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Acetylcholine as a catalyst of hydroperoxide decomposition to free radicals

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Abstract

In organic solvents, acetylcholine chloride accelerates lipid oxidation and hydroperoxide decomposition to free radicals similarly to cationic surfactants. The rates of radical formation in the reaction of acetylcholine with cumyl, tert-butyl, and limonene hydroperoxides and hydrogen peroxide at 37 °C were estimated by the inhibitor method using different radical acceptors. In an aqueous medium, hygroscopic acetylcholine does not react with hydroperoxides.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    D. A. Krugovov, E. A. Mengele & O. T. Kasaikina

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  1. D. A. Krugovov
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  2. E. A. Mengele
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  3. O. T. Kasaikina
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Correspondence to O. T. Kasaikina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1837–1842, August, 2014.

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Krugovov, D.A., Mengele, E.A. & Kasaikina, O.T. Acetylcholine as a catalyst of hydroperoxide decomposition to free radicals. Russ Chem Bull 63, 1837–1842 (2014). https://doi.org/10.1007/s11172-014-0673-9

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  • DOI: https://doi.org/10.1007/s11172-014-0673-9

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