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Magnetic effects in hydroperoxide decomposition in mixed micelles with cationic surfactants

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Abstract

The retardation effect of oxygen and external magnetic field on the yield of radicals in hydroperoxide decomposition in catalytic nanoreactors was discovered. Mixed reverse micelles formed by the cationic surfactants (Surf) and hydroperoxide {mLOOH...nSurf} play the role of nanoreactors. Similar effects of oxygen and external magnetic field (60–150 mT) on the yield of radicals are observed in the catalytic decomposition of hydroperoxide in the presence of acetylcholine. It is noteworthy that the retardation effect of the magnetic field decreases in the presence of paramagnetic particles such as oxygen and relatively stable radicals.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    O. T. Kasaikina

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, 1/3 Leninskie Gory, 119991, Moscow, Russian Federation

    O. T. Kasaikina & L. M. Pisarenko

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  1. O. T. Kasaikina
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  2. L. M. Pisarenko
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Correspondence to O. T. Kasaikina.

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Dedicated to Academician of the Russian Academy of Sciences A. L. Buchachenko on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2319–2324, October, 2015.

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Kasaikina, O.T., Pisarenko, L.M. Magnetic effects in hydroperoxide decomposition in mixed micelles with cationic surfactants. Russ Chem Bull 64, 2319–2324 (2015). https://doi.org/10.1007/s11172-015-1158-1

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  • DOI: https://doi.org/10.1007/s11172-015-1158-1

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