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Magnetically active coordination polymers containing VO2+ and Na+ cations linked by substituted malonic acid anions

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Abstract

The interaction of vanadyl sulfate VOSO4·3H2O and dimethylmalonic (H2Me2mal = = C3H6(CO2H)2), butylmalonic (H2Bumal = C4H10(CO2H)2), and cyclobutane-1,1-dicarboxylic (H2cbdc = C4H6(CO2H)2) acids with Na2CO3 at pH ∼4 in aqueous solutions gives crystals of compounds [Na4(VO)2(Me2mal)4(H2O)] n (1), {[Na6(VO)3(Bumal)6(H2O)15]· ·3H2O} n (2), and [Na2(VO)(cbdc)2(H2cbdc)(H2O)3] n (3), whose structures were determined by X-ray diffraction analysis. The formation of 3D (for 1) and 2D (for 2 and 3) polymer networks occurs in crystals of the compounds. These networks are constructed of mononuclear bis-chelate dianionic fragments [VOL2]2− (L is the corresponding dicarboxylic acid dianion) linked by the Na atoms. The magnetic properties of the obtained compounds were studied. The solid samples and solutions of complexes 1–3 were characterized by ESR spectroscopy.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninskii prosp., 119991, Moscow, Russian Federation

    E. S. Bazhina, G. G. Aleksandrov, M. A. Kiskin, N. N. Efimov, E. A. Ugolkova, V. V. Minin, A. A. Sidorov, V. M. Novotortsev & I. L. Eremenko

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  1. E. S. Bazhina
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  2. G. G. Aleksandrov
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  3. M. A. Kiskin
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  4. N. N. Efimov
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  5. E. A. Ugolkova
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  6. V. V. Minin
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  7. A. A. Sidorov
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  8. V. M. Novotortsev
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  9. I. L. Eremenko
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Correspondence to E. S. Bazhina.

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Dedicated to Academician of the Russian Academy of Sciences O. N. Chupakhin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1475–1486, July, 2014.

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Bazhina, E.S., Aleksandrov, G.G., Kiskin, M.A. et al. Magnetically active coordination polymers containing VO2+ and Na+ cations linked by substituted malonic acid anions. Russ Chem Bull 63, 1475–1486 (2014). https://doi.org/10.1007/s11172-014-0623-6

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  • DOI: https://doi.org/10.1007/s11172-014-0623-6

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