching: Foundations of the new reform. Harvard Educational Review, 57(1), 1–23.
Smith, J. P., DiSessa, A. A., & Roschelle, J. (1993). Misconceptions reconceived: A constructivist analysis of knowledge in transition. Journal of the Learning Sciences, 3(2), 115–163.
Stöckler, M. (1991). A short history of emergence and reductionism. In E. Agazzi (Ed.), The problem of reductionism in science (pp. 71–90). Dordrecht: Springer.
Taber, K. S. (2000). Multiple frameworks?: Evidence of manifold conceptions in individual cognitive structure. International Journal of Science Education, 22(4), 399–417.
Taber, K. S. (2001). Building the structural concepts of chemistry: Some considerations from educational research. Chemistry Education Research and Practice, 2(2), 123–158.
Taber, K. S. (2002). Chemical misconceptions: Prevention, diagnosis and cure (Vol. I). London: Royal Society of Chemistry.
Taber, K. S. (2008). Exploring conceptual integration in student thinking: Evidence from a case study. International Journal of Science Education, 30(14), 1915–1943.
Taber, K. S., & García-Franco, A. (2010). Learning processes in chemistry: Drawing upon cognitive resources to learn about the particulate structure of matter. Journal of the Learning Sciences, 19(1), 99–142.
Talanquer, V. (2006). Commonsense chemistry: A model for understanding students’ alternative conceptions. Journal of Chemical Education, 83(5), 811–816.
Talanquer, V. (2008). Students’ predictions about the sensory properties of chemical compounds: Additive versus emergent frameworks. Science Education, 92, 96–114.
Talanquer, V. (2009). On cognitive constraints and learning progressions: The case of “Structure of Matter”. International Journal of Science Education, 31(15), 2123–2136.
Talanquer, V. (2013a). How do students reason about chemical substances and reactions? In G. Tsaparlis & H. Sevian (Eds.), Concepts of matter in science education (pp. 331–345). Dordrecht: Springer.
Talanquer, V. (2013b). School chemistry: The need for transgression. Science & Education, 22(7), 1757–1773.
Talanquer, V. (2015). Threshold concepts in chemistry: The critical role of implicit schemas. Journal of Chemical Education, 92(1), 3–9.
Toulmin, S. E. (1958). The uses of argument. Cambridge: Cambridge University Press.
Tümay, H. (2014). Prospective chemistry teachers’ mental models of vapor pressure. Chemistry Education Research and Practice, 15, 366–379.
Valanides, N. (2000). Primary student teachers’ understanding of the particulate nature of matter and its transformations during dissolving. Chemistry Education Research and Practice, 1(2), 249–262.
Villani, G. (2014). Structured system in chemistry: Comparison with mechanics and biology. Foundations of Chemistry, 16(2), 107–123.
Wandersee, J., Mintzes, J., & Novak, J. (1994). Research on alternative conceptions in science. In D. L. Gabel (Ed.), Handbook of research on science teaching and learning (pp. 177–210). New York: MacMillan.
Weisberg, M. (2004). Qualitative theory and chemical explanation. Philosophy of Science, 71(5), 1071–1081.
Wilensky, U., & Resnick, M. (1999). Thinking in levels: A dynamic systems approach to making sense of the world. Journal of Science Education and Technology, 8(1), 3–19.
Acknowledgments
I would like to thank the reviewers for their critical review and valuable suggestions which helped me further improve this article. I also would like to thank Prof. Sibel Erduran and Prof. Yüksel Tufan for their constructive suggestions and discussions which improved this work.
Conflict of interest
The author declares no conflict of interest.
Author information
Authors and Affiliations
Corresponding author
Appendix: Acid Strength Concept Test
Appendix: Acid Strength Concept Test
What is acid?
What is strong acid and weak acid?
Please rank the following chemical compounds based on their relative acid strength from least to most acidic. Explain and justify your reasoning in ranking acid strength.
(A) CH4 | NH3 | H2O | HF |
(B) HF | HCl | HBr | HI |
(C) HClO | HClO2 | HClO3 | HClO4 |
(D) C2H5OH | CH3COOH | C6H5COOH |
Rights and permissions
About this article
Cite this article
Tümay, H. Emergence, Learning Difficulties, and Misconceptions in Chemistry Undergraduate Students’ Conceptualizations of Acid Strength. Sci & Educ 25, 21–46 (2016). https://doi.org/10.1007/s11191-015-9799-x
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11191-015-9799-x