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Dehydration of Xylose to Furfural and Its Valorization via Different Multicomponent Reactions Using Sulfonated Silica with Magnetic Properties as Recyclable Catalyst

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Abstract

Sulfonated silica with magnetic properties was studied for dehydration of xylose to furfural and posteriorly for furfural valorization through the Biginelli and Hantzsch multicomponent reactions. Eleven polysubstituted heterocycles were obtained in excellent yields and without any side-product (81–91 %), using a multicomponent green methodology. The presence of Fe3O4 particles allows an easy separation from the reaction medium giving a high yield in the reusability studies.

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Acknowledgments

We thank DIN-UPTC for financial support under the project No. SGI 1352, and CONICET, UN La Plata, and ANPCyT for financial support. GPR and AGS are members of CONICET.

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Authors and Affiliations

  1. Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia UPTC, Avenida Central del Norte, Vía Paipa, Tunja, Boyacá, Colombia

    José J. Martínez, Eliana Nope, Hugo Rojas & Jairo Cubillos

  2. Departamento de Química, Facultad de Ciencias Exactas, Centro de Investigación y Desarrollo en Ciencias Aplicadas “Dr. J.J. Ronco” (CINDECA), UNLP-CCT-CONICET. Calle 47 Nº 257, B1900AJK, La Plata, Argentina

    Ángel G. Sathicq & Gustavo P. Romanelli

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  1. José J. Martínez
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  2. Eliana Nope
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  3. Hugo Rojas
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  4. Jairo Cubillos
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  5. Ángel G. Sathicq
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  6. Gustavo P. Romanelli
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Correspondence to José J. Martínez.

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Martínez, J.J., Nope, E., Rojas, H. et al. Dehydration of Xylose to Furfural and Its Valorization via Different Multicomponent Reactions Using Sulfonated Silica with Magnetic Properties as Recyclable Catalyst. Catal Lett 144, 1322–1331 (2014). https://doi.org/10.1007/s10562-014-1267-8

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  • DOI: https://doi.org/10.1007/s10562-014-1267-8

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