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Guanidinium-based sulfonic acid as a new Brønsted acid organocatalyst in organic synthesis in water

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Abstract

Guanidinium-based sulfonic acid as a new Brønsted acid organocatalyst has been synthesized, characterized, and applied for the synthesis of 3,4-dihydroquinoxalin-2-amine, 1,6-dihydropyrazine-2,3-dicarbonitrile, triazolo[1,2-a]indazole-trione, and spiro triazolo[1,2-a]indazole-tetraone derivatives in an aqueous medium. The catalytic system, reported here, possesses the advantages of both homogeneous and heterogeneous catalysts and can be repetitively used in water.

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Acknowledgments

We gratefully acknowledge financial support from the Iran National Elites Foundation (INEF) and the Research Council of Shahid Beheshti University.

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Authors and Affiliations

  1. Faculty of Chemistry, Shahid Beheshti University, G. C., P. O. Box 19396-4716, Tehran, Iran

    Mozhdeh Seyyedhamzeh, Shabnam Shaabani, Mona Hamidzad Sangachin & Ahmad Shaabani

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  1. Mozhdeh Seyyedhamzeh
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  2. Shabnam Shaabani
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  3. Mona Hamidzad Sangachin
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  4. Ahmad Shaabani
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Correspondence to Ahmad Shaabani.

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Seyyedhamzeh, M., Shaabani, S., Hamidzad Sangachin, M. et al. Guanidinium-based sulfonic acid as a new Brønsted acid organocatalyst in organic synthesis in water. Res Chem Intermed 42, 2845–2855 (2016). https://doi.org/10.1007/s11164-015-2181-4

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  • DOI: https://doi.org/10.1007/s11164-015-2181-4

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