Abstract
A series of methanol synthesis catalysts, CuO/ZnO/Al2O3 and CuO/ZnO/Al2O3 containing 5 mol% of manganese physically admixed with γ-Al2O3 were tested for the direct synthesis of dimethyl ether from syngas. The catalysts were prepared by coprecipitation of the metal nitrates with several types of alkali carbonate solution. Aqueous solutions of Na2CO3, NaHCO3/Na2CO3 buffer, and NaHCO3 were used as the precipitating agents to investigate the effects of the preparation method on the microstructure of the precursors and on the physicochemical properties and reactivity of the resulting catalysts. It was found that the most responsible factor in determining the catalytic activity of the methanol synthesis catalyst is the preparation method rather than the incorporation of manganese as the structure modifier. There is a substantial correlation between the copper metal surface area and the activity of the catalyst derived from the structurally active precursor, hydrotalcite-like layered double hydroxides.
Similar content being viewed by others
References
Prasad PSS, Bae JW, Kang SH, Lee YJ, Jun KW (2008) Fuel Proc Technol 89:1281
Sofianos AC, Scurrell MS (1991) Ind Eng Chem Res 30:2372
Venugopal A, Palgunadi J, Jung KD, Joo OS, Shin CH (2008) Catal Lett 123:142
Klier K (1982) Advance in catalysis. Academic Press, New York, p 243
Höppener RH, Doesburg EBM, Scholten JJF (1986) Appl Catal 25:109
Meshkini F, Taghizadeh M, Bahmani M (2010) Fuel 89:170
Venugopal A, Palgunadi J, Deog JK, Joo OS, Shin CH (2009) J Mol Catal A Chem 302:20
Busetto C, Piero GD, Manara G (1984) J Catal 85:260
Frost RL, Ding Z, Martens WN, Johnson TE (2003) Thermochim Acta 398:167
Li JL, Inui T (1996) Appl Catal A Gen 137:105
Fujita S, Kanamori Y, Satriyo AM, Takezawa N (1998) Catal Today 45:241
Li J, Zhang W, Gao L, Gu P, Sha K, Wan H (1997) Appl Catal A Gen 165:411
Tan Y, Xie H, Cui H, Han Y, Zhong B (2005) Catal Today 104:25
Matulewicz ERA, Keijser MS, Mol JC, Kapteijn F (1984) Thermochim Acta 72:111
Evans JW, Wainwright MS, Bridgewater AJ, Young DJ (1983) Appl Catal 7:75
Fang D, Liu Z, Meng S, Wang L, Xu L, Wang H (2005) J Nat Gas Chem 14:107
Stone FS, Waller D (2003) Top Catal 22:305
Trifirò F, Vaccari A, Del Piero G (1988) Characterization of porous solids. Elsevier, Amsterdam
Fujita SI, Moribe S, Kanamori Y, Takezawa N (2000) Reac Kinet Catal Lett 70:11
Robinson WRAM, Mol JC (1990) Appl Catal 60:61
Qi GX, Zheng XM, Fei JH, Hou ZY (2001) J Mol Catal A Chem 176:195
Fei JH, Yang MX, Hou ZY, Zheng XM (2004) Energy Fuels 18:1584
Chen HY, Lin J, Tan KL, Li J (1998) Appl Surf Sci 126:323
Nakamura J, Uchijima T, Kanai Y, Fujitani T (1996) Catal Today 28:223
Velu S, Suzuki K, Osaki T (1999) Catal Lett 62:159
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Palgunadi, J., Yati, I. & Jung, K.D. Catalytic activity of Cu–Zn–Al–Mn admixed with gamma-alumina for the synthesis of DME from syngas: manganese effect or just method of preparation?. Reac Kinet Mech Cat 101, 117–128 (2010). https://doi.org/10.1007/s11144-010-0205-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11144-010-0205-z