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Peroxidation of β-diketones and β-keto esters with tert-butyl hydroperoxide in the presence of Cu(ClO4)2/SiO2

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Abstract

Reactions of β-diketones and β-keto esters with tert-butyl hydroperoxide under heterogeneous conditions using SiO2-supported copper(II) perchlorate as a catalyst give rise to α-peroxidation products in 65—82% yields. A possibility to reuse the catalyst was demonstrated.

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  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. O. Terent´ev, V. A. Vil´, O. V. Bityukov & G. I. Nikishin

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  1. A. O. Terent´ev
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  2. V. A. Vil´
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  3. O. V. Bityukov
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  4. G. I. Nikishin
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Correspondence to A. O. Terent´ev.

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Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday and to the 60th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2461—2466, November, 2014.

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Terent´ev, A.O., Vil´, V.A., Bityukov, O.V. et al. Peroxidation of β-diketones and β-keto esters with tert-butyl hydroperoxide in the presence of Cu(ClO4)2/SiO2 . Russ Chem Bull 63, 2461–2466 (2014). https://doi.org/10.1007/s11172-014-0763-8

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