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Magnetic cobalt ferrite nanoparticles functionalized with citric acid as a green nanocatalyst for one-pot three-component sonochemical synthesis of substituted 3-pyrrolin-2-ones

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Abstract

A clean, convenient and facile approach for one-pot ultrasonic assisted synthesis of substituted 3-pyrrolin-2-ones from diethyl acetylenedicarboxylate, aniline and aldehyde derivatives is described. The reactions were carried out in the presence of an efficient, green and reusable acidic nanocatalyst, magnetic cobalt ferrite nanoparticles functionalized with citric acid (CoFe2O4@CA), with high yields under mild conditions. Also, use of ultrasound irradiation made this approach an attractive protocol for the synthesis of these products. The method has been successful in achieving the green chemistry objective. An energy efficient protocol using ultrasound irradiation instead of conventional heating or stirring and use of ethanol as a non-hazardous, inexpensive and green solvent in the one-step reaction against sequential reaction steps thus combining the features of both economic and environmental advantages.

Graphic abstract

In this research, magnetic cobalt ferrite nanoparticles functionalized with citric acid (CoFe2O4@CA) catalyzed synthesis of substituted 3-pyrrolin-2-ones under ultrasonic irradiation via a practical and environmentally benign one-pot three-component protocol.

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Acknowledgements

This work was supported by the “Iran National Science Foundation”.

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Authors and Affiliations

  1. Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran

    Hamideh Ahankar & Ali Ramazani

  2. Research Institute of Modern Biological Techniques, University of Zanjan, P O Box 45195-313, Zanjan, Iran

    Ali Ramazani

  3. Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St., 50-383, Wrocław, Poland

    Katarzyna Ślepokura & Tadeusz Lis

  4. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P O Box 1410, 50-950, Wrocław, Poland

    Vasyl Kinzhybalo

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  1. Hamideh Ahankar
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  2. Ali Ramazani
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  3. Katarzyna Ślepokura
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  4. Tadeusz Lis
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  5. Vasyl Kinzhybalo
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Correspondence to Ali Ramazani.

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Ahankar, H., Ramazani, A., Ślepokura, K. et al. Magnetic cobalt ferrite nanoparticles functionalized with citric acid as a green nanocatalyst for one-pot three-component sonochemical synthesis of substituted 3-pyrrolin-2-ones. Res Chem Intermed 45, 5007–5025 (2019). https://doi.org/10.1007/s11164-019-03878-1

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